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Bis(imino)pyridine Ligand Deprotonation Promoted by a Transient Iron Amide Marco W. Bouwkamp, Emil Lobkovsky, and Paul J. Chirik pp 2 - 4; DOI: 10.1021/ic051839o |
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Heterodinuclear Cu-Tb Single-Molecule Magnet Jean-Pierre Costes, Françoise Dahan, and Wolfgang Wernsdorfer pp 5 - 7; DOI: 10.1021/ic050563h |
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Subnanosecond Isomerization in an Osmium-Dimethyl Sulfoxide Complex Nicholas V. Mockus, Jeffrey L. Petersen, and Jeffrey J. Rack pp 8 - 10; DOI: 10.1021/ic051720f |
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Mercury(II) Cyanide Coordination Polymer with Dinuclear Gold(I) Amidinate. Structure of the 2-D [Au2(2,6-Me2-formamidinate)2]·2Hg(CN)2·2THF Complex Ahmed A. Mohamed, Hanan E. Abdou, and John P. Fackler Jr. pp 11 - 13; DOI: 10.1021/ic051114k |
Thermochromic Triangular [MCo2] (M = Rh, Ir, Ru) Clusters Containing a Planar Metalladithiolene Ring in  3 CoordinationNorikiyo Nakagawa, Teppei Yamada, Masaki Murata, Manabu Sugimoto, and Hiroshi Nishihara pp 14 - 16; DOI: 10.1021/ic051829n |
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Electronic Structure, Bonding, Spectroscopy and Energetics of Fe-Dependent Nitrile Hydratase Active-Site Models Shannon N. Greene and Nigel G. J. Richards pp 17 - 36; DOI: 10.1021/ic050965p |
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Interaction of rac-[Ru(5,6-dmp)3]2+ with DNA: Enantiospecific DNA Binding and Ligand-Promoted Exciton Coupling Palanisamy Uma Maheswari, Venugopal Rajendiran, Helen Stoeckli-Evans, and Mallayan Palaniandavar pp 37 - 50; DOI: 10.1021/ic050940q |
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Electronic Energy-Transfer Rate Constants for Geometrical Isomers of a Bichromophoric Macrocyclic Complex Evan G. Moore, Paul V. Bernhardt, Mark J. Riley, and Trevor A. Smith pp 51 - 58; DOI: 10.1021/ic050396l |
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Dodecanuclear Manganese(III) Phosphonates with Cage Structures Hong-Chang Yao, Yi-Zhi Li, You Song, Yun-Sheng Ma, Li-Min Zheng, and Xin-Quan Xin pp 59 - 65; DOI: 10.1021/ic050775e |
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Mercury(II) Cysteine Complexes in Alkaline Aqueous Solution Farideh Jalilehvand, Bonnie O. Leung, Maryam Izadifard, and Emiliana Damian pp 66 - 73; DOI: 10.1021/ic0508932 |
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Dinuclear Cyano-Bridged CoIII-FeII Complexes as Precursors for Molecular Mixed-Valence Complexes of Higher Nuclearity Paul V. Bernhardt, Fernando Bozoglián, Gabriel González, Manuel Martínez, Brendan P. Macpherson, and Beatriz Sienra pp 74 - 82; DOI: 10.1021/ic0511423 |
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Synthesis, Structure, and Magnetic Behavior of a Series of Trinuclear Schiff Base Complexes of 5f (UIV, ThIV) and 3d (CuII, ZnII) Ions Lionel Salmon, Pierre Thuéry, Eric Rivière, and Michel Ephritikhine pp 83 - 93; DOI: 10.1021/ic0512375 |
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Interaction of 2- and 4-Mercaptopyridine with Pentacyanoferrates and Gold Nanoparticles Fábio Souza Nunes, Leonardo Da Silva Bonifácio, Koiti Araki, and Henrique Eisi Toma pp 94 - 101; DOI: 10.1021/ic0512429 |
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Spectroscopic Characterizations of Bridging Cysteine Ligand Variants of an Engineered Cu2(SCys)2 CuA Azurin Hee Jung Hwang, Nandini Nagraj, and Yi Lu pp 102 - 107; DOI: 10.1021/ic051375u |
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Analysis of Weak Interactions in the Crystal Packing of Inorganic Metalorganic Hybrids Based on Keggin Polyoxometalates and Dinuclear Copper(II)-Acetate Complexes Santiago Reinoso, Pablo Vitoria, Leire San Felices, Luis Lezama, and Juan M. Gutiérrez-Zorrilla pp 108 - 118; DOI: 10.1021/ic051322c |
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A Kinetic Study of the Ring-Opening Process in Tungsten Carbonyl Complexes Containing Hemilabile Metallodithiolate Ligands Andrea L. Phelps, Marilyn V. Rampersad, Shawn B. Fitch, Marcetta Y. Darensbourg, and Donald J. Darensbourg pp 119 - 126; DOI: 10.1021/ic051367d |
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Enhancement of Metal-Metal Coupling at a Considerable Distance by Using 4-Pyridinealdazine as a Bridging Ligand in Polynuclear Complexes of Rhenium and Ruthenium Mauricio Cattaneo, Florencia Fagalde, Néstor E. Katz, Ana María Leiva, and Russell Schmehl pp 127 - 136; DOI: 10.1021/ic051312b |
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Platinum(II) Complexes with Pyridyl Azolate-Based Chelates: Synthesis, Structural Characterization, and Tuning of Photo- and Electrophosphorescence Sheng-Yuan Chang, Jakka Kavitha, Shih-Wen Li, Chan-Shou Hsu, Yun Chi, Yu-Shan Yeh, Pi-Tai Chou, Gene-Hsiang Lee, Arthur J. Carty, Yu-Tai Tao, and Chin-Hsiung Chien pp 137 - 146; DOI: 10.1021/ic051393b |
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Phosphorescent Cu(I) Complexes of 2-(2'-pyridylbenzimidazolyl)benzene: Impact of Phosphine Ancillary Ligands on Electronic and Photophysical Properties of the Cu(I) Complexes Theresa MCormick, Wen-Li Jia, and Suning Wang pp 147 - 155; DOI: 10.1021/ic051412h |
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Syntheses, Structure, and Bonding of Rb14(Mg1-xInx)30. A Nonstoichiometric Phase with an Unusual Substitution in the Anion Framework Bin Li and John D. Corbett pp 156 - 161; DOI: 10.1021/ic0514290 |
Syntheses, Crystal Structures, and Magneto-Structural Correlations of Novel CuII Complexes Containing a Planar [Cu( -L1)]2 (HL1 = 3-(2-Pyridyl)pyrazole) Unit: From Dinuclear to Tetranuclear and Then to One-Dimensional CompoundsTong-Liang Hu, Jian-Rong Li, Chun-Sen Liu, Xue-Song Shi, Jiang-Ning Zhou, Xian-He Bu, and Joan Ribas pp 162 - 173; DOI: 10.1021/ic051488d |
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Assemblies of a New Flexible Multicarboxylate Ligand and d10 Metal Centers toward the Construction of Homochiral Helical Coordination Polymers: Structures, Luminescence, and NLO-Active Properties Shuangquan Zang, Yang Su, Yizhi Li, Zhaoping Ni, and Qingjin Meng pp 174 - 180; DOI: 10.1021/ic051502m |
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The First Acetimino Complexes of Rh(III). 4-Imino-2-methylpentan-2-amino-Rh(III) Complexes through Metal-Assisted Intramolecular Aldol-Type Condensation of Two Acetimino Ligands José Vicente, María-Teresa Chicote, Rita Guerrero, Inmaculada Vicente-Hernández, and Miguel M. Alvarez-Falcón pp 181 - 188; DOI: 10.1021/ic051521w |
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Tuning the Photoinduced O2-Evolving Reactivity of Mn4O47+, Mn4O46+, and Mn4O3(OH)6+ Manganese-Oxo Cubane Complexes Jian-Zhong Wu, Filippo De Angelis, Thomas G. Carrell, Glenn P. A. Yap, John Sheats, Roberto Car, and G. Charles Dismukes pp 189 - 195; DOI: 10.1021/ic051587r |
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New Tetragonal Structure Type for A2Ca10Sb9 (A = Li, Mg). Electronic Variability around a Zintl Phase Ashok K. Ganguli, Shalabh Gupta, and John D. Corbett pp 196 - 200; DOI: 10.1021/ic051536u |
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Facilitating Access to the Most Easily Ionized Molecule: an Improved Synthesis of the Key Intermediate, W2(hpp)4Cl2, and Related Compounds F. Albert Cotton, James P. Donahue, Nadine E. Gruhn, Dennis L. Lichtenberger, Carlos A. Murillo, Daren J. Timmons, Laura O. Van Dorn, Dino Villagrán, and Xiaoping Wang pp 201 - 213; DOI: 10.1021/ic0515709 |
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Octahedral and Tetrahedral Coinage Metal Clusters: Is Three-Dimensional d-Orbital Aromaticity Viable? Clémence Corminboeuf, Chaitanya S. Wannere, Debjani Roy, R. Bruce King, and Paul v. R. Schleyer pp 214 - 219; DOI: 10.1021/ic051576y |
Synthesis, Characterization, Sintering, and Leaching of  -TUPD/Monazite Radwaste MatricesN. Clavier, N. Dacheux, and R. Podor pp 220 - 229; DOI: 10.1021/ic051607p |
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DNA Interaction of Platinum(II) Complexes with 1,10-Phenanthroline and Extended Phenanthrolines Matteo Cusumano, Maria Letizia Di Pietro, and Antonino Giannetto pp 230 - 235; DOI: 10.1021/ic050880o |
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Synthesis and Characterization of Prussian Blue Analogues Incorporating the Edge-Bridged Octahedral [Zr6BCl12]2+ Cluster Core Laurance G. Beauvais and Jeffrey R. Long pp 236 - 243; DOI: 10.1021/ic051087y |
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Synthesis and Physicochemical Characterization of Two Gadolinium(III) TTDA-like Complexes and Their Interaction with Human Serum Albumin Ming-Hung Ou, Chien-Hung Tu, Su-Ching Tsai, Wei-Thung Lee, Gin-Chung Liu, and Yun-Ming Wang pp 244 - 254; DOI: 10.1021/ic050329r |
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Self-Assembly of a Tetranuclear Ni4 Cluster with an S = 4 Ground State: The First 3d Metal Cluster Bearing a 4-2:2-O,O Carbonate Ligand Matilde Fondo, Noelia Ocampo, Ana M. García-Deibe, Ramón Vicente, Montserrat Corbella, Manuel R. Bermejo, and Jesús Sanmartín pp 255 - 262; DOI: 10.1021/ic051194s |
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Synthesis and Structural Investigation of Tungsten Imido Amidinate and Guanidinate Complexes Corey B. Wilder, Laurel L. Reitfort, Khalil A. Abboud, and Lisa McElwee-White pp 263 - 268; DOI: 10.1021/ic051497m |
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Mixed Guanidinato/Alkylimido/Azido Tungsten(VI) Complexes: Synthesis and Structural Characterization Daniel Rische, Arne Baunemann, Manuela Winter, and Roland A. Fischer pp 269 - 277; DOI: 10.1021/ic0512431 |
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Closomers of High Boron Content: Synthesis, Characterization, and Potential Application as Unimolecular Nanoparticle Delivery Vehicles for Boron Neutron Capture Therapy Ling Ma, Julie Hamdi, Francis Wong, and M. Frederick Hawthorne pp 278 - 285; DOI: 10.1021/ic051214q |
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3,5-Dimethyl and 3,5-Di-tert-butylpyrazolato Complexes with Alkali Metals: Monomeric, Dimeric, Cluster, and 1D Chain Structures Sara-Ángelica Cortés-Llamas, Ramón Hernández-Lamoneda, Miguel-Ángel Velázquez-Carmona, Miguel-Angel Muñoz-Hernández, and Rubén A. Toscano pp 286 - 294; DOI: 10.1021/ic051294y |
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Self-Assembly, Reorganization, and Photophysical Properties of Silver(I)-Schiff-Base Molecular Rectangle and Polymeric Array Species Huang-Chun Wu, P. Thanasekaran, Chi-Hwe Tsai, Jing-Yun Wu, Sheng-Ming Huang, Yuh-Sheng Wen, and Kuang-Lieh Lu pp 295 - 303; DOI: 10.1021/ic051235k |
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Synthesis of a Large Amino-Phenolic Cage. Synthesis, Crystal Structures, and Acid-Base and Coordination Behavior toward Cations and Anions Gianluca Ambrosi, Paolo Dapporto, Mauro Formica, Vieri Fusi, Luca Giorgi, Annalisa Guerri, Mauro Micheloni, Paola Paoli, Roberto Pontellini, and Patrizia Rossi pp 304 - 314; DOI: 10.1021/ic051304v |
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Kinetics and Mechanism of the Oxidation of Hydroquinones by a trans-Dioxoruthenium(VI) Complex William W. Y. Lam, Mendy F. W. Lee, and Tai-Chu Lau pp 315 - 321; DOI: 10.1021/ic051382i |
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Synthesis of a One-Dimensional Metal-Dimer Assembled System with Interdimer Interaction, M2(dtp)4 (M = Ni, Pd; dtp = Dithiopropionato) Atsushi Kobayashi, Takahiko Kojima, Ryuichi Ikeda, and Hiroshi Kitagawa pp 322 - 327; DOI: 10.1021/ic051387f |
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Phosphato, Chromato, and Perrhenato Complexes of Titanium(IV) and Zirconium(IV) Containing Kläui's Tripodal Ligand Xiao-Yi Yi, Qian-Feng Zhang, Tony C. H. Lam, Eddie Y. Y. Chan, Ian D. Williams, and Wa-Hung Leung pp 328 - 335; DOI: 10.1021/ic051329u |
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Synthesis and Structural Characterization of Symmetrical closo-4,7-I2-1,2-C2B10H10 and [(CH3)3NH][nido-2,4-I2-7,8-C2B9H10] Bhaskar M. Ramachandran, Carolyn B. Knobler, and M. Frederick Hawthorne pp 336 - 340; DOI: 10.1021/ic051395w |
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Rearrangement of Molybdocene Tetraoxotetrasulfide Cp2MoS4O4 to Give [(Cp2MoS2H)2](HSO4)2: A Novel Proton-Stabilized Molybdocene Disulfide Dimer Andrzej Z. Rys, Anne-Marie Lebuis, and Alan Shaver pp 341 - 344; DOI: 10.1021/ic051332d |
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An Unusual Ligand in Copper Chemistry: Coordination Oligomers and Polymers Containing the [{CpMo(CO)2}2(,2-Sb2)] Cluster Hanh V. Ly, Masood Parvez, and Roland Roesler pp 345 - 351; DOI: 10.1021/ic051406l |
 -Acid/-Base Carbonyloxo, Carbonylsulfido, and Mixed-Valence Complexes of TungstenSimon Thomas, Edward R. T. Tiekink, and Charles G. Young pp 352 - 361; DOI: 10.1021/ic051456q |
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Static and Dynamic Quenching of Ru(II) Polypyridyl Excited States by Iodide Andras Marton, Christopher C. Clark, Ramya Srinivasan, Robert E. Freundlich, Amy A. Narducci Sarjeant, and Gerald J. Meyer pp 362 - 369; DOI: 10.1021/ic051467j |
Synthesis and Characterization of Ruthenacarborane Complexes Incorporating Chelating N-Donor Ligands: Unexpected Luminescence from the Complex [3-CO-3,3-{ 2-Me2N(CH2)2NMe2}-closo-3,1,2-RuC2B9H11]Paul A. Jelliss, Justin Mason, Jamie M. Nazzoli, Justin H. Orlando, Albert Vinson, Nigam P. Rath, and Michael J. Shaw pp 370 - 385; DOI: 10.1021/ic051463e |
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Synthesis and Full Characterization of Molybdenum and Antimony Corroles and Utilization of the Latter Complexes as Very Efficient Catalysts for Highly Selective Aerobic Oxygenation Reactions Inna Luobeznova, Marina Raizman, Israel Goldberg, and Zeev Gross pp 386 - 394; DOI: 10.1021/ic051483g |
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Low-Valent Low-Coordinated Manganese(I) Ion Dimer: A Temperature Dependent W-Band EPR Study Lorenzo Sorace, Christian Golze, Dante Gatteschi, Alessandro Bencini, Herbert W. Roesky, Jianfang Chai, and A. Claudia Stückl pp 395 - 400; DOI: 10.1021/ic051496u |
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Linear-Type S-Bridged Triruthenium Complexes with Aliphatic Aminothiolate Ligands: Synthesis, Characterization, and Properties Noriyuki Matsuura, Asako Igashira-Kamiyama, Tatsuya Kawamoto, and Takumi Konno pp 401 - 408; DOI: 10.1021/ic0515002 |
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Synthesis and Characterization of Novel Oxo-Centered Phosphanylzincates of Potassium and Cesium with a Central Zn6O2P4 Double-Heterocubane Cage Matthias Westerhausen, Gerhard Sapelza, Helmar Görls, and Peter Mayer pp 409 - 414; DOI: 10.1021/ic0515195 |
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Layered Single-Metal Hydroxide/Ethylene Glycol as a New Class of Hybrid Material Asayo Kasai and Shinobu Fujihara pp 415 - 418; DOI: 10.1021/ic051528d |
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Two New Structurally Related Strontium Gallium Nitrides: Sr4GaN3O and Sr4GaN3(CN2) Phillip M. Mallinson, Zoltán A. Gál, and Simon J. Clarke pp 419 - 423; DOI: 10.1021/ic051542q |
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Synthesis of (O2CEPh)1- Ligands (E = S, Se) by CO2 Insertion into Lanthanide Chalcogen Bonds and Their Utility in Forming Crystallographically Characterizable Organoaluminum Complexes [Me2Al(-O2CEPh)]2 William J. Evans, Kevin A. Miller, and Joseph W. Ziller pp 424 - 429; DOI: 10.1021/ic0515610 |
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Platinum-Osmium Cluster Complexes from the Addition of Pt(PBut3) Groups to Os3(CO)12 Richard D. Adams, Burjor Captain, and Lei Zhu pp 430 - 436; DOI: 10.1021/ic0515507 |
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New Signal Processing Method for the Faster Observation of Natural-Abundance 15N NMR Spectra and Its Application to N5+ Sharif D. Kunikeev, Howard S. Taylor, Thorsten Schroer, Ralf Haiges, C. J. Bigler Jones, and Karl O. Christe pp 437 - 442; DOI: 10.1021/ic051705a |
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An Octanuclear Complex Containing the {Fe3O}7+ Metal Core: Structural, Magnetic, Mössbauer, and Electron Paramagnetic Resonance Studies Athanassios K. Boudalis, Yiannis Sanakis, Françoise Dahan, Michael Hendrich, and Jean-Pierre Tuchagues pp 443 - 453; DOI: 10.1021/ic051652x |
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Synthesis, Characterization, and Electrochemical Studies on [1.1]Ferrocenophanes Containing Aluminum, Gallium, and Indium Jörg A. Schachner, Grzegorz A. Orlowski, J. Wilson Quail, Heinz-Bernhard Kraatz, and Jens Müller pp 454 - 459; DOI: 10.1021/ic051616y |
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Ruthenium Mediated C-H Activation of 2-(Arylazo)phenols: Characterization of an Intermediate and the Final Organoruthenium Complex Parna Gupta, Swati Dutta, Falguni Basuli, Shie-Ming Peng, Gene-Hsiang Lee, and Samaresh Bhattacharya pp 460 - 467; DOI: 10.1021/ic051874v |
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Cover Art Correction pp 468 - 468; DOI: 10.1021/ic058011m |
Issue 2
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Improved Synthetic Route to n-B18H22 Yuqi Li and Larry G. Sneddon pp 470 - 471; DOI: 10.1021/ic051712z |
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De Novo Design and Spectroscopic Characterization of a Dinucleating Copper-Binding Pentadecapeptide David A. Rockcliffe, Arthur Cammers, Ayaluru Murali, William K. Russell, and Victoria J. DeRose pp 472 - 474; DOI: 10.1021/ic051577q |
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First Structural Determination of a Trivalent Californium Compound with Oxygen Coordination Richard E. Sykora, Zerihun Assefa, Richard G. Haire, and Thomas E. Albrecht-Schmitt pp 475 - 477; DOI: 10.1021/ic051667v |
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Phosphonium-Borate Zwitterions, Anionic Phosphines, and Dianionic Phosphonium-Dialkoxides via Tetrahydrofuran Ring-Opening Reactions Gregory C. Welch, Jason D. Masuda, and Douglas W. Stephan pp 478 - 480; DOI: 10.1021/ic051713r |
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First 3D Pr(III)-Ni(II)-Na(I) Polymer and A 3D Pr(III) Open Network Based on Pyridine-2,4,6-tricarboxylic Acid Hong-Ling Gao, Long Yi, Bin Ding, Hong-Sheng Wang, Peng Cheng, Dai-Zheng Liao, and Shi-Ping Yan pp 481 - 483; DOI: 10.1021/ic051707v |
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Constitutional Self-Selection of [2 × 2] Homonuclear Grids from a Dynamic Mixture of Copper(I) and Silver(I) Metal Complexes Mihail Barboiu, Eddy Petit, Arie van der Lee, and Gavin Vaughan pp 484 - 486; DOI: 10.1021/ic0517220 |
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Aryl Isocyanate, Carbodiimide, and Isocyanide Prepared from Carbon Dioxide. A Metathetical Group-Transfer Tale Involving a Titanium-Imide Zwitterion Uriah J. Kilgore, Falguni Basuli, John C. Huffman, and Daniel J. Mindiola pp 487 - 489; DOI: 10.1021/ic052065e |
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Recognition of Secondary Structures in Proteins by a Diiron(III) Complex via a Hydrolytic Pathway Qunhui Pan, Wei Jiang, Zhanru Liao, Tianle Zhang, and Changlin Liu pp 490 - 492; DOI: 10.1021/ic050695a |
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High-Resolution EXAFS of the Active Site of Human Sulfite Oxidase: Comparison with Density Functional Theory and X-ray Crystallographic Results Hugh H. Harris, Graham N. George, and K. V. Rajagopalan pp 493 - 495; DOI: 10.1021/ic0512274 |
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Copper Complexes of Thiosemicarbazone-Pyridylhydrazine (THYNIC) Hybrid Ligands: A New Versatile Potential Bifunctional Chelator for Copper Radiopharmaceuticals Andrew R. Cowley, Jonathan R. Dilworth, Paul S. Donnelly, and Jonathan M. White pp 496 - 498; DOI: 10.1021/ic0514492 |
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The Central Role of Metal Coordination in Selenium Antioxidant Activity Erin E. Battin, Nathan R. Perron, and Julia L. Brumaghim pp 499 - 501; DOI: 10.1021/ic051594f |
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Novel Phosphoranido Complex of Rhodium(III) Tetraphenylporphyrin. Synthesis and Characterization Kazumasa Kajiyama, Takeshi K. Miyamoto, and Kaita Sawano pp 502 - 504; DOI: 10.1021/ic051655+ |
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Unique Asymmetric (CuII4) Double-Stranded Helicate from a Hexadentate Piperazine-Based Ligand: Ligand Conformation Isomerism upon Coordination Alok Ranjan Paital, Prasant Kumar Nanda, Sunirban Das, Guillem Aromí, and Debashis Ray pp 505 - 507; DOI: 10.1021/ic051455y |
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Facile Light-Triggered One-Step Synthesis of Small and Stable Platinum Nanoparticles in an Aqueous Medium from a -Cyclodextrin Host-Guest Inclusion Complex Salvatore Giuffrida, Giorgio Ventimiglia, Salvatore Petralia, Sabrina Conoci, and Salvatore Sortino pp 508 - 510; DOI: 10.1021/ic0517366 |
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Combining Hard and Soft Donors in Early-Transition-Metal Olefin Polymerization Catalysts Richard J. Long, Vernon C. Gibson, Andrew J. P. White, and David J. Williams pp 511 - 513; DOI: 10.1021/ic0517927 |
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Structure of Mg2.56V1.12W0.88O8 and Vibrational Raman Spectra of Mg2.5VWO8 and Mg2.5VMoO8 Jason D. Pless, Hack-Sung Kim, Jared P. Smit, Xiandong Wang, Peter C. Stair, and Kenneth R. Poeppelmeier pp 514 - 520; DOI: 10.1021/ic051740h |
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Probing the Vanadyl and Molybdenyl Bonds in Complex Vanadomolybdate Structures Jared P. Smit, Hack-Sung Kim, Jason D. Pless, Peter C. Stair, and Kenneth R. Poeppelmeier pp 521 - 528; DOI: 10.1021/ic051741+ |
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Fast Magnetization Tunneling in Tetranickel(II) Single-Molecule Magnets En-Che Yang, Wolfgang Wernsdorfer, Lev N. Zakharov, Yoshitomo Karaki, Akira Yamaguchi, Rose M. Isidro, Guo-Di Lu, Samuel A. Wilson, Arnold L. Rheingold, Hidehiko Ishimoto, and David N. Hendrickson pp 529 - 546; DOI: 10.1021/ic050093r |
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Tuning the Electronic Communication and Rates of Intramolecular Electron Transfer of Dimers of Trinuclear Ruthenium Clusters: Bridging and Ancillary Ligand Effects J. Catherine Salsman, Silvia Ronco, Casey H. Londergan, and Clifford P. Kubiak pp 547 - 554; DOI: 10.1021/ic050737v |
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6-Methylpyridyl for Pyridyl Substitution Tunes the Properties of Fluorescent Zinc Sensors of the Zinpyr Family Christian R. Goldsmith and Stephen J. Lippard pp 555 - 561; DOI: 10.1021/ic051113s |
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Mononuclear to Polynuclear Transition Induced by Ligand Coordination: Synthesis, X-ray Structure, and Properties of Mono-, Di-, and Polynuclear Copper(II) Complexes of Pyridyl-Containing Azo Ligands Srijit Das, Priyabrata Banerjee, Shie-Ming Peng, Gene-Hsiang Lee, Jinkwon Kim, and Sreebrata Goswami pp 562 - 570; DOI: 10.1021/ic051029c |
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Investigation of Group 12 Metal Complexes with a Tridentate SNS Ligand by X-ray Crystallography and 1H NMR Spectroscopy Wei Lai, Steven M. Berry, Deborah C. Bebout, and Raymond J. Butcher pp 571 - 581; DOI: 10.1021/ic051091+ |
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Syntheses, Structures, and Magnetic Properties of Cyano-Bridged Heterobimetallic Complexes Based on [Fe(bpca)(CN)3]- He-Rui Wen, Cai-Feng Wang, Jing-Lin Zuo, You Song, Xi-Rui Zeng, and Xiao-Zeng You pp 582 - 590; DOI: 10.1021/ic0511468 |
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Supramolecular Assembly of Gold(I) Complexes of Diphosphines and N,N'-Bis-4-methylpyridyl Oxalamide Biing-Chiau Tzeng, Hsien-Te Yeh, Ya-Ling Wu, Jau-Huei Kuo, Gene-Hsiang Lee, and Shie-Ming Peng pp 591 - 598; DOI: 10.1021/ic051297a |
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Syntheses, Structures, and Magnetic Properties of Inorganic-Organic Hybrid Cobalt(II) Phosphites Containing Bifunctional Ligands Jian Fan, Gordon T. Yee, Guangbin Wang, and Brian E. Hanson pp 599 - 608; DOI: 10.1021/ic051286h |
Aggregation of [(tBu3SiS)MX]: Structures of {[Br2Fe(-SSitBu3)2FeBr(THF)]Na(THF)4} , cis-[(THF)FeI]2(-SSitBu3)2, [(tBu3SiS)Fe]2(-SSitBu3)2, and Comparative Structure and Magnetism Studies of [(tBu3SiS)MX]n (M = Fe, Co, X = Cl, n = 12; M = Fe, Ni, X = Br, n = 12; M = Fe, X = I, n = 14)Orson L. Sydora, Thomas P. Henry, Peter T. Wolczanski, Emil B. Lobkovsky, Evan Rumberger, and David N. Hendrickson pp 609 - 626; DOI: 10.1021/ic051289u |
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On the Flexibility of the Structural Framework of Cubic LAMOX Compounds, in Relationship with Their Anionic Conduction Properties Philippe Lacorre, Ania Selmi, Gwenaël Corbel, and Brigitte Boulard pp 627 - 635; DOI: 10.1021/ic0513080 |
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Syntheses and Structures of Dinuclear Double-Stranded Helicates of Divalent Manganese, Iron, Cobalt, and Zinc Stuart D. Reid, Alexander J. Blake, Claire Wilson, and Jason B. Love pp 636 - 643; DOI: 10.1021/ic051433b |
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Novel Example of a Chain Structure Formed by 1,4-Dioxane and Cobalt(II) Links. Chain [Co3(-OOCCF3)4(-H2O)2(OOCCF3)2(H2O)2(C4H8O2)]·2C4H8O2 Víctor Calvo-Pérez, Sergei Ostrovsky, Andrés Vega, Juraj Pelikan, Evgenia Spodine, and Wolfgang Haase pp 644 - 649; DOI: 10.1021/ic051361o |
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Homochiral and Heterochiral Coordination Polymers and Networks of Silver(I) Tara J. Burchell and Richard J. Puddephatt pp 650 - 659; DOI: 10.1021/ic051365t |
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(Strept)avidin as Host for Biotinylated Coordination Complexes: Stability, Chiral Discrimination, and Cooperativity Andreas Loosli, Untung Edy Rusbandi, Julieta Gradinaru, Klaus Bernauer, Carl Wilhelm Schlaepfer, Michel Meyer, Sylwester Mazurek, Marjana Novic, and Thomas R. Ward pp 660 - 668; DOI: 10.1021/ic051405t |
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Reactions of (CF3)3BCO with Amines and Phosphines Maik Finze, Eduard Bernhardt, Helge Willner, and Christian W. Lehmann pp 669 - 678; DOI: 10.1021/ic0515305 |
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MS2(Me2PC2H4PMe2)2 (M = Mo, W): Acid-Base Properties, Proton Transfer, and Reversible Protonolysis of Sulfido Ligands Steven J. Smith, C. Matthew Whaley, Thomas B. Rauchfuss, and Scott R. Wilson pp 679 - 687; DOI: 10.1021/ic051443c |
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Orbital Angular Momentum Contribution to the Magneto-Optical Behavior of a Binuclear Cobalt(II) Complex S. M. Ostrovsky, K. Falk, J. Pelikan, D. A. Brown, Z. Tomkowicz, and W. Haase pp 688 - 694; DOI: 10.1021/ic0514748 |
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A New Family of Ruthenium(II) Polypyridine Complexes Bearing 5-Aryltetrazolate Ligands as Systems for Electrochemiluminescent Devices Stefano Stagni, Antonio Palazzi, Stefano Zacchini, Barbara Ballarin, Carlo Bruno, Massimo Marcaccio, Francesco Paolucci, Magda Monari, Maurizio Carano, and Allen J. Bard pp 695 - 709; DOI: 10.1021/ic0514905 |
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E2(CN)2 (E = S, Se) and Related Compounds Colin J. Burchell, Petr Kilian, Alexandra M. Z. Slawin, J. Derek Woollins, Karla Tersago, Christian Van Alsenoy, and Frank Blockhuys pp 710 - 716; DOI: 10.1021/ic0515103 |
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[Cd2(Te6O13)][Cd2Cl6] and Cd7Cl8(Te7O17): Novel Tellurium(IV) Oxide Slabs and Unusual Cadmium Chloride Architectures Hai-Long Jiang and Jiang-Gao Mao pp 717 - 721; DOI: 10.1021/ic051703q |
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Large Gas-Solid Structural Differences in Complexes of Haloacetonitriles with Boron Trifluoride James A. Phillips, Jason A. Halfen, John P. Wrass, Christopher C. Knutson, and Christopher J. Cramer pp 722 - 731; DOI: 10.1021/ic051491x |
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Stable 8-Hydroxyquinolinate-Based Podates as Efficient Sensitizers of Lanthanide Near-Infrared Luminescence Steve Comby, Daniel Imbert, Anne-Sophie Chauvin, and Jean-Claude G. Bünzli pp 732 - 743; DOI: 10.1021/ic0515249 |
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Unligated Diruthenium(II,II) Tetra(trifluoroacetate): The First X-ray Structural Study, Thermal Compressibility, Lewis Acidity, and Magnetism Evgeny V. Dikarev, Alexander S. Filatov, Rodolphe Clérac, and Marina A. Petrukhina pp 744 - 751; DOI: 10.1021/ic051537m |
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Complexes of Cytotoxic Chelators from the Dipyridyl Ketone Isonicotinoyl Hydrazone (HPKIH) Analogues Paul V. Bernhardt, Johan Mattsson, and Des R. Richardson pp 752 - 760; DOI: 10.1021/ic051573l |
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Tetrakis(dimethyltin)-Containing Tungstophosphate [{Sn(CH3)2}4(H2P4W24O92)2]28-: First Evidence for a Lacunary Preyssler Ion Firasat Hussain, Ulrich Kortz, Bineta Keita, Louis Nadjo, and Michael T. Pope pp 761 - 766; DOI: 10.1021/ic051990y |
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Strong Electronic Interaction between Two Dimolybdenum Units Linked by a Tetraazatetracene F. Albert Cotton, Zhong Li, Chun Y. Liu, Carlos A. Murillo, and Dino Villagrán pp 767 - 778; DOI: 10.1021/ic051614d |
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Luminescence Detection of Transition and Heavy Metals by Inversion of Excited States: Synthesis, Spectroscopy, and X-ray Crystallography of Ca, Mn, Pb, and Zn Complexes of 1,8-Anthraquinone-18-Crown-5 Mariappan Kadarkaraisamy and Andrew G. Sykes pp 779 - 786; DOI: 10.1021/ic051672z |
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DFT-INDO/S Modeling of New High Molar Extinction Coefficient Charge-Transfer Sensitizers for Solar Cell Applications Mohammad K. Nazeeruddin, Qing Wang, Le Cevey, Viviane Aranyos, Paul Liska, Egbert Figgemeier, Cedric Klein, Narukuni Hirata, Sara Koops, Saif A. Haque, James R. Durrant, Anders Hagfeldt, A. B. P. Lever, and Michael Grätzel pp 787 - 797; DOI: 10.1021/ic051727x |
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Syntheses and Structures of Strontium, Barium, and Europium Bis(diphosphanylamido) Complexes Peter W. Roesky pp 798 - 802; DOI: 10.1021/ic051738q |
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Quantum Chemistry Predicts Multiply Bonded Diuranium Compounds to Be Stable Björn O. Roos and Laura Gagliardi pp 803 - 807; DOI: 10.1021/ic051665a |
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Thermal Aqueous Solution Approach for the Synthesis of Triangular and Hexagonal Gold Nanoplates with Three Different Size Ranges Hsin-Cheng Chu, Chun-Hong Kuo, and Michael H. Huang pp 808 - 813; DOI: 10.1021/ic051758s |
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Aqueous Ferryl(IV) Ion: Kinetics of Oxygen Atom Transfer To Substrates and Oxo Exchange with Solvent Water Oleg Pestovsky and Andreja Bakac pp 814 - 820; DOI: 10.1021/ic051868z |
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Structure and Properties of Dinuclear [RuII([n]aneS4)] Complexes of 3,6-Bis(2-pyridyl)-1,2,4,5-tetrazine Mike Newell, James D. Ingram, Timothy L. Easun, Steven J. Vickers, Harry Adams, Michael D. Ward, and Jim A. Thomas pp 821 - 827; DOI: 10.1021/ic051151b |
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Synthesis, Characterization, and Preliminary Oxygenation Studies of Benzyl- and Ethyl-Substituted Pyridine Ligands of Carboxylate-Rich Diiron(II) Complexes Emily C. Carson and Stephen J. Lippard pp 828 - 836; DOI: 10.1021/ic051471v |
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Dioxygen-Initiated Oxidation of Heteroatomic Substrates Incorporated into Ancillary Pyridine Ligands of Carboxylate-Rich Diiron(II) Complexes Emily C. Carson and Stephen J. Lippard pp 837 - 848; DOI: 10.1021/ic051476s |
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Metal-Metal Interactions in Thallium(I)/Platinum(II) Compounds Involving a Chelating Dicarbene and Various Auxiliary Ligands Jay R. Stork, Marilyn M. Olmstead, James C. Fettinger, and Alan L. Balch pp 849 - 857; DOI: 10.1021/ic051252+ |
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The Effect of the Diphosphine Basicity on the Excited-State Properties of trans-(N2)2W(R2PCH2CH2PR2)2: Identification of Near-Degenerate, Luminescent 3MLCT and 3LF Terms B. L. Nordwig, D. J. Ohlsen, K. D. Beyer, A. S. Wruck, and J. G. Brummer pp 858 - 867; DOI: 10.1021/ic051360w |
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Five New Manganese--Azido 2D Compounds Synthesized in Aqueous Hydrazoic Acid from Pyrazine Derivatives Brigitte Bitschnau, Andreas Egger, Albert Escuer, Franz A. Mautner, Beate Sodin, and Ramon Vicente pp 868 - 876; DOI: 10.1021/ic051258z |
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A Windmill-Shaped Hexacopper(II) Molecule Built Up by Template Core-Controlled Expansion of Diaquatetrakis(2-adeninato-N3,N9)dicopper(II) with Aqua(oxydiacetato)copper(II) Josefa María González-Pérez, Carolina Alarcón-Payer, Alfonso Castiñeiras, Tiziana Pivetta, Luis Lezama, Duane Choquesillo-Lazarte, Guido Crisponi, and Juan Niclós-Gutiérrez pp 877 - 882; DOI: 10.1021/ic051965s |
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Synthesis and Crystal and Electronic Structures of the Na2(Sc4Nb2)(Nb6O12)3 Octahedral Niobium Cluster Oxide. Structural Correlations between AnBM6L12(Z) Series and Chevrel Phases Stéphane Cordier, Kaplan Kirakci, Bruno Fontaine, Jean-François Halet, Régis Gautier, and Christiane Perrin pp 883 - 893; DOI: 10.1021/ic0512678 |
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O-Atom-Transfer Oxidation of [Molybdenum(IV) Oxo{3,6-(acylamino)2-1,2-benzenedithiolato}2]2- Promoted by Intramolecular NH···S Hydrogen Bonds Koji Baba, Taka-aki Okamura, Chie Suzuki, Hitoshi Yamamoto, Tetsuo Yamamoto, Mitsuo Ohama, and Norikazu Ueyama pp 894 - 901; DOI: 10.1021/ic051493h |
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Oxorhenium(V) and Oxotechnetium(V) [NN][S]3 Complexes of 2-Phenylbenzothiazole Derivatives Stamatia Tzanopoulou, Ioannis C. Pirmettis, Georgios Patsis, Catherine Raptopoulou, Aris Terzis, Minas Papadopoulos, and Maria Pelecanou pp 902 - 909; DOI: 10.1021/ic051538e |
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Yttrium and Lanthanide Complexes Having a Chiral Phosphanylamide in the Coordination Sphere Tarun K. Panda, Michael T. Gamer, and Peter W. Roesky pp 910 - 916; DOI: 10.1021/ic051584e |
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Design of a New Family of Inorganic Compounds Ae2F2SnX3 (Ae = Sr, Ba; X = S, Se) Using Rock Salt and Fluorite 2D Building Blocks Houria Kabbour, Laurent Cario, Michel Danot, and Alain Meerschaut pp 917 - 922; DOI: 10.1021/ic051592v |
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Effect of Constrained Donor Atom Orientations on the Stabilities, Complexation Kinetics, Redox Potentials, and Structures of Macrocyclic Polythiaether Complexes. Copper(II) Complexes with Cyclopentanediyl Derivatives of [14]aneS4 in 80% Methanol Safaa H. Kakos, Luke T. Dressel, Jeffery D. Bushendorf, Casimir P. Kotarba, Prabodha Wijetunge, Chandrika P. Kulatilleke, Michael P. McGillivary, Gezahegn Chaka, Mary Jane Heeg, L. A. Ochrymowycz, and D. B. Rorabacher pp 923 - 934; DOI: 10.1021/ic051670e |
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Variability in the Structures of [4-(Aminomethyl)pyridine]silver(I) Complexes through Effects of Ligand Ratio, Anion, Hydrogen Bonding, and -Stacking Rodney P. Feazell, Cody E. Carson, and Kevin K. Klausmeyer pp 935 - 944; DOI: 10.1021/ic051659e |
Issue 3
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La9RbIr4O24: A Rubidium-Containing Oxide with a New Structure Type Samuel J. Mugavero III, Mark D. Smith, and Hans-Conrad zur Loye pp 946 - 948; DOI: 10.1021/ic051890s |
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Synthesis, Characterization, and X-ray Crystal Structure of a Gallium Monohydroxide and a Hetero-bimetallic Gallium Zirconium Oxide Sanjay Singh, Vojtech Jancik, Herbert W. Roesky, and Regine Herbst-Irmer pp 949 - 951; DOI: 10.1021/ic051769l |
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Exo-Coordination-Based Supramolecular Silver(I) Complexes of S2O Macrocycles: Effect of Ligand Isomerism on the Structural Diversity Joobeom Seo, Mi Ryoung Song, Ji-Eun Lee, So Young Lee, Il Yoon, Ki-Min Park, Jineun Kim, Jong Hwa Jung, Sung Bae Park, and Shim Sung Lee pp 952 - 954; DOI: 10.1021/ic051764o |
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Structural and Electronic Behavior of Unprecedented Five-Coordinate Iron(III) and Gallium(III) Complexes with a New Phenol-Rich Electroactive Ligand Mauricio Lanznaster, Hrant P. Hratchian, Mary Jane Heeg, Lew M. Hryhorczuk, Bruce R. McGarvey, H. Bernhard Schlegel, and Claudio N. Verani pp 955 - 957; DOI: 10.1021/ic050809i |
Relative Energies of  and Isomers of Keggin DodecatungstogallateKarthik M. Sundaram, Wade A. Neiwert, Craig L. Hill, and Ira A. Weinstock pp 958 - 960; DOI: 10.1021/ic051789n |
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FeIII-Binding Collagen Mimetics Garth A. Kinberger, Joseph P. Taulane, and Murray Goodman pp 961 - 963; DOI: 10.1021/ic0520059 |
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Thioamide Pincer Ligands with Charge Versatility Rowshan Ara Begum, Douglas Powell, and Kristin Bowman-James pp 964 - 966; DOI: 10.1021/ic051775h |
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Understanding the Origin of Metal-Sulfur Vibrations in an Oxo-Molybdenum Dithiolene Complex: Relevance to Sulfite Oxidase Frank E. Inscore, Sushilla Z. Knottenbelt, Nick D. Rubie, Hemant K. Joshi, Martin L. Kirk, and John H. Enemark pp 967 - 976; DOI: 10.1021/ic0506815 |
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Rational Design and Synthesis of Porous Organic-Inorganic Hybrid Frameworks Constructed by 1,3,5-Benzenetriphosphonic Acid and Pyridine Synthons Deyuan Kong, Jerzy Zoñ, Jennifer McBee, and Abraham Clearfield pp 977 - 986; DOI: 10.1021/ic0509377 |
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Crown Bowl: Metallocyclophane by Self-Assembly of 4'-Pyridylmethyl-Armed 12-Crown-4 Ethers with Ag+ Ions Yoichi Habata, Sachiko Yamada, and Futoshi Osaka pp 987 - 991; DOI: 10.1021/ic051047u |
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Synthesis and Redox Properties of Crowded Triarylphosphines Possessing Ferrocenyl Groups Katsuhide Sutoh, Shigeru Sasaki, and Masaaki Yoshifuji pp 992 - 998; DOI: 10.1021/ic051038l |
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Tuning the Magnetic Behavior via Dehydration/Hydration Treatment of a New Ferrimagnet with the Composition of K0.2Mn1.4Cr(CN)6·6H2O Zhengliang Lü, Xinyi Wang, Zhiliang Liu, Fuhui Liao, Song Gao, Rengen Xiong, Hongwei Ma, Deqing Zhang, and Daoben Zhu pp 999 - 1004; DOI: 10.1021/ic051145f |
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Electronic Effects of Electron-Donating and -Withdrawing Groups in Model Complexes for Iron-Tyrosine-Containing Metalloenzymes Mauricio Lanznaster, Ademir Neves, Adailton J. Bortoluzzi, Aline M. C. Assumpção, Ivo Vencato, Sergio P. Machado, and Sueli M. Drechsel pp 1005 - 1011; DOI: 10.1021/ic050869o |
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Malonate-Containing Manganese(III) Complexes: Synthesis, Crystal Structure, and Magnetic Properties of AsPh4[Mn(mal)2(H2O)2] Fernando S. Delgado, Nicolas Kerbellec, Catalina Ruiz-Pérez, Joan Cano, Francesc Lloret, and Miguel Julve pp 1012 - 1020; DOI: 10.1021/ic0508526 |
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Influence of Lattice Interactions on the Jahn-Teller Distortion of the [Cu(H2O)6]2+ Ion: Dependence of the Crystal Structure of K2[Cu(H2O)6](SO4)2x(SeO4)2-2x upon the Sulfate/Selenate Ratio Charles J. Simmons, Horst Stratemeier, Michael A. Hitchman, and Mark J. Riley pp 1021 - 1031; DOI: 10.1021/ic050790j |
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Three-Dimensional Nets from Star-Shaped Hexakis(arylthio)triphenylene Molecules and Silver(I) Salts Kunhao Li, Zhengtao Xu, Hanhui Xu, Patrick J. Carroll, and James C. Fettinger pp 1032 - 1037; DOI: 10.1021/ic051135e |
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Coordination of XeF2 to Calcium and Cadmium Hexafluorophosphates(V) Tina Buni  , Ga per Tavar, Melita Tramek, and Boris  emvapp 1038 - 1042; DOI: 10.1021/ic051083t |
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Solid-State Structural Characterization of a Rigid Framework of Lacunary Heteropolyniobates May Nyman, Aaron J. Celestian, John B. Parise, Gregory P. Holland, and Todd M. Alam pp 1043 - 1052; DOI: 10.1021/ic051155g |
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Kinetics of the Reaction of Chromium(VI) with Tris(1,10-phenanthroline)iron(II) Ions in Acidic Solutions. Anion and Medium Effects: Perchlorate versus Triflate Guodong Du and James H. Espenson pp 1053 - 1058; DOI: 10.1021/ic0511524 |
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Synthesis, Structural Characterization, and Theoretical Studies of Gold(I) and Gold(I)-Gold(III) Thiolate Complexes: Quenching of Gold(I) Thiolate Luminescence Manuel Bardají, Maria José Calhorda, Paulo J. Costa, Peter G. Jones, Antonio Laguna, M. Reyes Pérez, and M. D. Villacampa pp 1059 - 1068; DOI: 10.1021/ic051168u |
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Supramolecular Assemblies with Calix[6]arenes and Copper Ions: from Dinuclear to Trinuclear Linear Arrangements of Hydroxo-Cu(II) Complexes Guillaume Izzet, Huriye Akdas, Nicolas Hucher, Michel Giorgi, Thierry Prangé, and Olivia Reinaud pp 1069 - 1077; DOI: 10.1021/ic051221e |
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Terephthalamide-Containing Analogues of TREN-Me-3,2-HOPO Kristy M. Clarke Jurchen and Kenneth N. Raymond pp 1078 - 1090; DOI: 10.1021/ic0512882 |
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Donor-Acceptor Heteroleptic Open Sandwiches Gabriel Merino, Hiram I. Beltrán, and Alberto Vela pp 1091 - 1095; DOI: 10.1021/ic051391r |
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Dehydrogenative Silane Coupling on Silicon Surfaces via Early Transition Metal Catalysis Yun-Hui Li and Jillian M. Buriak pp 1096 - 1102; DOI: 10.1021/ic051431r |
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Unprecedented [V2O]6+ Core of a Centrosymmetric Thiosemicarbazonato Dimer: Spontaneous Deoxygenation of Oxovanadium(IV) Musa S. Shongwe, Huda N. R. Al-Kharousi, Harry Adams, Michael J. Morris, and Eckhard Bill pp 1103 - 1107; DOI: 10.1021/ic0511625 |
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Synthesis of Heterometal Cluster Complexes by the Reaction of Cobaltadichalcogenolato Complexes with Groups 6 and 8 Metal Carbonyls Masaki Murata, Satoru Habe, Shingo Araki, Kosuke Namiki, Teppei Yamada, Norikiyo Nakagawa, Takuya Nankawa, Masayuki Nihei, Jun Mizutani, Masato Kurihara, and Hiroshi Nishihara pp 1108 - 1116; DOI: 10.1021/ic0513282 |
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Nature of the Chemical Bond in Polypnictides: The Lone Pair Aromatic Anions P42- and As42- Florian Kraus, Tobias Hanauer, and Nikolaus Korber pp 1117 - 1123; DOI: 10.1021/ic0514445 |
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Incorporation of Triazacyclononane into the Metal Phosphonate Backbones Song-Song Bao, Gang-Sheng Chen, Yin Wang, Yi-Zhi Li, Li-Min Zheng, and Qin-Hui Luo pp 1124 - 1129; DOI: 10.1021/ic051498e |
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Supramolecular Asymmetric Induction in Dinuclear Triple-Stranded Helicates1 Robert M. Yeh and Kenneth N. Raymond pp 1130 - 1139; DOI: 10.1021/ic0515711 |
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Color Tuning of a Nickel Complex with a Novel N2S2 Pyridine-Containing Macrocyclic Ligand Abel Tamayo, Jaume Casabó, Lluis Escriche, Carlos Lodeiro, Berta Covelo, Carlos D. Brondino, Raikko Kivekäs, and Reijo Sillampää pp 1140 - 1149; DOI: 10.1021/ic051574d |
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Coordination Networks with Fluorinated Backbones Ye Gao, Brendan Twamley, and Jean'ne M. Shreeve pp 1150 - 1155; DOI: 10.1021/ic051608h |
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From Simple Monopyridine Clusters [Mo6Br13(Py-R)][n-Bu4N] and Hexapyridine Clusters [Mo6X8(Py-R)6][OSO2CF3]4 (X = Br or I) to Cluster-Cored Organometallic Stars, Dendrons, and Dendrimers Denise Méry, Lauriane Plault, Cátia Ornelas, Jaime Ruiz, Sylvain Nlate, Didier Astruc, Jean-Claude Blais, João Rodrigues, Stéphane Cordier, Kaplan Kirakci, and Christiane Perrin pp 1156 - 1167; DOI: 10.1021/ic051680f |
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Structure of an I-·(H2O)6 Anion Cluster in a 3D Anion Crystal Host [I·(H2O)6Fe(CN)6·H2O] 4- Wen Dong, Yan Ou-Yang, Hai-Bin Song, Dai-Zheng Liao, Zong-Hui Jiang, Shi-Ping Yan, and Peng Cheng pp 1168 - 1172; DOI: 10.1021/ic051657u |
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Energy Transfer in Hybrids Based on a Thiophene-Substituted Ethynylbipyridine Dimer Decorated with Re(I), Ru(II), and Os(II) Units Sébastien Goeb, Antoinette De Nicola, Raymond Ziessel, Cristiana Sabatini, Andrea Barbieri, and Francesco Barigelletti pp 1173 - 1183; DOI: 10.1021/ic051717w |
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Coupled Ion/Electron Hopping in LixNiO2: A 7Li NMR Study C. Chazel, M. Ménétrier, L. Croguennec, and C. Delmas pp 1184 - 1191; DOI: 10.1021/ic051593n |
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Toward Development of Water Soluble Dye Derivatized Nitrosyl Compounds for Photochemical Delivery of NO Stephen R. Wecksler, Jordan Hutchinson, and Peter C. Ford pp 1192 - 1200; DOI: 10.1021/ic051723s |
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Systematic Synthesis and Characterization of Single-Crystal Lanthanide Phenylphosphonate Nanorods Shu-Yan Song, Jian-Fang Ma, Jin Yang, Min-Hua Cao, Hong-Jie Zhang, Hai-Shui Wang, and Kui-Yue Yang pp 1201 - 1207; DOI: 10.1021/ic051749j |
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Synthesis of Variable-Aspect-Ratio, Single-Crystalline ZnO Nanostructures Bin Cheng, Wensheng Shi, Joette M. Russell-Tanner, Lei Zhang, and Edward T. Samulski pp 1208 - 1214; DOI: 10.1021/ic051786a |
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Syntheses and Quadratic Optical Nonlinearities of Ruthenium(II) Complexes with Ethynyl-Connected N-Methylpyridinium Electron Acceptors Benjamin J. Coe, Josephine L. Harries, Madeleine Helliwell, Bruce S. Brunschwig, James A. Harris, Inge Asselberghs, Sheng-Ting Hung, Koen Clays, Peter N. Horton, and Michael B. Hursthouse pp 1215 - 1227; DOI: 10.1021/ic051816+ |
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Has AuF7 Been Made? Sebastian Riedel and Martin Kaupp pp 1228 - 1234; DOI: 10.1021/ic051944y |
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Formation of Higher Chloride Complexes of Np(IV) and Pu(IV) in Water-Stable Room-Temperature Ionic Liquid [BuMeIm][Tf2N] Sergey I. Nikitenko and Philippe Moisy pp 1235 - 1242; DOI: 10.1021/ic050728m |
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Structural and Texture Evolution with Temperature of Layered Double Hydroxides Intercalated with Paramolybdate Anions D. Carriazo, C. Domingo, C. Martín, and V. Rives pp 1243 - 1251; DOI: 10.1021/ic0508674 |
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Rhodium Assisted C-H Activation of Benzaldehyde Thiosemicarbazones and Their Oxidation via Activation of Molecular Oxygen Rama Acharyya, Swati Dutta, Falguni Basuli, Shie-Ming Peng, Gene-Hsiang Lee, Larry R. Falvello, and Samaresh Bhattacharya pp 1252 - 1259; DOI: 10.1021/ic050505w |
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Dioxo- and Oxovanadium(V) Complexes of Thiohydrazone ONS Donor Ligands: Synthesis, Characterization, Reactivity, and Antiamoebic Activity Mannar R. Maurya, Amit Kumar, Abdul R. Bhat, Amir Azam, Cerstin Bader, and Dieter Rehder pp 1260 - 1269; DOI: 10.1021/ic050811+ |
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Insight into Framework Destruction in Ultramarine Pigments Eleonora Del Federico, Wolfgang Shöfberger, Johannes Schelvis, Sofia Kapetanaki, Lindsey Tyne, and Alexej Jerschow pp 1270 - 1276; DOI: 10.1021/ic050903z |
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Mono-, Di-, and Oligonuclear Complexes of CuII Ions and p-Hydroquinone Ligands: Syntheses, Electrochemical Properties, and Magnetic Behavior Günter Margraf, Tonia Kretz, Fabrizia Fabrizi de Biani, Franco Laschi, Serena Losi, Piero Zanello, Jan W. Bats, Bernd Wolf, Katarina Removi  -Langer, Michael Lang, Andrei Prokofiev, Wolf Assmus, Hans-Wolfram Lerner, and Matthias Wagnerpp 1277 - 1288; DOI: 10.1021/ic051016z |
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Synthesis, Characterization, and DNA Binding of New Water-Soluble Cyclopentadienyl Ruthenium(II) Complexes Incorporating Phosphines Antonio Romerosa, Tatiana Campos-Malpartida, Chaker Lidrissi, Mustapha Saoud, Manuel Serrano-Ruiz, Maurizio Peruzzini, Jose Antonio Garrido-Cárdenas, and Federico García-Maroto pp 1289 - 1298; DOI: 10.1021/ic051053q |
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Static Magnetic-Field-Induced Phase Lag in the Magnetization Response of Tris(dipicolinato)lanthanides Miki Sugita, Naoto Ishikawa, Tadahiko Ishikawa, Shin-ya Koshihara, and Youkoh Kaizu pp 1299 - 1304; DOI: 10.1021/ic051089i |
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Chemistry and Electrochemistry of the Heterodinuclear Complex ClPd(dppm)2PtCl: A M-M' Bond Providing Site Selectivity David Evrard, Sébastien Clément, Dominique Lucas, Bernard Hanquet, Michael Knorr, Carsten Strohmann, Andreas Decken, Yves Mugnier, and Pierre D. Harvey pp 1305 - 1315; DOI: 10.1021/ic051102z |
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Metal-Induced Reductive Ring Opening of 1,2,4,5-Tetrazines: Three Resulting Coordination Alternatives, Including the New Non-Innocent 1,2-Diiminohydrazido(2-) Bridging Ligand System Somnath Maji, Biprajit Sarkar, Srikanta Patra, Jan Fiedler, Shaikh M. Mobin, Vedavati G. Puranik, Wolfgang Kaim, and Goutam Kumar Lahiri pp 1316 - 1325; DOI: 10.1021/ic051532p |
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A Comparative Mechanistic Study of the Reversible Binding of NO to a Water-Soluble Octa-Cationic FeIII Porphyrin Complex Joo-Eun Jee, Maria Wolak, Domenico Balbinot, Norbert Jux, Achim Zahl, and Rudi van Eldik pp 1326 - 1337; DOI: 10.1021/ic051339v |
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O2 and CO Binding to Tetraaza-Tripodal-Capped Iron(II) Porphyrins Christian Ruzié, Pascale Even, David Ricard, Thierry Roisnel, and Bernard Boitrel pp 1338 - 1348; DOI: 10.1021/ic0514703 |
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Syntheses, Structural Determinations of [Ru(ROCS2)2(PPh3)2]+/0 Pairs, and Kinetic Analyses of Thermal Reactions Involving Transient trans-[Ru(iPrOCS2)2(PPh3)2] Species (ROCS2- = Ethyl- or Isopropyldithiocarbonate and PPh3 = Triphenylphosphine) Kyoko Noda, Yuko Ohuchi, Akira Hashimoto, Masayuki Fujiki, Sumitaka Itoh, Satoshi Iwatsuki, Toshiaki Noda, Takayoshi Suzuki, Kazuo Kashiwabara, and Hideo D. Takagi pp 1349 - 1355; DOI: 10.1021/ic051487l |
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Systematic DFT Study of Gas Phase and Solvated Uranyl and Neptunyl Complexes [AnO2X4]n (An = U, Np; X = F, Cl, OH, n = -2; X = H2O, n = +2) Maite García-Hernández, Christa Willnauer, Sven Krüger, Lyudmila V. Moskaleva, and Notker Rösch pp 1356 - 1366; DOI: 10.1021/ic051492p |
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Reactivity of Aquacobalamin and Reduced Cobalamin toward S-Nitrosoglutathione and S-Nitroso-N-acetylpenicillamine Maria Wolak, Gra  yna Stochel, and Rudi van Eldikpp 1367 - 1379; DOI: 10.1021/ic051300q |
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Titanium(II) and Titanium(III) Tetrahydroborates. Crystal Structures of [Li(Et2O)2][Ti2(BH4)5(PMe2Ph)4], Ti(BH4)3(PMe2Ph)2, and Ti(BH4)3(PEt3)2 Dean M. Goedde and Gregory S. Girolami pp 1380 - 1388; DOI: 10.1021/ic051556w |
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Production and Reactions of Organic-Soluble Lanthanide Complexes of the Monolacunary Dawson [1-P2W17O61]10- Polyoxotungstate Cécile Boglio, Géraldine Lenoble, Carine Duhayon, Bernold Hasenknopf, René Thouvenot, Cheng Zhang, Robertha C. Howell, Benjamin P. Burton-Pye, Lynn C. Francesconi, Emmanuel Lacôte, Serge Thorimbert, Max Malacria, Carlos Afonso, and Jean-Claude Tabet pp 1389 - 1398; DOI: 10.1021/ic051679g |
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cis-to-trans Isomerization Promoted by Pyridine as a Crucial Step for the Selective Preparation of trans-Pt(SAr)(Cl)(PAr'3)2 Fumikazu Yamashita, Hitoshi Kuniyasu, Jun Terao, and Nobuaki Kambe pp 1399 - 1404; DOI: 10.1021/ic051780l |
Issue 4
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Coordination Complexes with cis-TCNE Radical Anion Ligands. Models of M[TCNE]2 Magnets Guangbin Wang, Huifang Zhu, Jian Fan, Carla Slebodnick, and Gordon T. Yee pp 1406 - 1408; DOI: 10.1021/ic050854q |
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Geometric Preferences in Iron(II) and Zinc(II) Model Complexes of Peptide Deformylase Vivek V. Karambelkar, Chuanyun Xiao, Yingkai Zhang, Amy A. Narducci Sarjeant, and David P. Goldberg pp 1409 - 1411; DOI: 10.1021/ic050995s |
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New Disordering Mode for TFSI- Anions: The Nonequilibrium, Plastic Crystalline Structure of Et4NTFSI Wesley A. Henderson, Marie Herstedt, Victor G. Young, Jr., Stefano Passerini, Hugh C. De Long, and Paul C. Trulove pp 1412 - 1414; DOI: 10.1021/ic0513742 |
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Effect of the Transition Metal on the Synthesis of Quaternary Sulfides MPb8In17S34 (M = Cu, Ag, Au) Kuan-Chen Wang and Chi-Shen Lee pp 1415 - 1417; DOI: 10.1021/ic051447h |
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A New Type of Luminescent Alkynyl Au4Cu2 Cluster Héctor de la Riva, Mark Nieuwhuyzen, Claudio Mendicute Fierro, Paul R. Raithby, Louise Male, and M. Cristina Lagunas pp 1418 - 1420; DOI: 10.1021/ic051503e |
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Metal Clusters as Ligands. Substitution of Fe Ions in Fe/Mo/S Clusters by Thiophilic CuI Ions Markos Koutmos and Dimitri Coucouvanis pp 1421 - 1423; DOI: 10.1021/ic051860p |
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DFT Analysis of Interligand Vibrations in a Hydroperoxo Complex of Cobalt Bleomycin Pawel M. Kozlowski, Vadim V. Nazarenko, and Andrzej A. Jarzecki pp 1424 - 1426; DOI: 10.1021/ic051629b |
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Sulfur Stable Isotope Distribution of Polysulfide Anions in an (NH4)2Sn Aqueous Solution Alon Amrani, Alexey Kamyshny, Jr., Ovadia Lev, and Zeev Aizenshtat pp 1427 - 1429; DOI: 10.1021/ic051748r |
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Two New Borates Containing the First Examples of Large Isolated Polyborate Anions: Chain [B7O9(OH)5]2- and Ring [B14O20(OH)6]4- Zhi-Hong Liu, Lian-Qing Li, and Wen-Juan Zhang pp 1430 - 1432; DOI: 10.1021/ic051580+ |
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On the Composition and Crystal Structure of the New Quaternary Hydride Phase Li4BN3H10 Yaroslav E. Filinchuk, Klaus Yvon, Gregory P. Meisner, Frederick E. Pinkerton, and Michael P. Balogh pp 1433 - 1435; DOI: 10.1021/ic0518226 |
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UF3(H2O)(C2O4)0.5: A Fluorooxalate of Tetravalent Uranium with a Three-Dimensional Framework Structure Chih-Min Wang, Chia-Hsien Liao, Pei-Lin Chen, and Kwang-Hwa Lii pp 1436 - 1438; DOI: 10.1021/ic051960v |
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Layer-by-Layer Deposition of Bimetallic Nanoshells on Functionalized Polystyrene Beads Snigdhamayee Praharaj, Sudip Nath, Sudipa Panigrahi, Sujit Kumar Ghosh, Soumen Basu, Surojit Pande, Subhra Jana, and Tarasankar Pal pp 1439 - 1441; DOI: 10.1021/ic051915n |
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Robust Non-Interpenetrating Coordination Frameworks from New Shape-Persistent Building Blocks Jonathan H. Chong and Mark J. MacLachlan pp 1442 - 1444; DOI: 10.1021/ic052123w |
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Asymmetric Transformation of a Double-Stranded, Dicopper(I) Helicate Containing Achiral Bis(bidentate) Schiff Bases Nicolle C. Habermehl, Patricia M. Angus, Nathan L. Kilah, Lasse Norén, A. David Rae, Anthony C. Willis, and S. Bruce Wild pp 1445 - 1462; DOI: 10.1021/ic051478c |
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Synthesis and Electrochemistry of Undeca-substituted Metallo-benzoylbiliverdins Owendi Ongayi, M. Graça H. Vicente, Zhongping Ou, Karl M. Kadish, M. Ravi Kumar, Frank R. Fronczek, and Kevin M. Smith pp 1463 - 1470; DOI: 10.1021/ic050841c |
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Reduction of Vanadium(V) by L-Ascorbic Acid at Low and Neutral pH: Kinetic, Mechanistic, and Spectroscopic Characterization Patricia C. Wilkins, Michael D. Johnson, Alvin A. Holder, and Debbie C. Crans pp 1471 - 1479; DOI: 10.1021/ic050749g |
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A Density Functional Study of Uranyl Monocarboxylates Florian Schlosser, Sven Krüger, and Notker Rösch pp 1480 - 1490; DOI: 10.1021/ic050767y |
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Density Functional Study of the O2 Binding to [CuI(TPAR)]+ (TPA = Tris(2-pyridylmethyl)amine) in THF and EtCN Adam Johannes Johansson, Margareta R. A. Blomberg, and Per E. M. Siegbahn pp 1491 - 1497; DOI: 10.1021/ic050874s |
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Solution and Structural Investigations of Ligand Preorganization in Trivalent Lanthanide Complexes of Bicyclic Malonamides Bevin W. Parks, Robert D. Gilbertson, James E. Hutchison, Elisabeth Rather Healey, Timothy J. R. Weakley, Brian M. Rapko, Benjamin P. Hay, Sergei I. Sinkov, Grant A. Broker, and Robin D. Rogers pp 1498 - 1507; DOI: 10.1021/ic050437d |
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Two Three-Dimensional Metal-Organic Frameworks Containing One-Dimensional Hydroxyl/Carboxylate Mixed Bridged Metal Chains: Syntheses, Crystal Structures, and Magnetic Properties Xiao-Ju Li, Xin-Yi Wang, Song Gao, and Rong Cao pp 1508 - 1516; DOI: 10.1021/ic050999x |
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Syntheses and X-ray Crystal Structures of - and -[XeO2F][SbF6], [XeO2F][AsF6], [FO2XeFXeO2F][AsF6], and [XeF5][SbF6]·XeOF4 and Computational Studies of the XeO2F+ and FO2XeFXeO2F+ Cations and Related Species Bernard E. Pointner, Reijo J. Suontamo, and Gary J. Schrobilgen pp 1517 - 1534; DOI: 10.1021/ic0510260 |
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Bonding Trends of Thiosemicarbazones in Mononuclear and Dinuclear Copper(I) Complexes: Syntheses, Structures, and Theoretical Aspects Tarlok S. Lobana, Rekha, R. J. Butcher, A. Castineiras, E. Bermejo, and Prasad V. Bharatam pp 1535 - 1542; DOI: 10.1021/ic051018j |
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Novel Oxygen Chirality Induced by Asymmetric Coordination of an Ether Oxygen Atom to a Metal Center in a Series of Sugar-Pendant Dipicolylamine Copper(II) Complexes Yuji Mikata, Yuko Sugai, Makoto Obata, Masafumi Harada, and Shigenobu Yano pp 1543 - 1551; DOI: 10.1021/ic051513f |
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De Novo Design of Synthetic Di-Iron(I) Complexes as Structural Models of the Reduced Form of Iron-Iron Hydrogenase Jesse W. Tye, Marcetta Y. Darensbourg, and Michael B. Hall pp 1552 - 1559; DOI: 10.1021/ic051231f |
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Synthesis and Characterization of Silver(I) Coordination Networks Bearing Flexible Thioethers: Anion versus Ligand Dominated Structures Mohamed Osman Awaleh, Antonella Badia, François Brisse, and Xian-He Bu pp 1560 - 1574; DOI: 10.1021/ic051357c |
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Solvent Tuning of the Substitution Behavior of a Seven-Coordinate Iron(III) Complex Ivana Ivanovi -Burmazovi, Mohamed S. A. Hamza, and Rudi van Eldikpp 1575 - 1584; DOI: 10.1021/ic0514694 |
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Influence of Ionic Liquids Bearing Functional Groups in Dye-Sensitized Solar Cells Fellicien Mazille, Zhaofu Fei, Daibin Kuang, Dongbin Zhao, Shaik M. Zakeeruddin, Michael Grätzel, and Paul J. Dyson pp 1585 - 1590; DOI: 10.1021/ic051751a |
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GeO2 Natrolite-Type Infinite Four and Eight R-Containing Layers in a 2D Pure-Ge Framework: Ge3O5(OH)4[C2N2H10] Natalia Snejko, Manuela E. Medina, Enrique Gutierrez-Puebla, and M. Angeles Monge pp 1591 - 1594; DOI: 10.1021/ic051039d |
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Transition State Characterization for the Reversible Binding of Dihydrogen to Bis(2,2'-bipyridine)rhodium(I) from Temperature- and Pressure-Dependent Experimental and Theoretical Studies Etsuko Fujita, Bruce S. Brunschwig, Carol Creutz, James T. Muckerman, Norman Sutin, David Szalda, and Rudi van Eldik pp 1595 - 1603; DOI: 10.1021/ic0515498 |
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Tl(I), Fe(II), and Co(II) Complexes Supported by a Monoanionic N,N,N'-Heteroscorpionate Ligand Bis(3,5-di-tertbutylpyrazol-1-yl)-1-CH2NAr (Ar = 2,6-iPr2C6H3) Debashis Adhikari, Guangyu Zhao, Falguni Basuli, John Tomaszewski, John C. Huffman, and Daniel J. Mindiola pp 1604 - 1610; DOI: 10.1021/ic051704i |
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Synthesis, Structural Evolution, and Electrical Properties of the Novel Mo12 Cluster Compounds K1+xMo12S14 (x = 0, 1.1, 1.3, and 1.6) with a Tunnel Structure Soazig Picard, Patrick Gougeon, and Michel Potel pp 1611 - 1616; DOI: 10.1021/ic051622u |
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Anion Influence on the Structures of a Series of Copper(II) Metal-Organic Frameworks Pilar Díaz, Jordi Benet-Buchholz, Ramón Vilar, and Andrew J. P. White pp 1617 - 1626; DOI: 10.1021/ic051457i |
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Metal-Organic Frameworks from Homometallic Chains of Nickel(II) and 1,4-Cyclohexanedicarboxylate Connectors: Ferrimagnet-Ferromagnet Transformation Mohamedally Kurmoo, Hitoshi Kumagai, Motoko Akita-Tanaka, Katsuya Inoue, and Seishi Takagi pp 1627 - 1637; DOI: 10.1021/ic051633n |
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Covalent and Noncovalent Interactions for [Metal(dien)nucleobase]2+ Complexes with L-Tryptophan Derivatives: Formation of Palladium-Tryptophan Species by Nucleobase Substitution under Biologically Relevant Conditions Atilio I. Anzellotti, Michal Sabat, and Nicholas Farrell pp 1638 - 1645; DOI: 10.1021/ic051644g |
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Structure of Organic and Metal-Organic Networks Based on a Bifunctional m-Terphenyl Carboxylic Acid Diane A. Dickie, Gabriele Schatte, Michael C. Jennings, Hilary A. Jenkins, Sarah Y. L. Khoo, and Jason A. C. Clyburne pp 1646 - 1655; DOI: 10.1021/ic051690g |
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Multisite Effects on Intervalence Charge Transfer in a Clusterlike Trinuclear Assembly Containing Ruthenium and Osmium Deanna M. D'Alessandro, Murray S. Davies, and F. Richard Keene pp 1656 - 1666; DOI: 10.1021/ic051699i |
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Synthesis, Structure, and Spectroscopic and Magnetic Properties of Mesomorphic Octakis(hexylthio)-Substituted Phthalocyanine Rare-Earth Metal Sandwich Complexes Ay  e Gül Gürek, Tamara Basova, Dominique Luneau, Colette Lebrun, Evgeny Kol'tsov, Aseel K. Hassan, and Vefa Ahsenpp 1667 - 1676; DOI: 10.1021/ic051754n |
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Cyclic Voltammetry of Th(IV) in the Room-Temperature Ionic Liquid [Me3NnBu][N(SO2CF3)2] Anand I. Bhatt, Noel W. Duffy, David Collison, Iain May, and Robert G. Lewin pp 1677 - 1682; DOI: 10.1021/ic051750i |
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Synthesis and Reactivity of N-Heterocycle-B(C6F5)3 Complexes. 4. Competition between Pyridine- and Pyrrole-Type Substrates toward B(C6F5)3: Structure and Dynamics of 7-B(C6F5)3-7-azaindole and [7-Azaindolium]+[HOB(C6F5)3]- Francesca Focante, Isabella Camurati, Luigi Resconi, Simona Guidotti, Tiziana Beringhelli, Giuseppe D'Alfonso, Daniela Donghi, Daniela Maggioni, Pierluigi Mercandelli, and Angelo Sironi pp 1683 - 1692; DOI: 10.1021/ic051285p |
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Nanoscale Zinc Antimonides: Synthesis and Phase Stability Sabine Schlecht, Christoph Erk, and Maekele Yosef pp 1693 - 1697; DOI: 10.1021/ic051808t |
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Structural and Electronic Differences of Copper(I) Complexes with Tris(pyrazolyl)methane and Hydrotris(pyrazolyl)borate Ligands Kiyoshi Fujisawa, Tetsuya Ono, Yoko Ishikawa, Nagina Amir, Yoshitaro Miyashita, Ken-ichi Okamoto, and Nicolai Lehnert pp 1698 - 1713; DOI: 10.1021/ic051290t |
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Utilization of the Highly Environment-Sensitive Emission Properties of Rhenium(I) Amidodipyridoquinoxaline Biotin Complexes in the Development of Biological Probes Kenneth Kam-Wing Lo, Keith Hing-Kit Tsang, and Ka-Shing Sze pp 1714 - 1722; DOI: 10.1021/ic051266f |
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Axial Chirality and Supramolecular Interactions: The Case of [(2-P,P-{PPh2NMe}2CO)CuICl]2 Olaf Kühl, Steffen Blaurock, and Thomas Carls pp 1723 - 1727; DOI: 10.1021/ic051426n |
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Ruthenium(II) Bipyridyl Complexes as Photolabile Caging Groups for Amines Leonardo Zayat, Marcelo Salierno, and Roberto Etchenique pp 1728 - 1731; DOI: 10.1021/ic0512983 |
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Structure and Bonding in Monomeric Iron(III) Complexes with Terminal Oxo and Hydroxo Ligands Josè Gracia Budrìa, Simone Raugei, and Luigi Cavallo pp 1732 - 1738; DOI: 10.1021/ic051372h |
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Modified Dipicolinic Acid Ligands for Sensitization of Europium(III) Luminescence Michael R. George, Christopher A. Golden, Martin C. Grossel, and Richard J. Curry pp 1739 - 1744; DOI: 10.1021/ic051461u |
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Di- and Tetranuclear Metal Complexes with Phenoxo Bridges: Synthesis, Structures, and Photoluminescent and Electroluminescent Properties Hong-Yu Zhang, Kai-Qi Ye, Jing-Ying Zhang, Yin Liu, and Yue Wang pp 1745 - 1753; DOI: 10.1021/ic051531x |
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Volume-Based Thermodynamics: Estimations for 2:2 Salts H. Donald Brooke Jenkins and Leslie Glasser pp 1754 - 1756; DOI: 10.1021/ic051359x |
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[Au(CN)4]- as Both an Intramolecular and Intermolecular Bidentate Ligand with [(tmeda)Cu(-OH)] Dimers: from Antiferro- to Ferromagnetic Coupling in Polymorphs Michael J. Katz, Carolyn J. Shorrock, Raymond J. Batchelor, and Daniel B. Leznoff pp 1757 - 1765; DOI: 10.1021/ic0515094 |
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Synthesis and Characterization of Novel Dinuclear Copper(I) Complexes. Dimerization of [CuL(PPh3)2] (L = methyl 3-hydroxy-3-(p-R-phenyl)-2-propenedithioate) Ivan García-Orozco, Ma. Carmen Ortega-Alfaro, José G. López-Cortés, Ruben Alfredo Toscano, and Cecilio Alvarez-Toledano pp 1766 - 1773; DOI: 10.1021/ic0515958 |
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Magneto-Structural Correlations in Cu(tn)Cl2 (tn = 1,3-Diaminopropane): Two-Dimensional Spatially Anisotropic Triangular Magnet Formed by Hydrogen Bonds Vladimír Zele  ák, Al beta Orendáová, Ivana Císa ová, Juraj  ernák, Oxana V. Kravchyna, Ju-Hyun Park, Martin Orendá, Alexander G. Anders, Alexander Feher, and Mark W. Meiselpp 1774 - 1782; DOI: 10.1021/ic0516109 |
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Pentafluoronitrosulfane, SF5NO2 Norman Lu, Joseph S. Thrasher, Stefan von Ahsen, Helge Willner, Drahomir Hnyk, and Heinz Oberhammer pp 1783 - 1788; DOI: 10.1021/ic0516212 |
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Coordination Chemistry of Ga(C5Me4Ph): Novel Homoleptic d10 Cluster Complexes of Palladium Beatrice Buchin, Christian Gemel, Thomas Cadenbach, and Roland A. Fischer pp 1789 - 1794; DOI: 10.1021/ic051658m |
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Aqueous Spectroscopy and Redox Properties of Carboxylate-Bound Titanium Ritika Uppal, Christopher D. Incarvito, K. V. Lakshmi, and Ann M. Valentine pp 1795 - 1804; DOI: 10.1021/ic051714j |
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Platinum(II)-Mediated Coupling Reactions of Acetonitrile with the Exocyclic Nitrogen of 9-Methyladenine and 1-Methylcytosine. Synthesis, NMR Characterization, and X-ray Structures of New Azametallacycle Complexes Bruno Longato, Diego Montagner, Giuliano Bandoli, and Ennio Zangrando pp 1805 - 1814; DOI: 10.1021/ic051755f |
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Dizinc Alkoxides and Amides Supported by Binucleating Bis(amidoamine) Ligands Mark L. Hlavinka, Michael J. McNevin, Richard Shoemaker, and John R. Hagadorn pp 1815 - 1822; DOI: 10.1021/ic051669f |
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Synthesis, Characterization, and Hydrolysis of Aluminum(III) Compounds Bearing the C6F5-Substituted -Diketiminate HC[(CMe)(NC6F5)]2 (L) Ligand Zhi Yang, Hongping Zhu, Xiaoli Ma, Jianfang Chai, Herbert W. Roesky, Cheng He, Jörg Magull, Hans-Georg Schmidt, and Mathias Noltemeyer pp 1823 - 1827; DOI: 10.1021/ic051718o |
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Solid-State 23Na and 7Li NMR Investigations of Sodium- and Lithium-Reduced Mesoporous Titanium Oxides Andy Y. H. Lo, Robert W. Schurko, Melissa Vettraino, Boris O. Skadtchenko, Michel Trudeau, and David M. Antonelli pp 1828 - 1838; DOI: 10.1021/ic051654h |
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Pu(VI) Hydrolysis: Further Evidence for a Dimeric Plutonyl Hydroxide and Contrasts with U(VI) Chemistry Sean D. Reilly and Mary P. Neu pp 1839 - 1846; DOI: 10.1021/ic051760j |
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Formation and Characterization of the Uranium Methylidene Complexes CH2=UHX (X = F, Cl, and Br) Jonathan T. Lyon and Lester Andrews pp 1847 - 1852; DOI: 10.1021/ic051785i |
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Syntheses, Characterization, and X-ray Crystal Structures of -Diketiminate Group 13 Hydrides, Chlorides, and Fluorides Sanjay Singh, Hans-Jürgen Ahn, Andreas Stasch, Vojtech Jancik, Herbert W. Roesky, Aritra Pal, Mariana Biadene, Regine Herbst-Irmer, Mathias Noltemeyer, and Hans-Georg Schmidt pp 1853 - 1860; DOI: 10.1021/ic0517826 |
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Photochemical and Time Resolved Spectroscopic Studies of Intermediates Relevant to Iridium-Catalyzed Methanol Carbonylation: Photoinduced CO Migratory Insertion Maurizio Volpe, GuangWu, Alexei Iretskii, and Peter C. Ford pp 1861 - 1870; DOI: 10.1021/ic0513033 |
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Group 10 Metal Aminopyridinato Complexes: Synthesis, Structure, and Application as Aryl-Cl Activation and Hydrosilane Polymerization Catalysts Stefan Deeken, Sebastian Proch, Eugenio Casini, Hans F. Braun, Christian Mechtler, Christoph Marschner, Günter Motz, and Rhett Kempe pp 1871 - 1879; DOI: 10.1021/ic0518273 |
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Preface: Overview of the Forum on Solar and Renewable Energy Richard Eisenberg and Daniel G. Nocera: pp 1880 - 1880; DOI: 10.1021/ic0580083 |
Issue 5
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Synthesis and Characterization of a Soluble Bimetallic Oxalate-Based Bidimensional Magnet: [K(18-crown-6)]3[Mn3(H2O)4{Cr(ox)3}3] Eugenio Coronado, José Ramón Galán-Mascarós, and Carlos Martí-Gastaldo pp 1882 - 1884; DOI: 10.1021/ic0517570 |
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Unique Formation of a Pentanuclear Lanthanum(III) Thiolate Oxide Cluster via Control of Hydrolysis Hong-Xi Li, Mei-Ling Cheng, Zhi-Gang Ren, Wen-Hua Zhang, Jian-Ping Lang, and Qi Shen pp 1885 - 1887; DOI: 10.1021/ic052073v |
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Gold(I) 2-Arene Complexes Qing-Shan Li, Chong-Qing Wan, Ru-Yi Zou, Feng-Bo Xu, Hai-Bin Song, Xiang-Jian Wan, and Zheng-Zhi Zhang pp 1888 - 1890; DOI: 10.1021/ic051869r |
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Ionic Liquid of Choline Chloride/Malonic Acid as a Solvent in the Synthesis of Open-Framework Iron Oxalatophosphates Chyi-Yang Sheu, Shang-Fan Lee, and Kwang-Hwa Lii pp 1891 - 1893; DOI: 10.1021/ic0518475 |
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Epitaxial Film Growth and Superconducting Behavior of Sodium-Cobalt Oxyhydrate, NaxCoO2·yH2O (x ~ 0.3, y ~ 1.3) Kenji Sugiura, Hiromichi Ohta, Kenji Nomura, Hiroshi Yanagi, Masahiro Hirano, Hideo Hosono, and Kunihito Koumoto pp 1894 - 1896; DOI: 10.1021/ic051865m |
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(10,3)-a Noninterpenetrated Network Built from a Piedfort Ligand Pair Yanxiong Ke, David J. Collins, Daofeng Sun, and Hong-Cai Zhou pp 1897 - 1899; DOI: 10.1021/ic051900p |
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General Route to Three-Dimensional Framework Uranyl Transition Metal Phosphates with Atypical Structural Motifs: The Case Examples of Cs2{(UO2)4[Co(H2O)2]2(HPO4)(PO4)4} and Cs3+x[(UO2)3CuH4-x(PO4)5]·H2O Tatiana Y. Shvareva and Thomas E. Albrecht-Schmitt pp 1900 - 1902; DOI: 10.1021/ic051922b |
Spin Transitions in a Dithiazolyl Radical: Preparation, Crystal Structures, and Magnetic Properties of 3-Cyanobenzo-1,3,2-dithiazolyl, C7H3S2N2 Antonio Alberola, Rebecca J. Collis, Simon M. Humphrey, Robert J. Less, and Jeremy M. Rawson pp 1903 - 1905; DOI: 10.1021/ic051935p |
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Selective Oxidations of a Dithiolate Complex Produce a Mixed Sulfonate/Thiolate Complex Balwant S. Chohan and Michael J. Maroney pp 1906 - 1908; DOI: 10.1021/ic051982h |
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Hydrothermal Synthesis and Structure of a Three-Dimensional Cobalt(II) Triazolate Magnet Wayne Ouellette, José R. Galán-Mascarós, Kim R. Dunbar, and Jon Zubieta pp 1909 - 1911; DOI: 10.1021/ic051992i |
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C-H-Activated Aluminum Hydroxide via Molecular Oxygen Xiaofei Li, Haibin Song, Lili Duan, Chunming Cui, and Herbert W. Roesky pp 1912 - 1914; DOI: 10.1021/ic0600230 |
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Zirconium-Substituted Isopolytungstates: Structural Models for Zirconia-Supported Tungsten Catalysts Hugo Carabineiro, Richard Villanneau, Xavier Carrier, Patrick Herson, Francisco Lemos, Fernando Ramôa Ribeiro, Anna Proust, and Michel Che pp 1915 - 1923; DOI: 10.1021/ic051941l |
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Synthesis, Structures, and Magnetic Properties of Tetranuclear CuII-LnIII Complexes Jean-Pierre Costes, Magali Auchel, Françoise Dahan, Viviane Peyrou, Sergiu Shova, and Wolfgang Wernsdorfer pp 1924 - 1934; DOI: 10.1021/ic050587o |
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Synthesis and Theoretical Study of a Series of Dipalladium(I) Complexes Containing the Pd2(-CO)2 Core Sylvie Baig, Brigitte Richard, Philippe Serp, Claude Mijoule, Khansaa Hussein, Nathalie Guihéry, Jean-Claude Barthelat, and Philippe Kalck pp 1935 - 1944; DOI: 10.1021/ic050910n |
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The First Metal-Based Paullone Derivative with High Antiproliferative Activity in Vitro Anatoly Dobrov, Vladimir B. Arion, Norbert Kandler, Werner Ginzinger, Michael A. Jakupec, Anna Rufi  ska, Nikolai Graf von Keyserlingk, Markus Galanski, Christian Kowol, and Bernhard K. Kepplerpp 1945 - 1950; DOI: 10.1021/ic0511120 |
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Synthesis and Spectroscopic and Magnetic Characterization of Tris(3,5-dimethylpyrazol-1-yl)borate Iron Tricyanide Building Blocks, a Cluster, and a One-Dimensional Chain of Squares Dongfeng Li, Sean Parkin, Guangbin Wang, Gordon T. Yee, and Stephen M. Holmes pp 1951 - 1959; DOI: 10.1021/ic051044h |
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New Insights into the Coordination Chemistry and Molecular Structure of Copper(II) Histidine Complexes in Aqueous Solutions J. Gerbrand Mesu, Tom Visser, Fouad Soulimani, Ernst E. van Faassen, Peter de Peinder, Andrew M. Beale, and Bert M. Weckhuysen pp 1960 - 1971; DOI: 10.1021/ic051305n |
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A New Type of Hybrid Magnetic Semiconductor Based upon Polymeric Iodoplumbate and Metal-Organic Complexes as Templates Zhang-Jing Zhang, Sheng-Chang Xiang, Yong-Fan Zhang, A-Qing Wu, Li-Zhen Cai, Guo-Cong Guo, and Jin-Shun Huang pp 1972 - 1977; DOI: 10.1021/ic051350v |
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Syntheses of [F5TeNH3][AsF6], [F5TeN(H)Xe][AsF6], and F5TeNF2 and Characterization by Multi-NMR and Raman Spectroscopy and by Electronic Structure Calculations: The X-ray Crystal Structures of - and -F5TeNH2, [F5TeNH3][AsF6], and [F5TeN(H)Xe][AsF6] Barbara Fir, J. Marc Whalen, Hélène P. A. Mercier, David A. Dixon, and Gary J. Schrobilgen pp 1978 - 1996; DOI: 10.1021/ic051451t |
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Precursors to Clusters with the Topology of the PN Cluster of Nitrogenase: Edge-Bridged Double Cubane Clusters [(Tp)2Mo2Fe6S8L4]z: Synthesis, Structures, and Electron Transfer Series Curtis P. Berlinguette, Taichi Miyaji, Yugen Zhang, and R. H. Holm pp 1997 - 2007; DOI: 10.1021/ic051770k |
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The Butterfly Dimer [(tBu3SiO)Cr]2(-OSitBu3)2 and Its Oxidative Cleavage to (tBu3SiO)2Cr(=N-N=CPh2)2 and (tBu3SiO)2Cr=N(2,6-Ph2-C6H3) Orson L. Sydora, David S. Kuiper, Peter T. Wolczanski, Emil B. Lobkovsky, Adriana Dinescu, and Thomas R. Cundari pp 2008 - 2021; DOI: 10.1021/ic051481w |
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Crystal Structure and Physical Properties of Fe1.5Pb5.5In10S22 Yoshitaka Matsushita and Yutaka Ueda pp 2022 - 2026; DOI: 10.1021/ic0515296 |
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Effect of N-Methylation of Macrocyclic Amine Ligands on the Spin State of Iron(III): A Tale of Two Fluoro Complexes John F. Berry, Eckhard Bill, Ricardo García-Serres, Frank Neese, Thomas Weyhermüller, and Karl Wieghardt pp 2027 - 2037; DOI: 10.1021/ic051823y |
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Facile Controlled Synthesis of MnO2 Nanostructures of Novel Shapes and Their Application in Batteries Fangyi Cheng, Jianzhi Zhao, Wene Song, Chunsheng Li, Hua Ma, Jun Chen, and Panwen Shen pp 2038 - 2044; DOI: 10.1021/ic051715b |
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Hydroxy- and Mercaptopyridine Pincer Platinum and Palladium Complexes Generated by Silver-Free Halide Abstraction Alexey V. Chuchuryukin, Preston A. Chase, Allison M. Mills, Martin Lutz, Anthony L. Spek, Gerard P. M. van Klink, and Gerard van Koten pp 2045 - 2054; DOI: 10.1021/ic051773x |
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New Polyoxometalate Compounds Built up of Lacunary Wells-Dawson Anions and Trivalent Lanthanide Cations Ying Lu, Yan Xu, Yangguang Li, Enbo Wang, Xinxin Xu, and Ying Ma pp 2055 - 2060; DOI: 10.1021/ic0515857 |
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Novel Phenanthroline Ligands and Their Kinetically Locked Copper(I) Complexes with Unexpected Photophysical Properties Venkateshwarlu Kalsani, Michael Schmittel, Andrea Listorti, Gianluca Accorsi, and Nicola Armaroli pp 2061 - 2067; DOI: 10.1021/ic051828v |
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New Synthesis Route to and Physical Properties of Lanthanum Monoiodide Mikhail Ryazanov, Lorenz Kienle, Arndt Simon, and Hansjürgen Mattausch pp 2068 - 2074; DOI: 10.1021/ic051834r |
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Substituent Effects on Nitrosyl Iron Corrole Complexes Fe(Ar3C)(NO) Crisjoe A. Joseph, Matthew S. Lee, Alexei V. Iretskii, Guang Wu, and Peter C. Ford pp 2075 - 2082; DOI: 10.1021/ic051956j |
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Tri- and Tetranuclear Copper(II) Complexes Consisting of Mononuclear Cu(II) Chiral Building Blocks with a Sugar-Derived Schiff's Base Ligand Ajay K. Sah, Tomoaki Tanase, and Masahiro Mikuriya pp 2083 - 2092; DOI: 10.1021/ic051862+ |
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Pyrazine as a Building Block for Molecular Architectures with PtII Michael Willermann, Clodagh Mulcahy, Roland K. O. Sigel, Marta Morell Cerdà, Eva Freisinger, Pablo J. Sanz Miguel, Michael Roitzsch, and Bernhard Lippert pp 2093 - 2099; DOI: 10.1021/ic051966k |
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Rb6(InCo)2(Si9O26): A Mixed-Metal Silicate Containing 20-Membered-Ring Silicate Single Layers with a Very Low Si:O Ratio Ling-I Hung, Sue-Lein Wang, Yen-Hung Chen, and Kwang-Hwa Lii pp 2100 - 2103; DOI: 10.1021/ic052154r |
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Substitution of Au or Hg into BaTl2 and BaIn2. New Ternary Examples of Smaller CeCu2-Type Intermetallic Phases Jing-Cao Dai and John D. Corbett pp 2104 - 2111; DOI: 10.1021/ic051891k |
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Solution and Solid-State Study of Heteroleptic Hg(II)-Thiolates: Crystal Structures of [Hg4I4(SCH2CH2NH2)4] and [Hg4I8(SCH2CH2NH3)2]n·nH2O Mohan S. Bharara, Sean Parkin, and David A. Atwood pp 2112 - 2118; DOI: 10.1021/ic051993a |
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Syntheses and Structures of Magnesium and Zinc Boraamidinates: EPR and DFT Investigations of Li, Mg, Zn, B, and In Complexes of the [PhB(NtBu)2]- Anion Radical Tristram Chivers, Dana J. Eisler, Chantall Fedorchuk, Gabriele Schatte, Heikki M. Tuononen, and René T. Boeré pp 2119 - 2131; DOI: 10.1021/ic0520014 |
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Anion- and Solvent-Directed Assembly in Silver Bis(thioimidazolyl)methane Chemistry and the Silver-Sulfur Interaction Rosalice M. Silva, Mark D. Smith, and James R. Gardinier pp 2132 - 2142; DOI: 10.1021/ic052025a |
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A Novel Heteroditopic Terpyridine-Pincer Ligand as Building Block for Mono- and Heterometallic Pd(II) and Ru(II) Complexes Marcella Gagliardo, Gema Rodríguez, Henk H. Dam, Martin Lutz, Anthony L. Spek, Remco W. A. Havenith, Paolo Coppo, Luisa De Cola, Franti ek Hartl, Gerard P. M. van Klink, and Gerard van Kotenpp 2143 - 2155; DOI: 10.1021/ic051967c |
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Investigation of Vanadocene(IV) -Amino Acid Complexes: Synthesis, Structure, and Behavior in Physiological Solutions, Human Plasma, and Blood Jaromír Vinklárek, Hana Palá ková, Jan Honzíek, Jana Holubová, Michal Holapek, and Ivana Císaovápp 2156 - 2162; DOI: 10.1021/ic050687u |
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Preparative Routes to Luminescent Mixed-Ligand Rhenium(I) Dicarbonyl Complexes Joanna L. Smithback, Jeffrey B. Helms, Erick Schutte, Stephen M. Woessner, and B. Patrick Sullivan pp 2163 - 2174; DOI: 10.1021/ic050707s |
Synthesis and Structural Characterization of -Diketiminate-Lanthanide Amides and Their Catalytic Activity for the Polymerization of Methyl Methacrylate and  -CaprolactoneYingming Yao, Zhenqin Zhang, Hongmei Peng, Yong Zhang, Qi Shen, and Jun Lin pp 2175 - 2183; DOI: 10.1021/ic051158t |
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3-Phenyl-4-benzoyl-5-isoxazolonate Complex of Eu3+ with Tri-n-octylphosphine Oxide as a Promising Light-Conversion Molecular Device Rani Pavithran, N. S. Saleesh Kumar, S. Biju, M. L. P. Reddy, Severino A. Junior, and Ricardo O. Freire pp 2184 - 2192; DOI: 10.1021/ic051781d |
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Synthesis and Spectroscopic Studies on Copper(II) Binuclear Complexes of 1-Phenylamidino-O-alkylurea (alkyl = n-propyl, n- and iso-butyl) with 1,3-Diaminopropane or Ethylenediamine S. Pramodini Devi, R. K. Hemakumar Singh, and R. M. Kadam pp 2193 - 2198; DOI: 10.1021/ic051037t |
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Theoretical Characterization of the "Very Rapid" Mo(V) Species Generated in the Oxidation of Xanthine Oxidase Craig A. Bayse pp 2199 - 2202; DOI: 10.1021/ic0511930 |
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Synthesis, Structural and Spectroscopic Characterization, Catalytic Properties, and Thermal Transformations of New Cyclic Di- and Trisiloxanediolato Tantalum Complexes Ramesh N. Kapoor, Francisco Cervantes-Lee, Charles F. Campana, Curtis Haltiwanger, Kent Abney, and Keith H. Pannell pp 2203 - 2208; DOI: 10.1021/ic051274w |
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-Acid/-Base Carbonyloxomolybdenum(IV) Complexes and Their Oxomolybdenum(VI/IV) Precursors Michael S. Malarek, David J. Evans, Paul D. Smith, Ashley R. Bleeker, Jonathan M. White, and Charles G. Young pp 2209 - 2216; DOI: 10.1021/ic0510314 |
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New Cubic Perovskite Na(Cu2.5Ti0.5)Ti4O12 with Square Planar Coordination of Ti4+ Maxim Avdeev and Vladimir B. Nalbandyan pp 2217 - 2220; DOI: 10.1021/ic051413+ |
5,6,7,8-Tetrafluoro-3 4 2,1,2,4-benzothiaselenadiazine, 5,6,7,8-Tetrafluoro-1,342,2,4-benzodithiadiazine, and Their Hydrocarbon Analogues: Molecular and Crystal StructuresAlexander Yu. Makarov, Karla Tersago, Kanda Nivesanond, Frank Blockhuys, Christian Van Alsenoy, Mikhail K. Kovalev, Irina Yu. Bagryanskaya, Yuri V. Gatilov, Makhmut M. Shakirov, and Andrey V. Zibarev pp 2221 - 2228; DOI: 10.1021/ic051534+ |
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Design of a Magnetic Bistability Molecular System Constructed by H-Bonding and ···-Stacking Interactions X. M. Ren, S. Nishihara, T. Akutagawa, S. Noro, and T. Nakamura pp 2229 - 2234; DOI: 10.1021/ic051563k |
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Single Structure Widely Distributed in a GeTe-Sb2Te3 Pseudobinary System: A Rock Salt Structure is Retained by Intrinsically Containing an Enormous Number of Vacancies within its Crystal Toshiyuki Matsunaga, Rie Kojima, Noboru Yamada, Kouichi Kifune, Yoshiki Kubota, Yoshikazu Tabata, and Masaki Takata pp 2235 - 2241; DOI: 10.1021/ic051677w |
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Synthesis of Zinc, Copper, Nickel, Cobalt, and Iron Complexes Using Tris(pyrazolyl)methane Sulfonate Ligands: A Structural Model for N,N,O Binding in Metalloenzymes Elizabeth T. Papish, Michael T. Taylor, Finith E. Jernigan III, Michael J. Rodig, Robert R. Shawhan, Glenn P. A. Yap, and Fernando A. Jové pp 2242 - 2250; DOI: 10.1021/ic051579a |
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Electrochemistry and Spectroelectrochemistry of meso-Substituted Free-Base Corroles in Nonaqueous Media: Reactions of (Cor)H3, [(Cor)H4]+, and [(Cor)H2]- Jing Shen, Jianguo Shao, Zhongping Ou, Wenbo E, Beata Koszarna, Daniel T. Gryko, and Karl M. Kadish pp 2251 - 2265; DOI: 10.1021/ic051729h |
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Different Nuclearity Silver(I) Complexes with Novel Tetracyano Pendant-Armed Hexaazamacrocyclic Ligands María del Carmen Fernández-Fernández, Rufina Bastida, Alejandro Macías, Paulo Pérez-Lourido, and Laura Valencia pp 2266 - 2275; DOI: 10.1021/ic051627r |
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Synthesis and Thermolysis of Aluminum Amidinates: A Ligand-Exchange Route for New Mixed-Ligand Systems Allison L. Brazeau, Zhaohui Wang, Chris N. Rowley, and Seán T. Barry pp 2276 - 2281; DOI: 10.1021/ic051856d |
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Synthesis and X-ray Structures of New Titanium(IV) Aryloxides and Their Exploitation for the Ring Opening Polymerization of -Caprolactone Matthew G. Davidson, Matthew D. Jones, Matthew D. Lunn, and Mary F. Mahon pp 2282 - 2287; DOI: 10.1021/ic051708n |
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Synthesis, Structure, and Unusual Reactivity of -Halovinyl Cobalt Porphyrin Complexes Joseph M. Fritsch, Noah D. Retka, and Kristopher McNeill pp 2288 - 2295; DOI: 10.1021/ic0518834 |
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Kinetic and Thermodynamic Aspects of the Regioselective Addition of Bifunctional Hydroxylaminooxime-type HO-Nucleophiles to Pt-Complexed Nitriles Konstantin V. Luzyanin, Vadim Yu. Kukushkin, Maxim L. Kuznetsov, Alexander D. Ryabov, Markus Galanski, Matti Haukka, Eugene V. Tretyakov, Victor I. Ovcharenko, Maximilian N. Kopylovich, and Armando J. L. Pombeiro pp 2296 - 2306; DOI: 10.1021/ic051909r |
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Mononuclear [NiII(L)(P-(o-C6H4S)2(o-C6H4SH))]0/1- (L = Thiolate, Selenolate, PPh3, and Cl) Complexes with Intramolecular [Ni···S···H···S]/[Ni···H···S] Interactions Modulated by the Coordinated Ligand L: Relevance to the [NiFe] Hydrogenases Chien-Hong Chen, Gene-Hsiang Lee, and Wen-Feng Liaw pp 2307 - 2316; DOI: 10.1021/ic051924w |
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Hexanuclear Iron(III) Salicylaldoximato Complexes Presenting the [Fe6(3-O)2(2-OR)2]12+ Core: Syntheses, Crystal Structures, and Spectroscopic and Magnetic Characterization Catherine P. Raptopoulou, Athanassios K. Boudalis, Yiannis Sanakis, Vassilis Psycharis, Juan Modesto Clemente-Juan, Michael Fardis, George Diamantopoulos, and George Papavassiliou pp 2317 - 2326; DOI: 10.1021/ic051945q |
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Electron-Donating or -Withdrawing Nature of Substituents Revealed by the Electrochemistry of Metal-Free Phthalocyanines Renjie Li, Xianxi Zhang, Peihua Zhu, Dennis K. P. Ng, Nagao Kobayashi, and Jianzhuang Jiang pp 2327 - 2334; DOI: 10.1021/ic051931k |
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Selenium-Centered, Undecanuclear Silver Cages Surrounded by Iodo and Dialkyldiselenophosphato Ligands. Syntheses, Structures, and Photophysical Properties C. W. Liu, Iu-Jie Shang, Rei-Jen Fu, Ben-Jie Liaw, Ju-Chun Wang, and I-Jy Chang pp 2335 - 2340; DOI: 10.1021/ic052015+ |
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Isomers of a Dibismuthane, R2Bi-BiR2 [R = 2,6-(Me2NCH2)2C6H3], and Unusual Reactions with Oxygen: Formation of [R2Bi]2(O2) and R'R' 'Bi [R' = 2-(Me2NCH2)-6-{Me2N(O)CH2}C6H3; R' ' = 2-(Me2NCH2)-6-{O(O)C}C6H3] Lucia Balazs, Hans J. Breunig, Enno Lork, Albert Soran, and Cristian Silvestru pp 2341 - 2346; DOI: 10.1021/ic052160n |
Synthesis, Structural Characterization, and Catalytic Performance of Dititanium-Substituted  -Keggin SilicotungstateYuya Goto, Keigo Kamata, Kazuya Yamaguchi, Kazuhiro Uehara, Shiro Hikichi, and Noritaka Mizuno pp 2347 - 2356; DOI: 10.1021/ic052179q |
Issue 6
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A Nickel Superoxide Dismutase Maquette That Reproduces the Spectroscopic and Functional Properties of the Metalloenzyme Jason Shearer and Linh M. Long pp 2358 - 2360; DOI: 10.1021/ic0514344 |
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Crystal Structure and Electronic and Magnetic Properties of Hexacyanoosmate(III) Pablo Albores, Leonardo D. Slep, Luis M. Baraldo, Ricardo Baggio, María Teresa Garland, and Eva Rentschler pp 2361 - 2363; DOI: 10.1021/ic0516818 |
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Largest Mixed Transition Metal/Actinide Cluster: A Bimetallic Mn/Th Complex with a [Mn10Th6O22(OH)2]18+ Core Abhudaya Mishra, Khalil A. Abboud, and George Christou pp 2364 - 2366; DOI: 10.1021/ic052089l |
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Aluminum Tetraphenylporphyrin and Aluminum Phthalocyanine Neutral Radicals Julie A. Cissell, Thomas P. Vaid, and Arnold L. Rheingold pp 2367 - 2369; DOI: 10.1021/ic051794r |
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Observation of Triplet Intraligand Excited States through Nanosecond Step-Scan Fourier Transform Infrared Spectroscopy Dmitry E. Polyansky, Evgeny O. Danilov, and Felix N. Castellano pp 2370 - 2372; DOI: 10.1021/ic0518374 |
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Influence of the Electrochemical Conversion of [(LH)MnIICl2] into [(L)MnIIICl]+ on the Protonic State of a Phenol-Containing Ligand Laurent Sabater, Christelle Hureau, Régis Guillot, and Ally Aukauloo pp 2373 - 2375; DOI: 10.1021/ic051882b |
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New Valence-Sandwich [MnII4MnIII4MnII4] Aggregate Showing Single-Molecule Magnet Behavior Yangguang Li, Wolfgang Wernsdorfer, Rodolphe Clérac, Ian J. Hewitt, Christopher E. Anson, and Annie K. Powell pp 2376 - 2378; DOI: 10.1021/ic051819m |
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Large Pressure-Induced Red Shift of the Luminescence Band Originating from Nonstacked Square-Planar [Pt(SCN)4]2- in a Novel Trimetallic Complex Geneviève Levasseur-Thériault, Christian Reber, Christophe Aronica, and Dominique Luneau pp 2379 - 2381; DOI: 10.1021/ic051836b |
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Synthesis of Organically Templated Nanoporous Tin(II/IV) Phosphate for Radionuclide and Metal Sequestration Dawn M. Wellman, Shas V. Mattigod, Kent E. Parker, Steve M. Heald, Chongmin Wang, and Glen E. Fryxell pp 2382 - 2384; DOI: 10.1021/ic051949v |
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Synthesis of Cationic Oxorhenium Salen Complexes via -Oxo Abstraction and Their Activity in Catalytic Reductions Elon A. Ison, Jeanette E. Cessarich, Guodong Du, Phillip E. Fanwick, and Mahdi M. Abu-Omar pp 2385 - 2387; DOI: 10.1021/ic0520768 |
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New Architectures for Zirconium Polyphosphonates with a Tailor-Made Open-Framework Structure Riccardo Vivani, Ferdinando Costantino, Umberto Costantino, and Morena Nocchetti pp 2388 - 2390; DOI: 10.1021/ic052146a |
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Validity of the Classical Monte Carlo Method To Model the Magnetic Properties of a Large Transition-Metal Cluster: Mn19 Nicola Lima, Andrea Caneschi, Dante Gatteschi, Mikael Kritikos, and L. Gunnar Westin pp 2391 - 2393; DOI: 10.1021/ic051936h |
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Synthesis and Structure of Asymmetric Zirconium-Substituted Silicotungstates, [Zr6O2(OH)4(H2O)3(-SiW10O37)3]14- and [Zr4O2(OH)2(H2O)4(-SiW10O37)2]10- Bassem S. Bassil, Michael H. Dickman, and Ulrich Kortz pp 2394 - 2396; DOI: 10.1021/ic052131c |
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H2, N2, CO, and CO2 Sorption Properties of a Series of Robust Sodalite-Type Microporous Coordination Polymers Jorge A. R. Navarro, Elisa Barea, Juan M. Salas, Norberto Masciocchi, Simona Galli, Angelo Sironi, Conchi O. Ania, and José B. Parra pp 2397 - 2399; DOI: 10.1021/ic060049r |
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First Study of Metal Hybrids of Boronic Acids: Second-Sphere Coordination Networks in the Structures of 4-Carboxyphenylboronic Acid with Some Transition Metals Nanappan SeethaLekshmi and V. R. Pedireddi pp 2400 - 2402; DOI: 10.1021/ic052100h |
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Monomeric Iron(II) Hydroxo and Iron(III) Dihydroxo Complexes Stabilized by Intermolecular Hydrogen Bonding Laurent Bénisvy, Sabine Halut, Bruno Donnadieu, Jean-Pierre Tuchagues, Jean-Claude Chottard, and Yun Li pp 2403 - 2405; DOI: 10.1021/ic060100r |
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Diruthenium Dithiolato Cyanides: Basic Reactivity Studies and a Post Hoc Examination of Nature's Choice of Fe versus Ru for Hydrogenogenesis Aaron K. Justice, Rachel C. Linck, and Thomas B. Rauchfuss pp 2406 - 2412; DOI: 10.1021/ic051989z |
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2,4,6-Tris(2-pyridyl)-1,3,5-triazine (tptz)-Derived [RuII(tptz)(acac)(CH3CN)]+ and Mixed-Valent [(acac)2RuIII{(-tptz-H+)-}RuII(acac)(CH3CN)]+ Sandeep Ghumaan, Sanjib Kar, Shaikh M. Mobin, B. Harish, Vedavati G. Puranik, and Goutam Kumar Lahiri pp 2413 - 2423; DOI: 10.1021/ic0514288 |
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Design of Novel Bilayer Compounds of the CPO-8 Type Containing 1D Channels Kjell Ove Kongshaug and Helmer Fjellvåg pp 2424 - 2429; DOI: 10.1021/ic050662v |
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Influence of Water Content on the Self-Assembly of Metal-Organic Frameworks Based on Pyridine-3,5-dicarboxylate Yi-Long Lu, Jing-Yun Wu, Ming-Che Chan, Sheng-Ming Huang, Chia-Shiang Lin, Te-Wei Chiu, Yen-Hsiang Liu, Yuh-Sheng Wen, Chuen-Her Ueng, Tsung-Mei Chin, Chen-Hsiung Hung, and Kuang-Lieh Lu pp 2430 - 2437; DOI: 10.1021/ic0512577 |
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A Bidentate Terephthalamide Ligand, TAMmeg, as an Entry into Terephthalamide-Containing Therapeutic Iron Chelating Agents Kristy M. Clarke Jurchen and Kenneth N. Raymond pp 2438 - 2447; DOI: 10.1021/ic051287+ |
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Mechanism of pH-Dependent Decomposition of Monoalkylamine Diazeniumdiolates to Form HNO and NO, Deduced from the Model Compound Methylamine Diazeniumdiolate, Density Functional Theory, and CBS-QB3 Calculations Andrew S. Dutton, Christopher P. Suhrada, Katrina M. Miranda, David A. Wink, Jon M. Fukuto, and K. N. Houk pp 2448 - 2456; DOI: 10.1021/ic051505z |
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Pericyclic Transition-State-Like Aromaticity in the Inorganic Ions Se2I42+ and S2O42- Qin Zhang, Xin Lu, Rong-Bin Huang, and Lan-Sun Zheng pp 2457 - 2460; DOI: 10.1021/ic051420y |
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Acetylenic Carbon-13 Chemical Shift Tensors for Diphenylacetylene and (2-Diphenylacetylene)Pt(PPh3)2: A Solid-State NMR and Theoretical Study Kristopher J. Harris, Guy M. Bernard, Chris McDonald, Robert McDonald, Michael J. Ferguson, and Roderick E. Wasylishen pp 2461 - 2473; DOI: 10.1021/ic051548f |
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Highly Stable Chiral Cadmium 1,2,4-Benzenetricarboxylate: Synthesis, Structure, and NLO and Fluorescence Properties Lei Wang, Ming Yang, Guanghua Li, Zhan Shi, and Shouhua Feng pp 2474 - 2478; DOI: 10.1021/ic051566x |
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Synthesis and Characterization of f-Element Iodate Architectures with Variable Dimensionality, - and -Am(IO3)3 Wolfgang Runde, Amanda C. Bean, Lia F. Brodnax, and Brian L. Scott pp 2479 - 2482; DOI: 10.1021/ic0516414 |
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Diastereospecific and Diastereoselective Syntheses of Ruthenium(II) Complexes Using N,N' Bidentate Ligands Aryl-pyridin-2-ylmethyl-amine ArNH-CH2-2-C5H4N and Their Oxidation to Imine Ligands Javier Gómez, Gabriel García-Herbosa, José V. Cuevas, Ana Arnáiz, Arancha Carbayo, Asunción Muñoz, Larry Falvello, and Phillip E. Fanwick pp 2483 - 2493; DOI: 10.1021/ic051590a |
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Theoretical Studies of Borazynes and Azaborines Paul J. Fazen and Luke A. Burke pp 2494 - 2500; DOI: 10.1021/ic051649d |
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Isomeric Molecular Rectangles Resulting from Self-Assembly of Dicopper Complexes of Macrocyclic Ligands Anna Company, Laura Gómez, Josep Maria López Valbuena, Ruben Mas-Ballesté, Jordi Benet-Buchholtz, Antoni Llobet, and Miquel Costas pp 2501 - 2508; DOI: 10.1021/ic051759k |
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Photophysics of Platinum-Acetylide Substituted Hexa-peri-hexabenzocoronenes Kye-Young Kim, Shengxia Liu, Muhammet E. Köse, and Kirk S. Schanze pp 2509 - 2519; DOI: 10.1021/ic051788v |
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Structural Variations in Novel Silver(I) Complexes with Bitopic Pyrazole/N-Heterocyclic Carbene Ligands Pei Ling Chiu, Chih Yuan Chen, Chun-Chin Lee, Meng-Hua Hsieh, Chuan-Hung Chuang, and Hon Man Lee pp 2520 - 2530; DOI: 10.1021/ic051840n |
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Orbital Interactions in Fe(II)/Co(III) Heterobimetallocenes: Single versus Double Bridge Ralf Warratz, Gerhard Peters, Felix Studt, René-Hermann Römer, and Felix Tuczek pp 2531 - 2542; DOI: 10.1021/ic051809l |
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Tri-[Pt2Tl]3- and Polynuclear Chain [Pt-Tl]- Complexes Based on Nonbridged PtII-TlI Bonds: Solid State and Frozen Solution Photophysical Properties Larry R. Falvello, Juan Forniés, Raquel Garde, Ana García, Elena Lalinde, M. Teresa Moreno, Alexander Steiner, Milagros Tomás, and Isabel Usón pp 2543 - 2552; DOI: 10.1021/ic051818u |
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Boron Macrocycles Having a Calix-Like Shape. Synthesis, Characterization, X-ray Analysis, and Inclusion Properties Victor Barba, Raúl Villamil, Rolando Luna, Carolina Godoy-Alcántar, Herbert Höpfl, Hiram I. Beltran, Luis S. Zamudio-Rivera, Rosa Santillan, and Norberto Farfán pp 2553 - 2561; DOI: 10.1021/ic051850o |
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Co3(RL)2(hfac)6 Ladder Complex of 5-[4-(N-tert-Butyl-N-aminoxyl)phenyl]pyrimidine Lora M. Field, M. Carmen Morón, Paul M. Lahti, Fernando Palacio, Armando Paduan-Filho, and Nei F. Oliveira Jr. pp 2562 - 2567; DOI: 10.1021/ic051884w |
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Assembly of a New Family of Mercury(II) Zwitterionic Thiolate Complexes from a Preformed Compound [Hg(Tab)2](PF6)2 [Tab = 4-(Trimethylammonio)benzenethiolate] Jin-Xiang Chen, Wen-Hua Zhang, Xiao-Yan Tang, Zhi-Gang Ren, Yong Zhang, and Jian-Ping Lang pp 2568 - 2580; DOI: 10.1021/ic051875n |
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Synthesis, Structure, and Luminescent Properties of Microporous Lanthanide Metal-Organic Frameworks with Inorganic Rod-Shaped Building Units Xiaodan Guo, Guangshan Zhu, Fuxing Sun, Zhongyue Li, Xiaojun Zhao, Xiaotian Li, Hanchang Wang, and Shilun Qiu pp 2581 - 2587; DOI: 10.1021/ic0518881 |
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Synthesis and Structural Characterization of [3-B,S,S-B(mimR)3]Ir(CO)(PPh3)H (R = But, Ph) and [4-B(mimBut)3]M(PPh3)Cl (M = Rh, Ir): Analysis of the Bonding in Metal Borane Compounds Victoria K. Landry, Jonathan G. Melnick, Daniela Buccella, Keliang Pang, Joseph C. Ulichny, and Gerard Parkin pp 2588 - 2597; DOI: 10.1021/ic051975t |
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Effect of the Methyl-Coenzyme-M Reductase Protein Matrix on the Hole-Size and Nonplanar Deformations of Coenzyme F430 Curren Mbofana and Marc Zimmer pp 2598 - 2602; DOI: 10.1021/ic0521832 |
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Metallomacrocycles Incorporating a Hemilabile Tröger's Base Derived Ligand Meisa S. Khoshbin, Maxim V. Ovchinnikov, Chad A. Mirkin, James A. Golen, and Arnold L. Rheingold pp 2603 - 2609; DOI: 10.1021/ic052000b |
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Stabilization of Coordinated Carbonate in Aqueous Acidic Solution: Steric Inhibition of Protonation in Co(III) Complexes Containing Chelated Carbonate Sarah E. Cheyne, Lisa F. McClintock, and Allan G. Blackman pp 2610 - 2618; DOI: 10.1021/ic0521325 |
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Dimolybdenum-Containing Molecular Triangles and Squares with Diamidate Linkers: Structural Diversity and Complexity F. Albert Cotton, Chun Y. Liu, Carlos A. Murillo, and Xiaoping Wang pp 2619 - 2626; DOI: 10.1021/ic0521473 |
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Silver(I) 3-Aminomethylpyridine Complexes, Part 1: Effect of Ligand Ratio, -Stacking, and Temperature with a Noninteracting Anion Rodney P. Feazell, Cody E. Carson, and Kevin K. Klausmeyer pp 2627 - 2634; DOI: 10.1021/ic0512835 |
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Silver(I) 3-Aminomethylpyridine Complexes, Part 2: Effect of Ligand Ratio, Hydrogen Bonding, and -Stacking with an Interacting Anion Rodney P. Feazell, Cody E. Carson, and Kevin K. Klausmeyer pp 2635 - 2643; DOI: 10.1021/ic051284x |
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Catalytic Ability of a Cationic Ru(II) Monochloro Complex for the Asymmetric Hydrogenation of Dimethyl Itaconate and Enamides Isabel Serrano, Montserrat Rodríguez, Isabel Romero, Antoni Llobet, Teodor Parella, Juan M. Campelo, Diego Luna, José M. Marinas, and Jordi Benet-Buchholz pp 2644 - 2651; DOI: 10.1021/ic051032w |
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Calix[4]azacrowns as Novel Molecular Scaffolds for the Generation of Visible and Near-Infrared Lanthanide Luminescence Issam Oueslati, Rute A. Sá Ferreira, Luís D. Carlos, Carlos Baleizão, Mário N. Berberan-Santos, Baltazar de Castro, Jacques Vicens, and Uwe Pischel pp 2652 - 2660; DOI: 10.1021/ic051159l |
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Fiber-Optic Infrared Spectroelectrochemical Studies of Six-Coordinate Manganese Nitrosyl Porphyrins in Nonaqueous Media Zaki N. Zahran, Michael J. Shaw, Masood A. Khan, and George B. Richter-Addo pp 2661 - 2668; DOI: 10.1021/ic051190n |
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Ten-Vertex Iron-Monocarbollide Complexes: Synthesis and Reactivity of the Anion [4,9-{Fe(CO)4}-9,9,9-(CO)3-arachno-9,6-FeCB8H11]- Andreas Franken, Thomas D. McGrath, and F. Gordon A. Stone pp 2669 - 2677; DOI: 10.1021/ic051946i |
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Homoleptic Rare Earth Dipyridylamides [Ln2(N(NC5H4)2)6], Ln = Ce, Nd, Sm, Ho, Er, Tm, Yb, and Sc: Metal Oxidation by the Amine Melt and in 1,2,3,4-Tetrahydroquinoline with the Focus of Different Metal Activation by Amalgams, Liquid Ammonia, and Microwaves Klaus Müller-Buschbaum and Catharina C. Quitmann pp 2678 - 2687; DOI: 10.1021/ic0514795 |
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Synthesis, Structures, and Electrochemistry of Gold(III) Ethylenediamine Complexes and Interactions with Guanosine 5'-Monophosphate Shourong Zhu, Waldemar Gorski, Douglas R. Powell, and Judith A. Walmsley pp 2688 - 2694; DOI: 10.1021/ic051411p |
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Heteroleptic Cu(II) Dipyrromethene Complexes Linked via Hydrogen Bonds, Coordinative Bonds, and Covalent Bonds: Probing the Coordination Environment by Electron Paramagnetic Resonance Spectroscopy Katja Heinze and Anja Reinhart pp 2695 - 2703; DOI: 10.1021/ic0515047 |
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Synthesis of Thin Cr3Se4 Films from Modulated Elemental Reactants via Two Amorphous Intermediates: A Detailed Examination of the Reaction Mechanism Malte Behrens, Ragnar Kiebach, Wolfgang Bensch, Dietrich Häussler, and Wolfgang Jäger pp 2704 - 2712; DOI: 10.1021/ic0515204 |
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Ae2Sb2X4F2 (Ae = Sr, Ba): New Members of the Homologous Series Ae2M1+nX3+nF2 Designed from Rock Salt and Fluorite 2D Building Blocks Houria Kabbour and Laurent Cario pp 2713 - 2717; DOI: 10.1021/ic051969x |
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Cu4Mo6Se8: Synthesis, Crystal Structure, and Electronic Structure of a New Chevrel Phase Structure Type Michael A. McGuire, Chinmoy Ranjan, and Francis J. DiSalvo pp 2718 - 2726; DOI: 10.1021/ic052013p |
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Evidence for the Formation of a cis-Dichlorovinyl Anion upon Reduction of cis-1,2-Dichlorovinyl(pyridine)cobaloxime Angela D. Follett and Kristopher McNeill pp 2727 - 2732; DOI: 10.1021/ic052020d |
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Coinage Metal Complexes of a Boron-Substituted Soft Scorpionate Ligand Christopher A. Dodds, Mark Garner, John Reglinski, and Mark D. Spicer pp 2733 - 2741; DOI: 10.1021/ic052032z |
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Selective Hg(II) Detection in Aqueous Solution with Thiol Derivatized Fluoresceins Elizabeth M. Nolan, Maryann E. Racine, and Stephen J. Lippard pp 2742 - 2749; DOI: 10.1021/ic052083w |
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Characterization of Sol-Gel-Synthesized LiFePO4 by Multiple Scattering XAFS Marco Giorgetti, Mario Berrettoni, Silvera Scaccia, and Stefano Passerini pp 2750 - 2757; DOI: 10.1021/ic0521170 |
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Influence of Solvent Composition on the Kinetics of Cyclooctene Epoxidation by Hydrogen Peroxide Catalyzed by Iron(III) [tetrakis(pentafluorophenyl)] Porphyrin Chloride [(F20TPP)FeCl] Ned A. Stephenson and Alexis T. Bell pp 2758 - 2766; DOI: 10.1021/ic0521776 |
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Synthesis and Thermolysis of Aluminum Amidinates: A Ligand-Exchange Route for New Mixed-Ligand Systems Allison L. Brazeau, Zhaohui Wang, Chris N. Rowley, and Sean T. Barry: pp 2767 - 2767; DOI: 10.1021/ic0680011 |
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Control of Oxygen Atom Chirality and Chelate Ring Conformation by Protected/Free Sugar Hydroxyl Groups in Glucose-Pendant Dipicolylamine-Copper(II) Complexes Yuji Mikata, Yuko Sugai, and Shigenobu Yano: pp 2768 - 2768; DOI: 10.1021/ic060243d |
Issue 7
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Coarse and Fine Tuning of the Electronic Energies of Triimineplatinum(II) Square-Planar Complexes Wei-Hsuan Chen, Eric W. Reinheimer, Kim R. Dunbar, and Mohammad A. Omary pp 2770 - 2772; DOI: 10.1021/ic051518c |
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Early Metal Di- and Tricyanometalates: Useful Building Blocks for Constructing Magnetic Clusters Dongfeng Li, Sean Parkin, Guangbin Wang, Gordon T. Yee, and Stephen M. Holmes pp 2773 - 2775; DOI: 10.1021/ic051630a |
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First Metal Azide Complex with Isonicotinate as a Bridging Ligand Showing New Net Topology: Hydrothermal Synthesis, Structure, and Magnetic Properties Fu-Chen Liu, Yong-Fei Zeng, Jiao Jiao, Xian-He Bu, Joan Ribas, and Stuart R. Batten pp 2776 - 2778; DOI: 10.1021/ic051896h |
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Phase Transitions and Second-Harmonic Generation in Sodium Monothiophosphate Nathan J. Takas and Jennifer A. Aitken pp 2779 - 2781; DOI: 10.1021/ic0520216 |
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Two Chain Compounds of [M(N3)2(HCOO)][(CH3)2NH2] (M = Fe and Co) with a Mixed Azido/Formato Bridge Displaying Metamagnetic Behavior Tao Liu, Yanjuan Zhang, Zheming Wang, and Song Gao pp 2782 - 2784; DOI: 10.1021/ic0521527 |
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[P6Se12]4-: A Phosphorus-Rich Selenophosphate with Low-Valent P Centers In Chung, Angela L. Karst, David P. Weliky, and Mercouri G. Kanatzidis pp 2785 - 2787; DOI: 10.1021/ic0601135 |
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Synthesis, Structures, and Luminescent Properties of Phenol-Pyridyl Boron Complexes Hongyu Zhang, Cheng Huo, Kaiqi Ye, Peng Zhang, Wenjing Tian, and Yue Wang pp 2788 - 2794; DOI: 10.1021/ic051881j |
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Spectroscopic Properties and Electronic Structure of Five- and Six-Coordinate Iron(II) Porphyrin NO Complexes: Effect of the Axial N-Donor Ligand V. K. K. Praneeth, Christian Näther, Gerhard Peters, and Nicolai Lehnert pp 2795 - 2811; DOI: 10.1021/ic050865j |
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Solution and Solid-State Properties of Luminescent M-M Bond-Containing Coordination/Organometallic Polymers Using the RNC-M2(dppm)2-CNR Building Blocks (M = Pd, Pt; R = Aryl, Alkyl) Jean-François Bérubé, Karl Gagnon, Daniel Fortin, Andreas Decken, and Pierre D. Harvey pp 2812 - 2823; DOI: 10.1021/ic0509480 |
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Oscillatory Reactions Involving Hydrogen Peroxide and Thiosulfate-Kinetics of the Oxidation of Tetrathionate by Hydrogen Peroxide Michal Vosla , Pavel Mat jka, and Igor Schreiberpp 2824 - 2834; DOI: 10.1021/ic051355s |
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Quantum Chemistry-Based Analysis of the Vibrational Spectra of Five-Coordinate Metalloporphyrins [M(TPP)Cl] Florian Paulat, V. K. K. Praneeth, Christian Näther, and Nicolai Lehnert pp 2835 - 2856; DOI: 10.1021/ic0510866 |
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Structures, Photoluminescence, Up-Conversion, and Magnetism of 2D and 3D Rare-Earth Coordination Polymers with Multicarboxylate Linkages Jin Yang, Qi Yue, Guo-Dong Li, Jun-Jun Cao, Guang-Hua Li, and Jie-Sheng Chen pp 2857 - 2865; DOI: 10.1021/ic051557o |
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STM/STS Observation of Polyoxoanions on HOPG Surfaces: the Wheel-Shaped [Cu20Cl(OH)24(H2O)12(P8W48O184)]25- and the Ball-Shaped [{Sn(CH3)2(H2O)}24{Sn(CH3)2}12(A-PW9O34)12]36- Mohammad S. Alam, Viacheslav Dremov, Paul Müller, Andrei V. Postnikov, Sib Sankar Mal, Firasat Hussain, and Ulrich Kortz pp 2866 - 2872; DOI: 10.1021/ic051586z |
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Sequential Reaction Intermediates in Aliphatic C-H Bond Functionalization Initiated by a Bis(-oxo)dinickel(III) Complex Jaeheung Cho, Hideki Furutachi, Shuhei Fujinami, Takehiko Tosha, Hideki Ohtsu, Osamu Ikeda, Akane Suzuki, Masaharu Nomura, Tomoya Uruga, Hajime Tanida, Toshihide Kawai, Koji Tanaka, Teizo Kitagawa, and Masatatsu Suzuki pp 2873 - 2885; DOI: 10.1021/ic0514243 |
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Controlling Aggregation of Copper(II)-Based Coordination Compounds: From Mononuclear to Dinuclear, Tetranuclear, and Polymeric Copper Complexes John Fielden, Joanna Sprott, De-Liang Long, Paul Kögerler, and Leroy Cronin pp 2886 - 2895; DOI: 10.1021/ic051647t |
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Syntheses, Structures, Near-Infrared and Visible Luminescence, and Magnetic Properties of Lanthanide-Organic Frameworks with an Imidazole-Containing Flexible Ligand Zheng-Hua Zhang, You Song, Taka-aki Okamura, Yasuchika Hasegawa, Wei-Yin Sun, and Norikazu Ueyama pp 2896 - 2902; DOI: 10.1021/ic0518071 |
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Electronic Properties, Redox Behavior, and Interactions with H2O2 of pH-Sensitive Hydroxyphenyl-1,2,4-triazole-Based Oxovanadium(V) Complexes Wesley R. Browne, Alette G. J. Ligtenbarg, Johannes W. de Boer, Tieme A. van den Berg, Martin Lutz, Anthony L. Spek, Franti ek Hartl, Ronald Hage, and Ben L. Feringapp 2903 - 2916; DOI: 10.1021/ic051848x |
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New Oligophosphines and (Hydroxymethyl)phosphonium Chlorides Dmitry Moiseev, Brian R. James, Brian O. Patrick, and Thomas Q. Hu pp 2917 - 2924; DOI: 10.1021/ic0518935 |
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Dinuclear Copper(II) Complexes with {Cu2(-hydroxo)bis(-carboxylato)}+ Cores and Their Reactions with Sugar Phosphate Esters: A Substrate Binding Model of Fructose-1,6-bisphosphatase Merii Kato, Tomoaki Tanase, and Masahiro Mikuriya pp 2925 - 2941; DOI: 10.1021/ic051942d |
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Weak Exchange Interaction Supported by a Biologically Relevant Long Chemical Bridge in a Cu-Peptide Model Compound Ernanni D. Vieira, Nieves M. C. Casado, Gianella Facchin, Maria H. Torre, Antonio J. Costa-Filho, and Rafael Calvo pp 2942 - 2947; DOI: 10.1021/ic051957b |
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Thermodynamic and Kinetic Studies on Reactions of Pt(II) Complexes with Biologically Relevant Nucleophiles Nadine Summa, Wolfgang Schiessl, Ralph Puchta, Nico van Eikema Hommes, and Rudi van Eldik pp 2948 - 2959; DOI: 10.1021/ic051955r |
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Electronic Structures of KNa3In9 and Na2In, Two Metallic Phases with Classical Closed-Shell Electronic Configurations Bin Li and John D. Corbett pp 2960 - 2964; DOI: 10.1021/ic051981p |
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Supramolecuar Motifs in s-Block Metal-Bound Sulfonated Monoazo Dyes: The Case of Orange G Alan R. Kennedy, Jennifer B. A. Kirkhouse, and Lynda Whyte pp 2965 - 2971; DOI: 10.1021/ic0520115 |
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One Dense and Two Open Chiral Metal-Organic Frameworks: Crystal Structures and Physical Properties Shuangquan Zang, Yang Su, Yizhi Li, Huizhen Zhu, and Qingjin Meng pp 2972 - 2978; DOI: 10.1021/ic0520418 |
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Analogue Reaction Systems of Selenate Reductase Jun-Jieh Wang, Christian Tessier, and R. H. Holm pp 2979 - 2988; DOI: 10.1021/ic0521630 |
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Structural, Thermodynamic, and Mesomorphic Consequences of Replacing Nitrates with Trifluoroacetate Counteranions in Ternary Lanthanide Complexes with Hexacatenar Tridentate Ligands Homayoun Nozary, Stéphane Torelli, Laure Guénée, Emmanuel Terazzi, Gérald Bernardinelli, Bertrand Donnio, Daniel Guillon, and Claude Piguet pp 2989 - 3003; DOI: 10.1021/ic052017u |
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Copper-Dioxygen Adducts and the Side-on Peroxo Dicopper(II)/Bis(-oxo) Dicopper(III) Equilibrium: Significant Ligand Electronic Effects Lanying Q. Hatcher, Michael A. Vance, Amy A. Narducci Sarjeant, Edward I. Solomon, and Kenneth D. Karlin pp 3004 - 3013; DOI: 10.1021/ic052185m |
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Linear Polypseudorotaxanes Possessing Many Metal Centers Constructed from Inclusion Complexes of -, -, and -Cyclodextrins with 4,4'-Dipyridine Ying-Wei Yang, Yong Chen, and Yu Liu pp 3014 - 3022; DOI: 10.1021/ic0601438 |
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Studies of a Dinuclear Manganese Complex with Phenoxo and Bis-acetato Bridging in the Mn2(II,II) and Mn2(II,III) States: Coordination Structural Shifts and Oxidation State Control in Bridged Dinuclear Complexes Yilma Gultneh, Yohannes T. Tesema, Teshome B. Yisgedu, Ray J. Butcher, Guangbin Wang, and Gordon T. Yee pp 3023 - 3033; DOI: 10.1021/ic060039q |
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Catalytic Mechanism of Dopamine -Monooxygenase Mediated by Cu(III)-Oxo Kazunari Yoshizawa, Naoki Kihara, Takashi Kamachi, and Yoshihito Shiota pp 3034 - 3041; DOI: 10.1021/ic0521168 |
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Structure Determination and Relative Properties of Novel Noncentrosymmetric Borates MM'4(BO3)3 (M = Na, M' = Ca and M = K, M' = Ca, Sr) L. Wu, X. L. Chen, Y. P. Xu, and Y. P. Sun pp 3042 - 3047; DOI: 10.1021/ic051494+ |
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Structure and Photochemical Properties of (-Alkoxo)bis(-carboxylato)diruthenium Complexes with Naphthylacetate Ligands Misaki Nakai, Takuzo Funabiki, Chikara Ohtsuki, Masafumi Harada, Akio Ichimura, Rika Tanaka, Isamu Kinoshita, Masahiro Mikuriya, Hiroaki Benten, Hideo Ohkita, Shinzaburo Ito, Makoto Obata, and Shigenobu Yano pp 3048 - 3056; DOI: 10.1021/ic051582u |
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Developing the {M(CO)3}+ Core for Fluorescence Applications: Rhenium Tricarbonyl Core Complexes with Benzimidazole, Quinoline, and Tryptophan Derivatives Lihui Wei, John W. Babich, Wayne Ouellette, and Jon Zubieta pp 3057 - 3066; DOI: 10.1021/ic0517319 |
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Calcium Tetraboride-Does It Exist? Synthesis and Properties of a Carbon-Doped Calcium Tetraboride That Is Isotypic with the Known Rare Earth Tetraborides Ruth Schmitt, Björn Blaschkowski, Klaus Eichele, and H.-Jürgen Meyer pp 3067 - 3073; DOI: 10.1021/ic0518430 |
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The Imidazole Role in Strontium -Diketonate Complexes Formation Fabio Marchetti, Claudio Pettinari, Riccardo Pettinari, Augusto Cingolani, Roberto Gobetto, Michele R. Chierotti, Andrei Drozdov, and Sergey I. Troyanov pp 3074 - 3085; DOI: 10.1021/ic051972g |
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Proton-Transfer and H2-Elimination Reactions of Main-Group Hydrides EH4- (E = B, Al, Ga) with Alcohols Oleg A. Filippov, Andrey M. Filin, Viktoria N. Tsupreva, Natalia V. Belkova, Agustí Lledós, Gregori Ujaque, Lina M. Epstein, and Elena S. Shubina pp 3086 - 3096; DOI: 10.1021/ic052028n |
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Three in One: TSA, TSA', and SA Units in One Crystal Structure of a Yttrium(III) Complex with a Monophosphinated H4dota Analogue Jan Kotek, Jakub Rudovsk  , Petr Hermann, and Ivan Lukepp 3097 - 3102; DOI: 10.1021/ic060006a |
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Crystal Structures of Triazine-3-thione Derivatives by Reaction with Copper and Cobalt Salts Elena López-Torres, M Antonia Mendiola, and César J. Pastor pp 3103 - 3112; DOI: 10.1021/ic052009d |
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Biologically Relevant Phosphoranes: Structural Characterization of Glucofuranose- and Xylofuranose-Based Phosphoranes1 Natalya V. Timosheva, A. Chandrasekaran, and Robert R. Holmes pp 3113 - 3123; DOI: 10.1021/ic052105e |
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DNA Oxidation in Anionic Reverse Micelles: Ruthenium-Mediated Damage at Guanine in Single- and Double-Stranded DNA Sarah E. Evans, Soe Mon, Robinder Singh, Lev R. Ryzhkov, and Veronika A. Szalai pp 3124 - 3132; DOI: 10.1021/ic0521022 |
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Insertion of the Ga(I) Bis-imidinate Ga(DDP) into the Metal Halogen Bonds of Rh(I) Complexes. How Electrophilic Are Coordinated Ga(DDP) Fragments? Andreas Kempter, Christian Gemel, Ned J. Hardman, and Roland A. Fischer pp 3133 - 3138; DOI: 10.1021/ic0521731 |
Issue 8
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Ratiometric Zn2+ Sensor and Strategy for Hg2+ Selective Recognition by Central Metal Ion Replacement Zhikun Wu, Yongfang Zhang, Jin Shi Ma, and Guoqiang Yang pp 3140 - 3142; DOI: 10.1021/ic051589b |
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[NaCuII4] Cluster from Alkali Template Assembly of Two Asymmetric End-On Azido-Bridged [CuII2] Units Prasant Kumar Nanda, Guillem Aromí, and Debashis Ray pp 3143 - 3145; DOI: 10.1021/ic052209p |
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Synthesis, Structural Characterization, and Theoretical Studies of Complexes of Magnesium and Calcium with Gallium Heterocycles Cameron Jones, David P. Mills, Jamie A. Platts, and Richard P. Rose pp 3146 - 3148; DOI: 10.1021/ic060136j |
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Syntheses, Crystal Structures, and Properties of Heterometallic Iodoplumbates: Bicubane, Ribbon, and Chain Configurations Le-Qing Fan, Li-Ming Wu, and Ling Chen pp 3149 - 3151; DOI: 10.1021/ic052211g |
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One-Dimensional -Chloromanganese(II)-Tetrathiafulvalene (TTF) Coordination Compound Chunyang Jia, Shi-Xia Liu, Christina Ambrus, Antonia Neels, Gaël Labat, and Silvio Decurtins pp 3152 - 3154; DOI: 10.1021/ic060056f |
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Highly Efficient, Selective, and General Method for the Preparation of Meridional Homo- and Heteroleptic Tris-cyclometalated Iridium Complexes Shouquan Huo, Joseph C. Deaton, Manju Rajeswaran, and William C. Lenhart pp 3155 - 3157; DOI: 10.1021/ic060089v |
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Dual Emission from Luminescent Nonalanthanide Clusters Steve Comby, Rosario Scopelliti, Daniel Imbert, Loïc Charbonnière, Raymond Ziessel, and Jean-Claude G. Bünzli pp 3158 - 3160; DOI: 10.1021/ic060080t |
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A Polar Luminescent Zn Polymer Containing an Unusual Noninterpenetrated utp Net Jian Zhang, Yu-Biao Chen, Shu-Mei Chen, Zhao-Ji Li, Jian-Kai Cheng, and Yuan-Gen Yao pp 3161 - 3163; DOI: 10.1021/ic060276t |
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Catalytic Reduction of Hydrazine to Ammonia by a Vanadium Thiolate Complex Wei-Cheng Chu, Chi-Chin Wu, and Hua-Fen Hsu pp 3164 - 3166; DOI: 10.1021/ic060171q |
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Adventures with Substances Containing Metals in Negative Oxidation States John E. Ellis pp 3167 - 3186; DOI: 10.1021/ic052110i |
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Characterization of a Bimetallic-Bridging Intermediate in the Reduction of NO to N2O: a Density Functional Theory Study Takehiro Ohta, Teizo Kitagawa, and Constantinos Varotsis pp 3187 - 3190; DOI: 10.1021/ic050991n |
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Structural and Spectroscopic Characterization of Copper(II) Complexes of a New Bisamide Functionalized Imidazole Tripod and Evidence for the Formation of a Mononuclear End-On Cu-OOH Species Lionel E. Cheruzel, Matthew R. Cecil, Sara E. Edison, Mark S. Mashuta, Michael J. Baldwin, and Robert M. Buchanan pp 3191 - 3202; DOI: 10.1021/ic051280s |
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Trisilane-1,3-diolato Complexes of Ti and Zr: Syntheses and X-ray Crystal Structures C. Krempner, M. Köckerling, H. Reinke, and K. Weichert pp 3203 - 3211; DOI: 10.1021/ic0514997 |
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Correlated ab Initio Study of the Excited State of the Iron-Coordinated-Mode Noninnocent Glyoxalbis(mercaptoanil) Ligand Sabri Messaoudi, Vincent Robert, Nathalie Guihéry, and Daniel Maynau pp 3212 - 3216; DOI: 10.1021/ic051526t |
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Crystal Structure and Ionic Conductivity of Three Polymorphic Phases of Rubidium Trifluoromethyl Sulfonate, RbSO3CF3 Lars Hildebrandt, Robert Dinnebier, and Martin Jansen pp 3217 - 3223; DOI: 10.1021/ic0516313 |
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Structural Diversity of the Oxovanadium Organodiphosphonate System: A Platform for the Design of Void Channels Wayne Ouellette, Ming Hui Yu, Charles J. O'Connor, and Jon Zubieta pp 3224 - 3239; DOI: 10.1021/ic0517422 |
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Parametrization of the Magnetic Behavior of the Triangular Spin Ladder Chains Organically Templated: (C2N2H10)[M(HPO3)F3] (MIII = Fe, Cr, and V). Crystal Structure and Thermal and Spectroscopic Properties of the Iron(III) Phase Sergio Fernández-Armas, José L. Mesa, José L. Pizarro, Juan Modesto Clemente-Juan, Eugenio Coronado, María I. Arriortua, and Teófilo Rojo pp 3240 - 3248; DOI: 10.1021/ic051804o |
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Homoleptic Alkaline Earth Metal Bis(trifluoromethanesulfonyl)imide Complex Compounds Obtained from an Ionic Liquid Arash Babai and Anja-Verena Mudring pp 3249 - 3255; DOI: 10.1021/ic051820l |
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Hexagonal and Prismatic Nanowalled ZnO Microboxes Fenghua Zhao, Wenjiao Lin, Mingmei Wu, Ningsheng Xu, Xianfeng Yang, Z. Ryan Tian, and Qiang Su pp 3256 - 3260; DOI: 10.1021/ic051833z |
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Underlying Spin-Orbit Coupling Structure of Intervalence Charge Transfer Bands in Dinuclear Polypyridyl Complexes of Ruthenium and Osmium Deanna M. D'Alessandro, Peter H. Dinolfo, Murray S. Davies, Joseph T. Hupp, and F. Richard Keene pp 3261 - 3274; DOI: 10.1021/ic051841f |
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Hybrid Organic-Inorganic Conductor with a Magnetic Chain Anion: -BETS2[FeIII(C2O4)Cl2] [BETS = Bis(ethylenedithio)tetraselenafulvalene] Bin Zhang, Zheming Wang, Yan Zhang, Kazuyuki Takahashi, Yoshinori Okano, Hengbo Cui, Hayao Kobayashi, Katsuya Inoue, Mohamedally Kurmoo, Francis L. Pratt, and Daoben Zhu pp 3275 - 3280; DOI: 10.1021/ic051870q |
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Syntheses and Structures of Two Low-Dimensional Beryllium Phosphate Compounds: [C5H14N2]2[Be3(HPO4)5]·H2O and [C6H18N2]0.5[Be2(PO4)(HPO4)OH]·0.5H2O Min Guo, Jihong Yu, Jiyang Li, Yi Li, and Ruren Xu pp 3281 - 3286; DOI: 10.1021/ic051906e |
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Novel 3D, 2D, and 0D First-Row Coordination Compounds with 4,4'-Bipyridine-N,N'-dioxide Incorporating Sulfur-Containing Anions Déborah González Mantero, Antonia Neels, and Helen Stoeckli-Evans pp 3287 - 3294; DOI: 10.1021/ic051934x |
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The Mixed-Valent Manganese [3 × 3] Grid [Mn(III)4Mn(II)5(2poap-2H)6](ClO4)10·10H2O, a Mesoscopic Spin-1/2 Cluster Oliver Waldmann, Hans U. Güdel, Timothy L. Kelly, and Laurence K. Thompson pp 3295 - 3300; DOI: 10.1021/ic052055d |
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Weak Metamagnetic-like 1D Manganese(II) Complex with a Double 1,1-Azido Bridge: A Structure and Magnetic Study Anamika Das, Georgina M. Rosair, M. Salah El Fallah, Joan Ribas, and Samiran Mitra pp 3301 - 3306; DOI: 10.1021/ic052088t |
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Structures and Bonding in K0.91U1.79S6 and KU2Se6 Hiroshi Mizoguchi, Danielle Gray, Fu Qiang Huang, and James A. Ibers pp 3307 - 3311; DOI: 10.1021/ic052140l |
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Synthesis and Characterization of Aluminum-Containing Tin(IV) Heterobimetallic Sulfides Zhi Yang, Xiaoli Ma, Vojtech Jancik, Zhensheng Zhang, Herbert W. Roesky, Jörg Magull, Mathias Noltemeyer, Hans-Georg Schmidt, Raymundo Cea-Olivares, and Rubén A. Toscano pp 3312 - 3315; DOI: 10.1021/ic052139m |
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Toward an Accurate Determination of 195Pt Chemical Shifts by Density Functional Computations: The Importance of Unspecific Solvent Effects and the Dependence of Pt Magnetic Shielding Constants on Structural Parameters Mariusz Sterzel and Jochen Autschbach pp 3316 - 3324; DOI: 10.1021/ic052143y |
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Silver(I) Coordination Polymers Based on A Nano-Sized Bent Bis(3-acetylenylphenyl-(4-cyanophenyl))oxadiazole Ligand: The Role of Ligand Isomerism and the Templating Effect of Polyatomic Anions and Solvent Intermediates Yu-Bin Dong, Hong-Xia Xu, Jian-Ping Ma, and Ru-Qi Huang pp 3325 - 3343; DOI: 10.1021/ic052158w |
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Assembly of Lipophilic Tetranuclear (Cu4 and Zn4) Molecular Metallophosphonates from 2,4,6-Triisopropylphenylphosponic Acid and Pyrazole Ligands Vadapalli Chandrasekhar, Palani Sasikumar, Ramamoorthy Boomishankar, and Ganapathi Anantharaman pp 3344 - 3351; DOI: 10.1021/ic060003y |
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Imino Sulfinamidines: Synthesis and Coordination Chemistry of a Novel Class of Chiral Bidentate Ligands Anthony G. M. Barrett, Andrew A. Gray, Michael S. Hill, Peter B. Hitchcock, Panayiotis A. Procopiou, and Andrew J. P. White pp 3352 - 3358; DOI: 10.1021/ic052104m |
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Metal Coordination by Sterically Hindered Heterocyclic Ligands, Including 2-Vinylpyridine, Assessed by Investigation of Cobaloximes Patrizia Siega, Lucio Randaccio, Patricia A. Marzilli, and Luigi G. Marzilli pp 3359 - 3368; DOI: 10.1021/ic051383a |
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Syntheses and Molecular Structure of Some Rh and Ru Complexes with the Chelating Diphenyl (2-Pyridyl)phosphine Ligand Katarzyna Wajda-Hermanowicz, Zbigniew Ciunik, and Andrzej Kochel pp 3369 - 3377; DOI: 10.1021/ic051442k |
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Investigation of Tetrahedral Mixed-Metal Carbonyl Clusters by Two-Dimensional 59Co COSY and DQFCOSY NMR Experiments Pierre Kempgens, Karim Elbayed, Jésus Raya, Pierre Granger, Jacky Rosé, and Pierre Braunstein pp 3378 - 3383; DOI: 10.1021/ic051544a |
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Unsaturation in Binuclear Cyclopentadienyliron Carbonyls Hongyan Wang, Yaoming Xie, R. Bruce King, and Henry F. Schaefer III pp 3384 - 3392; DOI: 10.1021/ic051613l |
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EXAFS and IR Structural Study of Platinum-Based Anticancer Drugs' Degradation by Diethyl Dithiocarbamate Diane Bouvet, Alain Michalowicz, Sylvie Crauste-Manciet, Denis Brossard, and Karine Provost pp 3393 - 3398; DOI: 10.1021/ic051904u |
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The Electronic Ground State of [V(urea)6]3+ Probed by NIR Luminescence, Electronic Raman, and High-Field EPR Spectroscopies Rémi Beaulac, Philip L. W. Tregenna-Piggott, Anne-Laure Barra, H  gni Weihe, Dominique Luneau, and Christian Reberpp 3399 - 3407; DOI: 10.1021/ic051709f |
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Crystallization of Zeolites from Organo-Silicic Colloids Graciela Pacheco-Malagón, Patricia Pérez-Romo, Norma A. Sánchez-Flores, María L. Guzmán-Castillo, Carlos López-Franco, José M. Saniger, Francisco Hernández-Beltrán, and José J. Fripiat pp 3408 - 3414; DOI: 10.1021/ic051929t |
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Oxidation of Iodide by a Series of Fe(III) Complexes in Acetonitrile Xiaoguang Wang and David M. Stanbury pp 3415 - 3423; DOI: 10.1021/ic052022y |
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Synthetic Analogues of the Active Site of the A-Cluster of Acetyl Coenzyme A Synthase/CO Dehydrogenase: Syntheses, Structures, and Reactions with CO Todd C. Harrop, Marilyn M. Olmstead, and Pradip K. Mascharak pp 3424 - 3436; DOI: 10.1021/ic0520465 |
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Lanthanum and Alkali Metal Coordination Chemistry of the Bis(dimethylphenylsilyl)amide Ligand William J. Evans, Daniel B. Rego, and Joseph W. Ziller pp 3437 - 3443; DOI: 10.1021/ic052091c |
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Density Functional Theory Studies of Actinide(III) Motexafins (An-Motex2+, An = Ac, Cm, Lr). Structure, Stability, and Comparison with Lanthanide(III) Motexafins Xiaoyan Cao, Quansong Li, Anna Moritz, Zhizhong Xie, Michael Dolg, Xuebo Chen, and Weihai Fang pp 3444 - 3451; DOI: 10.1021/ic052128t |
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Synthesis and Characterization of Rhenium-Copper Sulfide Cluster Complexes [(Ph3P)2N][Re3(CuX)(3-S)4Cl6(PMe2Ph)3] (X = Cl, Br, I) Kazuya Iijima, Tomoaki Sunaga, Masaya Hirose, and Taro Saito pp 3452 - 3455; DOI: 10.1021/ic052135h |
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Cu(I) Dinuclear Complexes with Tripodal Ligands vs Monodentate Donors: Triphenylphosphine, Thiourea, and Pyridine. A 1H NMR Titration Study Marcello Gennari, Maurizio Lanfranchi, Luciano Marchiò, Maria Angela Pellinghelli, Matteo Tegoni, and Roberto Cammi pp 3456 - 3466; DOI: 10.1021/ic052129l |
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Olefin Epoxidation by the Hydrogen Peroxide Adduct of a Novel Non-heme Mangangese(IV) Complex: Demonstration of Oxygen Transfer by Multiple Mechanisms Guochuan Yin, Maria Buchalova, Andrew M. Danby, Chris M. Perkins, David Kitko, John D. Carter, William M. Scheper, and Daryle H. Busch pp 3467 - 3474; DOI: 10.1021/ic0522030 |
Issue 9
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Highly Active Titanium-Based Olefin Polymerization Catalysts Supported by Bidentate Phenoxyamide Ligands Daniel C. H. Oakes, Vernon C. Gibson, Andrew J. P. White, and David J. Williams pp 3476 - 3477; DOI: 10.1021/ic060146k |
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New Cuprates Featuring Ladderlike Periodic Arrays of [Cu3O8]10- Trimeric Magnetic Nanostructures Xunhua Mo, Kristen M. S. Etheredge, Shiou-Jyh Hwu, and Qun Huang pp 3478 - 3480; DOI: 10.1021/ic060292q |
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Manganese Complexes of 1,3,5-Triaza-7-phosphaadamantane (PTA): The First Nitrogen-Bound Transition-Metal Complex of PTA Brian J. Frost, Carolyn M. Bautista, Rongcai Huang, and Jason Shearer pp 3481 - 3483; DOI: 10.1021/ic060322p |
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Pyrazolate-Bridging Dinucleating Ligands Containing Hydrogen-Bond Donors: Synthesis and Structure of Their Cobalt Analogues Paul J. Zinn, Douglas R. Powell, Victor W. Day, Michael P. Hendrich, Thomas N. Sorrell, and A. S. Borovik pp 3484 - 3486; DOI: 10.1021/ic060009n |
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Assembly of a Heterobinuclear 2-D Network: A Rare Example of Endo- and Exocyclic Coordination of PdII/AgI in a Single Macrocycle Il Yoon, Joobeom Seo, Ji-Eun Lee, Ki-Min Park, Jae Sang Kim, Myoung Soo Lah, and Shim Sung Lee pp 3487 - 3489; DOI: 10.1021/ic060005i |
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Synthesis and Structure of the Bilayer Hydrate Na0.3NiO2·1.3D2O Sangmoon Park, Yongjae Lee, Margaret Elcombe, and Thomas Vogt pp 3490 - 3492; DOI: 10.1021/ic060235x |
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Large-Scale Fabrication of TiO2 Hierarchical Hollow Spheres Xiaoxu Li, Yujie Xiong, Zhengquan Li, and Yi Xie pp 3493 - 3495; DOI: 10.1021/ic0602502 |
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Synthesis of Boron-Iodinated o-Carborane Derivatives. Water Stability of the Periodinated Monoprotic Salt Francesc Teixidor, Gemma Barberà, Clara Viñas, Reijo Sillanpää, and Raikko Kivekäs pp 3496 - 3498; DOI: 10.1021/ic060124y |
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Molecular and Electronic Structures of Oxo-bis(benzene-1,2-dithiolato)chromate(V) Monoanions. A Combined Experimental and Density Functional Study Ruta Kapre, Kallol Ray, Isabelle Sylvestre, Thomas Weyhermüller, Serena DeBeer George, Frank Neese, and Karl Wieghardt pp 3499 - 3509; DOI: 10.1021/ic051844s |
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Di- and Trinuclear Complexes Derived from Hexakis(2-pyridyloxy)cyclotriphosphazene. Unusual P-O Bond Cleavage in the Formation of [{(L'CuCl)2(Co(NO3)}Cl] (L' = N3P3(OC5H4N)5(O)) Vadapalli Chandrasekhar, Balasubramanian Murugesa Pandian, and Ramachandran Azhakar pp 3510 - 3518; DOI: 10.1021/ic0517467 |
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NMR and EPR Studies of Chloroiron(III) Tetraphenyl-chlorin and Its Complexes with Imidazoles and Pyridines of Widely Differing Basicities Sheng Cai, Tatjana Kh. Shokhireva, Dennis L. Lichtenberger, and F. Ann Walker pp 3519 - 3531; DOI: 10.1021/ic0515352 |
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Titanium(III) Trisamidotriazacyclononane: Reactions with C60 and Radicals Sónia Barroso, Jinlan Cui, Alberto R. Dias, M. Teresa Duarte, Humberto Ferreira, Rui T. Henriques, M. Conceição Oliveira, José R. Ascenso, and Ana M. Martins pp 3532 - 3537; DOI: 10.1021/ic0516156 |
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Syntheses, Crystal Structures, and Magnetic Characterization of Five New Dimeric Manganese(III) Tetradentate Schiff Base Complexes Exhibiting Single-Molecule-Magnet Behavior Zhengliang Lü, Mei Yuan, Feng Pan, Song Gao, Deqing Zhang, and, and Daoben Zhu pp 3538 - 3548; DOI: 10.1021/ic051648l |
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Citrate, in Collaboration with a Guanidinium Ion, as a Generator of Cubane-like Complexes with a Range of Metal Cations: Synthesis, Structures, and Magnetic Properties of [C(NH2)3]8[(MII)4(cit)4]·8H2O (M = Mg, Mn, Fe, Co, Ni, and Zn; cit = Citrate) Timothy A. Hudson, Kevin J. Berry, Boujemaa Moubaraki, Keith S. Murray, and Richard Robson pp 3549 - 3556; DOI: 10.1021/ic051779m |
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Synthesis, Molecular and Electronic Structure, and TDDFT and TDDFT-PCM Study of the Solvatochromic Properties of (Me2Pipdt)Mo(CO)4 Complex (Me2Pipdt = N,N'-Dimethylpiperazine-2,3-dithione) Victor N. Nemykin, Joseph G. Olsen, Eranda Perera, and Partha Basu pp 3557 - 3568; DOI: 10.1021/ic051653p |
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Copper(II) Hexaaza Macrocyclic Binuclear Complexes Obtained from the Reaction of Their Copper(I) Derivates and Molecular Dioxygen Miquel Costas, Xavi Ribas, Albert Poater, Josep Maria López Valbuena, Raül Xifra, Anna Company, Miquel Duran, Miquel Solà, Antoni Llobet, Montserrat Corbella, Miguel Angel Usón, José Mahía, Xavier Solans, Xiaopeng Shan, and Jordi Benet-Buchholz pp 3569 - 3581; DOI: 10.1021/ic051800j |
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Structure, Luminescence, and Adsorption Properties of Two Chiral Microporous Metal-Organic Frameworks Qianrong Fang, Guangshan Zhu, Ming Xue, Jinyu Sun, Fuxing Sun, and Shilun Qiu pp 3582 - 3587; DOI: 10.1021/ic051810k |
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Syntheses, Structures, Ionic Conductivities, and Magnetic Properties of Three New Transition-Metal Borophosphates Na5(H3O){MII3[B3O3(OH)]3(PO4)6}·2H2O (MII = Mn, Co, Ni) Miao Yang, Jihong Yu, Jiancheng Di, Jiyang Li, Peng Chen, Qianrong Fang, Yan Chen, and Ruren Xu pp 3588 - 3593; DOI: 10.1021/ic051916f |
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Effects of Tris(pyrazolyl)borato Ligand Substituents on Dioxygen Activation and Stabilization by Copper Compounds Gabriel Aullón, Sergiu M. Gorun, and Santiago Alvarez pp 3594 - 3601; DOI: 10.1021/ic0519279 |
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Synthesis, Structure, and Characterization of Novel Two- and Three-Dimensional Vanadates: Ba2.5(VO2)3(SeO3)4·H2O and La(VO2)3(TeO6)·3H2O T. Sivakumar, Kang Min Ok, and P. Shiv Halasyamani pp 3602 - 3605; DOI: 10.1021/ic052103u |
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Multiple Bicyclic Diamide-Lutetium Complexes in Solution: Chemometric Analysis of Deep-UV Raman Spectroscopic Data Victor A. Shashilov, Vladimir V. Ermolenkov, and Igor K. Lednev pp 3606 - 3612; DOI: 10.1021/ic0600331 |
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Mechanistic Information from Low-Temperature Rapid-Scan and NMR Measurements on the Protonation and Subsequent Reductive Elimination Reaction of a (Diimine)platinum(II) Dimethyl Complex Bror J. Wik, Ivana Ivanovic-Burmazovic, Mats Tilset, and Rudi van Eldik pp 3613 - 3621; DOI: 10.1021/ic0519537 |
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Synthesis and Thermodynamic Evaluation of Mixed Hexadentate Linear Iron Chelators Containing Hydroxypyridinone and Terephthalamide Units1 Rebecca J. Abergel and Kenneth N. Raymond pp 3622 - 3631; DOI: 10.1021/ic052111a |
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Determination of the Solution Structures of Melamine-Based Bis- and Tris-Macrocyclic Ligand Copper(II) Complexes Peter Comba, Yaroslav D. Lampeka, Alexander I. Prikhod'ko, and Gopalan Rajaraman pp 3632 - 3638; DOI: 10.1021/ic052124o |
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Equatorially Connected Diruthenium(II,III) Units toward Paramagnetic Supramolecular Structures with Singular Magnetic Properties M. Carmen Barral, Teresa Gallo, Santiago Herrero, Reyes Jiménez-Aparicio, M. Rosario Torres, and Francisco A. Urbanos pp 3639 - 3647; DOI: 10.1021/ic052174t |
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Borohydride, Azide, and Chloride Anions As Terminal Ligands on Fe/Mo/S Clusters. Synthesis, Structure and Characterization of [(Cl4-cat)(PPr3) MoFe3S4(X)2]2(Bu4N)4 and [(Cl4-cat)(PPr3)MoFe3S4 (PPr3)(X)]2(Bu4N)2 (X = N3-, BH4-, Cl-) Double-Fused Cubanes. NMR Reactivity Studies of [(Cl4-cat)(PPr3) MoFe3S4(BH4)2]2(Bu4N)4 Markos Koutmos, Irene P. Georgakaki, and Dimitri Coucouvanis pp 3648 - 3656; DOI: 10.1021/ic052156b |
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Fe(III)-Coordination Properties of Neuromelanin Components: 5,6-Dihydroxyindole and 5,6-Dihydroxyindole-2-carboxylic Acid Louise K. Charkoudian and Katherine J. Franz pp 3657 - 3664; DOI: 10.1021/ic060014r |
Synthesis, Structure, and Magnetic Properties of Cs2-xRbxCu3P4O14 (0.0  x 0.8): A New Series of Copper(II) Phosphates Containing Periodic Arrays of Staggered Square-Planar CuO4 TrimersK. G. Sanjaya Ranmohotti, Xunhua Mo, M. Kirklyn Smith, and Shiou-Jyh Hwu pp 3665 - 3670; DOI: 10.1021/ic060069t |
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2D and 3D Cu(hfac)2 Complexes with Nitronyl Nitroxide Biradicals Eugene Tretyakov, Sergei Fokin, Galina Romanenko, Vladimir Ikorskii, Sergei Vasilevsky, and Victor Ovcharenko pp 3671 - 3678; DOI: 10.1021/ic060132e |
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Three Novel Silver Complexes with Ligand-Unsupported Argentophilic Interactions and Their Luminescent Properties Xi Liu, Guo-Cong Guo, Ming-Lai Fu, Xue-Hui Liu, Ming-Sheng Wang, and Jin-Shun Huang pp 3679 - 3685; DOI: 10.1021/ic0601539 |
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Porphyrazines as Molecular Scaffolds: Flexible Syntheses of Novel Multimetallic Complexes Tomasz Goslinski, Chang Zhong, Matthew J. Fuchter, Charlotte L. Stern, Andrew J. P. White, Anthony G. M. Barrett, and Brian M. Hoffman pp 3686 - 3694; DOI: 10.1021/ic060176n |
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Novel Cation [N(SO2NMe3)2]+ and Its Synthesis and Crystal Structure. Dichloride of Imido-bis(sulfuric) Acid HN(SO2Cl)2. Part 1. Crystal Structures of KN(SO2Cl)2·(1/2)CH3CN, KN(SO2Cl)2·(1/6)CH2Cl2, and [PCl4][N(SO2Cl)2] J. Taraba and Z. Zak pp 3695 - 3700; DOI: 10.1021/ic051628j |
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Memory Devices Based on Lanthanide (Sm3+, Eu3+, Gd3+) Complexes Junfeng Fang, Han You, Jiangshan Chen, Jian Lin, and Dongge Ma pp 3701 - 3704; DOI: 10.1021/ic051783y |
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Various Coordination Modes of the Bis(di(o-N,N-dimethylanilinyl)phosphino)methane Ligand in Mononuclear and Binuclear Complexes of Group 8 and Group 9 Metals James N. L. Dennett, Matthias Bierenstiel, Michael J. Ferguson, Robert McDonald, and Martin Cowie pp 3705 - 3717; DOI: 10.1021/ic051639c |
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Pressure Effect on Bulk Weak Ferromagnets: (BDH-TTP)[M(isoq)2(NCS)4] (M = CrIII, FeIII; isoq = Isoquinoline) Satoshi Kudo, Akira Miyazaki, Toshiaki Enoki, Stéphane Golhen, Lahcène Ouahab, Takashi Toita, and Jun-ichi Yamada pp 3718 - 3725; DOI: 10.1021/ic0518778 |
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Extending the Time: Solvothermal Syntheses, Crystal Structures, and Properties of Two Non-isostructural Thioantimonates with the Composition [Mn(tren)]Sb2S4 Michael Schaefer, Daniel Kurowski, Arno Pfitzner, Christian Näther, Zomaje Rejai, Karina Möller, Nancy Ziegler, and Wolfgang Bensch pp 3726 - 3731; DOI: 10.1021/ic0519739 |
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Mechanistic Analysis of the Electrocatalytic Properties of Dissolved and Isomers of [SiW12O40]4- and Solid [Ru(bipy)3]2[-SiW12O40] on the Reduction of Nitrite in Acidic Aqueous Media Jie Zhang, Joo-Kheng Goh, Wee-Tee Tan, and Alan M. Bond pp 3732 - 3740; DOI: 10.1021/ic0519943 |
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A Three-Dimensional Framework Structure Constructed from 2-(2-Pyridyl-N-oxide) Ethylphosphonic Acid and Nd(III) Xin-min Gan, Brian M. Rapko, Jesse Fox, Iris Binyamin, Sylvie Pailloux, Eileen N. Duesler, and Robert T. Paine pp 3741 - 3745; DOI: 10.1021/ic051937+ |
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Synthesis, X-ray Crystal Structures, Magnetism, and Phosphate Ester Cleavage Properties of Copper(II) Complexes of N-Substituted Derivatives of 1,4,7-Triazacyclononane Matthew J. Belousoff, Martin B. Duriska, Bim Graham, Stuart R. Batten, Boujemaa Moubaraki, Keith S. Murray, and Leone Spiccia pp 3746 - 3755; DOI: 10.1021/ic051983+ |
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Photophysical Properties and Excitation Polarization of fac/mer-Ruthenium Complexes with 5'-Amino-2,2'-bipyridine-5-carboxylic Acid Derivatives Masato Kyakuno, Shigero Oishi, and Hitoshi Ishida pp 3756 - 3765; DOI: 10.1021/ic052002w |
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Thermal Degradation of Acetate-Intercalated Hydroxy Double and Layered Hydroxy Salts Everson Kandare and Jeanne M. Hossenlopp pp 3766 - 3773; DOI: 10.1021/ic060071k |
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Synthesis, Structure, and Properties of an Fe(II) Carbonyl [(PaPy3)Fe(CO)](ClO4): Insight into the Reactivity of Fe(II)-CO and Fe(II)-NO Moieties in Non-Heme Iron Chelates of N-Donor Ligands Raman K. Afshar, Apurba K. Patra, Eckhard Bill, Marilyn M. Olmstead, and Pradip K. Mascharak pp 3774 - 3781; DOI: 10.1021/ic060020n |
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Solid State Molecular Structures of Transition Metal Hexafluorides Thomas Drews, Joanna Supe  , Adelheid Hagenbach, and Konrad Seppeltpp 3782 - 3788; DOI: 10.1021/ic052029f |
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Effects of Steric Constraint on Chromium(III) Complexes of Tetraazamacrocycles. 3. Insights into the Temperature-Dependent Radiationless Deactivation of the 2Eg (Oh) Excited State of trans-[Cr(N4)(CN)2]+ Complexes Michael T. Vagnini, Noel A. P. Kane-Maguire, and Paul S. Wagenknecht pp 3789 - 3793; DOI: 10.1021/ic052170o |
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Heteroleptic Bis(Phthalocyaninato) Europium(III) Complexes Fused with Different Numbers of 15-Crown-5 Moieties. Synthesis, Spectroscopy, Electrochemistry, and Supramolecular Structure Ning Sheng, Renjie Li, Chi-Fung Choi, Wei Su, Dennis K. P. Ng, Xuegui Cui, Kengo Yoshida, Nagao Kobayashi, and Jianzhuang Jiang pp 3794 - 3802; DOI: 10.1021/ic0600937 |
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CO2 Fixation by Cu2+ and Zn2+ Complexes of a Terpyridinophane Aza Receptor. Crystal Structures of Cu2+ Complexes, pH-Metric, Spectroscopic, and Electrochemical Studies Begoña Verdejo, Juan Aguilar, Enrique García-España, Pablo Gaviña, Julio Latorre, Conxa Soriano, José M. Llinares, and Antonio Doménech pp 3803 - 3815; DOI: 10.1021/ic060278d |
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Synthesis and Characterization of Triazenide and Triazene Complexes of Ruthenium and Osmium Gabriele Albertin, Stefano Antoniutti, Marco Bedin, Jesús Castro, and Soledad Garcia-Fontán pp 3816 - 3825; DOI: 10.1021/ic052063u |
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Synthesis of Organically Templated Nanoporous Tin(II/IV) Phosphate for Radionuclide and Metal Sequestration Dawn M. Wellman, Shas V. Mattigod, Kent E. Parker, Steve M.Heald, Chongmin Wang, and Glen E. Fryxell: pp 3826 - 3826; DOI: 10.1021/ic068003l |
Issue 10
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Crystal Structures of Extended Europium Cyanamide-Carbodiimide Compounds Derived from Different Reaction Conditions: Temperature-Controlled Syntheses of In0.08Eu4(NCN)3I3, Eu8I9(CN)(NCN)3, and In0.28Eu12(NCN)5I14.91 Wuping Liao and Richard Dronskowski pp 3828 - 3830; DOI: 10.1021/ic051899u |
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Metal Salen Derivatives as Catalysts for the Alternating Copolymerization of Oxetanes and Carbon Dioxide To Afford Polycarbonates Donald J. Darensbourg, Poulomi Ganguly, and Wonsook Choi pp 3831 - 3833; DOI: 10.1021/ic052109j |
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Mechanism of Water Exchange in Aqueous Uranyl(VI) Ion. A Density Functional Molecular Dynamics Study Michael Bühl and Hendrik Kabrede pp 3834 - 3836; DOI: 10.1021/ic060156l |
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Polymorphic Alternating HNN-Cobalt(II) Chains Both Behaving as Single-Chain Magnets (HNN = 4,4,5,5-Tetramethylimidazolin-1-oxyl 3-Oxide) Norio Ishii, Takayuki Ishida, and Takashi Nogami pp 3837 - 3839; DOI: 10.1021/ic052119k |
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Tripodal Bis(imidazole) Thioether Copper(I) Complexes: Mimics of the Cu(B) Site of Hydroxylase Enzymes L. Zhou, D. Powell, and K. M. Nicholas pp 3840 - 3842; DOI: 10.1021/ic052121b |
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Decarboxylation of 2,2'-Bipyridinyl-4,4'-dicarboxylic Acid Diethyl Ester during Microwave Synthesis of the Corresponding Trichelated Ruthenium Complex Thomas J. Anderson, Jill R. Scott, Frank Millett, and Bill Durham pp 3843 - 3845; DOI: 10.1021/ic060008v |
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Particular Topological Complexity of Lead Oxide Blocks in Pb31O22X18 (X = Br, Cl) Sergey V. Krivovichev, Oleg I. Siidra, Evgenii V. Nazarchuk, Peter C. Burns, and Wulf Depmeier pp 3846 - 3848; DOI: 10.1021/ic060166m |
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First Crystal Structure Studies of CaAlH5 Claudia Weidenthaler, Terry J. Frankcombe, and Michael Felderhoff pp 3849 - 3851; DOI: 10.1021/ic0602042 |
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Bis[iridium(I)] Complex of Inverted N-Confused Porphyrin Motoki Toganoh, Jo Konagawa, and Hiroyuki Furuta pp 3852 - 3854; DOI: 10.1021/ic060203+ |
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Interweaving of Triple-Helical and Extended Metal-O-Metal Single-Helical Chains with the Same Helix Axis in a 3D Metal-Organic Framework Shuangquan Zang, Yang Su, Yizhi Li, Zhaoping Ni, Huizhen Zhu, and Qingjin Meng pp 3855 - 3857; DOI: 10.1021/ic060286u |
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Synthesis and Structure of Dilacunary Decatungstogermanate, [-GeW10O36]8- Nadeen H. Nsouli, Bassem S. Bassil, Michael H. Dickman, Ulrich Kortz, Bineta Keita, and Louis Nadjo pp 3858 - 3860; DOI: 10.1021/ic0603252 |
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Synthesis and Structure of K3Mg20In14, a Stuffed Variant of the BaHg11 Structure Type with a Magnesium-Indium Network Bin Li and John D. Corbett pp 3861 - 3863; DOI: 10.1021/ic060215v |
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Thallophilic Interactions in Aryloxide Compounds: the {Tl2(2-OAr)4} Structural Motif in (TlOAr)4 and Tl2Cu(OAr)4 Compounds Montana V. Childress, David Millar, Todd M. Alam, Kevin A. Kreisel, Glenn P. A. Yap, Lev N. Zakharov, James A. Golen, Arnold L. Rheingold, and Linda H. Doerrer pp 3864 - 3877; DOI: 10.1021/ic050955o |
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Toward a More General Synthetic Route to Paramagnetic Solids Containing RCNSSS+ Radical Cations. A Structure-Property Correlation for RCNSSS+ (R = F5C2, Cl3C) Andreas Decken, Saba M. Mattar, Jack Passmore, Konstantin V. Shuvaev, and Laurence K. Thompson pp 3878 - 3886; DOI: 10.1021/ic050577n |
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Local Structure of Actinide Dioxide Solid Solutions Th1-xUxO2 and Th1-xPuxO2 S. Hubert, J. Purans, G. Heisbourg, P. Moisy, and N. Dacheux pp 3887 - 3894; DOI: 10.1021/ic050888y |
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Structural and Photophysical Properties of Coordination Networks Combining [Ru(Bpym)(CN)4]2- or [{Ru(CN)4}2(-bpym)]4- Anions (bpym = 2,2'-Bipyrimidine) with Lanthanide(III) Cations: Sensitized Near-Infrared Luminescence from Yb(III), Nd(III), and Er(III) Following Ru-to-Lanthanide Energy Transfer Juan-Manuel Herrera, Simon J. A. Pope, Harry Adams, Stephen Faulkner, and Michael D. Ward pp 3895 - 3904; DOI: 10.1021/ic0521574 |
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Coordination Chemistry of Tetradentate N-Donor Ligands Containing Two Pyrazolyl-Pyridine Units Separated by a 1,8-Naphthyl Spacer: Dodecanuclear and Tetranuclear Coordination Cages and Cyclic Helicates Stephen P. Argent, Harry Adams, Thomas Riis-Johannessen, John C. Jeffery, Lindsay P. Harding, Olimpia Mamula, and Michael D. Ward pp 3905 - 3919; DOI: 10.1021/ic060157d |
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A New Structural Motif for Biological Iron: Iron K-Edge XAS Reveals a [Fe4--(OR)5(OR)9-10] Cluster in the Ascidian Perophora annectens Patrick Frank, Anthony DeTomaso, Britt Hedman, and Keith O. Hodgson pp 3920 - 3931; DOI: 10.1021/ic051445x |
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Structure and Magnetism of [M3]6/7+ Metal Chain Complexes from Density Functional Theory: Analysis for Copper and Predictions for Silver M. Bénard, J. F. Berry, F. A. Cotton, C. Gaudin, X. López, C. A. Murillo, and M.-M. Rohmer pp 3932 - 3940; DOI: 10.1021/ic051799o |
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Metal-Organic Architectures of Silver(I), Cadmium(II), and Copper(II) with a Flexible Tricarboxylate Ligand Hui-Fang Zhu, Jian Fan, Taka-aki Okamura, Zheng-Hua Zhang, Guang-Xiang Liu, Kai-Bei Yu, Wei-Yin Sun, and Norikazu Ueyama pp 3941 - 3948; DOI: 10.1021/ic051925o |
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Construction of 3d-4f Mixed-Metal Complexes Based on a Binuclear Oxovanadium Unit: Synthesis, Crystal Structure, EPR, and Magnetic Properties Wei Shi, Xiao-Yan Chen, Bin Zhao, Ao Yu, Hai-Bin Song, Peng Cheng, Hong-Gen Wang, Dai-Zheng Liao, and Shi-Ping Yan pp 3949 - 3957; DOI: 10.1021/ic051979y |
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A Computational Study of the Nondissociative Mechanisms that Interchange Apical and Equatorial Atoms in Square Pyramidal Molecules Henry S. Rzepa and Marion E. Cass pp 3958 - 3963; DOI: 10.1021/ic0519988 |
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Tetrahedral Co(II) Coordination in -Type Cobalt Hydroxide: Rietveld Refinement and X-ray Absorption Spectroscopy Renzhi Ma, Zhaoping Liu, Kazunori Takada, Katsutoshi Fukuda, Yasuo Ebina, Yoshio Bando, and Takayoshi Sasaki pp 3964 - 3969; DOI: 10.1021/ic052108r |
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Aluminum Phosphinate and Phosphates of Salen Ligands Amitabha Mitra, Sean Parkin, and David A. Atwood pp 3970 - 3975; DOI: 10.1021/ic052090k |
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2D Hydrogen-Bonded Square-Grid Coordination Networks with a Substitution-Active Metal Site Kanji Takaoka, Masaki Kawano, Toshiya Hozumi, Shin-ichi Ohkoshi, and Makoto Fujita pp 3976 - 3982; DOI: 10.1021/ic052138u |
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Porphyrazines Peripherally Functionalized with Hybrid Ligands as Molecular Scaffolds for Bimetallic Metal-Ion Coordination Chang Zhong, Min Zhao, Tomasz Goslinski, Charlotte Stern, Anthony G. M. Barrett, and Brian M. Hoffman pp 3983 - 3989; DOI: 10.1021/ic052169p |
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Structural and Spectroscopic Characterization of a Diruthenium o-Dioxolene Complex Possessing a Singly Occupied Molecular Orbital Delocalized over the Entire Molecule, [Ru2(3,6-DTBDiox)4]- Katsunori Mochizuki, Takashi Kawamura, Ho-Chol Chang, and Susumu Kitagawa pp 3990 - 3997; DOI: 10.1021/ic052180p |
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Controllable Assembly of Metal-Directed Coordination Polymers under Diverse Conditions: A Case Study of the MII-H3tma/Bpt Mixed-Ligand System Miao Du, Xiu-Juan Jiang, and Xiao-Jun Zhao pp 3998 - 4006; DOI: 10.1021/ic060001d |
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Effects of Axial Coordination on the Ru-Ru Single Bond in Diruthenium Paddlewheel Complexes Sanjib K. Patra, Nabanita Sadhukhan, and Jitendra K. Bera pp 4007 - 4015; DOI: 10.1021/ic0600073 |
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Influence of Steric Hindrance of Organic Ligand on the Structure of Keggin-Based Coordination Polymer Yan-Ping Ren, Xiang-Jian Kong, Xiang-Yang Hu, Meng Sun, La-Sheng Long, Rong-Bin Huang, and Lan-Sun Zheng pp 4016 - 4023; DOI: 10.1021/ic060004q |
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Synthesis and Photochemistry of a Two-Position Ru(terpy)(phen)(L)2+ Scorpionate Complex Sylvestre Bonnet, Jean-Paul Collin, and Jean-Pierre Sauvage pp 4024 - 4034; DOI: 10.1021/ic060029p |
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Increasing Structure Dimensionality of Copper(I) Complexes by Varying the Flexible Thioether Ligand Geometry and Counteranions Rong Peng, Dan Li, Tao Wu, Xiao-Ping Zhou, and Seik Weng Ng pp 4035 - 4046; DOI: 10.1021/ic060074x |
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Unusual Mn-Mn Spin Coupling in the Polar Intermetallic Compounds CaMn2Sb2 and SrMn2Sb2 Svilen Bobev, Justin Merz, Ana Lima, Veronika Fritsch, Joe D. Thompson, John L. Sarrao, Michael Gillessen, and Richard Dronskowski pp 4047 - 4054; DOI: 10.1021/ic060092e |
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Construction of [(5-C5Me5)WS3Cu3]-Based Supramolecular Compounds from Preformed Incomplete Cubane-Like Clusters [PPh4][(5-C5Me5)WS3(CuX)3] (X = CN, Br) Qing-Feng Xu, Jin-Xiang Chen, Wen-Hua Zhang, Zhi-Gang Ren, Hong-Xi Li, Yong Zhang, and Jian-Ping Lang pp 4055 - 4064; DOI: 10.1021/ic060115p |
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Rare Earth Coordination Polymers with Zeolite Topology Constructed from 4-Connected Building Units Xiaodan Guo, Guangshan Zhu, Zhongyue Li, Yan Chen, Xiaotian Li, and Shilun Qiu pp 4065 - 4070; DOI: 10.1021/ic060116h |
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A New Family of Mono- and Dicarboxylic Ruthenium Complexes [Ru(DIP)2(L2)]2+ (DIP = 4,7-diphenyl-1,10-phenanthroline): Synthesis, Solution Behavior, and X-ray Molecular Structure of trans-[Ru(DIP)2(MeOH)2][OTf]2 Regis Caspar, Christine Cordier, Jenny B. Waern, Carine Guyard-Duhayon, Michel Gruselle, Pascal Le Floch, and Hani Amouri pp 4071 - 4078; DOI: 10.1021/ic0601236 |
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In Situ FT-IR and UV-vis Spectroscopy of the Low-Temperature NO Disproportionation Mediated by Solid State Manganese(II) Porphyrinates Garik G. Martirosyan, Arsen S. Azizyan, Tigran S. Kurtikyan, and Peter C. Ford pp 4079 - 4087; DOI: 10.1021/ic051824q |
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New Luminescent Europium(III) Chelates for DNA Labeling Takuya Nishioka, Jingli Yuan, Yuji Yamamoto, Keiko Sumitomo, Zhen Wang, Kimikazu Hashino, Chihiro Hosoya, Keisuke Ikawa, Guilan Wang, and Kazuko Matsumoto pp 4088 - 4096; DOI: 10.1021/ic051276g |
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Solvent Effects on the Structural and Formyl Substrate Reactivity Properties of a Nitrogen/Sulfur-Ligated Zinc Hydroxide Complex Russell A. Allred, Kelly Doyle, Atta M. Arif, and Lisa M. Berreau pp 4097 - 4108; DOI: 10.1021/ic051603k |
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Proton Reduction and Dihydrogen Oxidation on Models of the [2Fe]H Cluster of [Fe] Hydrogenases. A Density Functional Theory Investigation Giuseppe Zampella, Claudio Greco, Piercarlo Fantucci, and Luca De Gioia pp 4109 - 4118; DOI: 10.1021/ic051986m |
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The Reversible and Stereoselective N- to C-bonded Rearrangement of Tris(2-pyridylmethyl)-1,4,7-triazacyclononanecobalt(III) W. Gregory Jackson, Josephine A. McKeon, David C. R. Hockless, and Anthony C. Willis pp 4119 - 4135; DOI: 10.1021/ic051997f |
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Mixed Substituted Porphyrins: Structural and Electrochemical Redox Properties P. Bhyrappa, M. Sankar, and B. Varghese pp 4136 - 4149; DOI: 10.1021/ic052035b |
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From One-Dimensional Chains to Three-Dimensional Networks: Solvothermal Synthesis of Thiogallates in Ethylenediamine Paz Vaqueiro pp 4150 - 4156; DOI: 10.1021/ic052043s |
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Experimental and Theoretical Investigations of IR Spectra and Electronic Structures of the U(OH)2, UO2(OH), and UO2(OH)2 Molecules Xuefeng Wang, Lester Andrews, and Jun Li pp 4157 - 4166; DOI: 10.1021/ic052071a |
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Synthesis and Characterization of Single-Crystal Ce(OH)CO3 and CeO2 Triangular Microplates Zhiyan Guo, Fanglin Du, Guicun Li, and Zuolin Cui pp 4167 - 4169; DOI: 10.1021/ic052189r |
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Synthesis, Isolation, and Structural Characterization of the C4h Isomer of Metal(1,2-naphthalocyanine) and Its One-Dimensional Conductor of the Axially Substituted Species Eduardo H. Gacho, Hiroyuki Imai, Ryo Tsunashima, Toshio Naito, Tamotsu Inabe, and Nagao Kobayashi pp 4170 - 4176; DOI: 10.1021/ic0520622 |
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Electronic Configuration of High-Spin Imidazole-Ligated Iron(II) Octaethylporphyrinates Chuanjiang Hu, Jin An, Bruce C. Noll, Charles E. Schulz, and W. Robert Scheidt pp 4177 - 4185; DOI: 10.1021/ic052194v |
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Large-Scale Synthesis of Perpendicular Side-Faceted One-Dimensional ZnO Nanocrystals Xiao Li Zhang and Young Soo Kang pp 4186 - 4190; DOI: 10.1021/ic052208x |
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Heterobimetallic Activation of Dioxygen: Characterization and Reactivity of Novel Cu(I)-Ge(II) Complexes John T. York, Victor G. Young, Jr., and William B. Tolman pp 4191 - 4198; DOI: 10.1021/ic060050q |
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Water-Exchange Study Revealed Unexpected Substitution Behavior of [(CO)2(NO)Re(H2O)3]2+ in Aqueous Media Marie-Line Lehaire, Pascal V. Grundler, Stefan Steinhauser, Niklaus Marti, Lothar Helm, Kaspar Hegetschweiler, Roger Schibli, and André E. Merbach pp 4199 - 4204; DOI: 10.1021/ic060010m |
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Template- and pH-Directed Assembly of Diruthenium Diphosphonates with Different Topologies and Oxidation States Bin Liu, Ping Yin, Xiao-Yi Yi, Song Gao, and Li-Min Zheng pp 4205 - 4213; DOI: 10.1021/ic060041h |
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Diastereopure Fe(II) and Zn(II) Complexes Derived from a Tridentate N,N',N-Bis(methyl-L-prolinate)-Substituted Pyridine Ligand Silvia Gosiewska, Jeroen J. L. M. Cornelissen, Martin Lutz, Anthony L. Spek, Gerard van Koten, and Robertus J. M. Klein Gebbink pp 4214 - 4227; DOI: 10.1021/ic060134z |
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Bimetallic Fluorine-Substituted Anilido-Aldimine Zinc Complexes for CO2/(Cyclohexene Oxide) Copolymerization Taekki Bok, Hoseop Yun, and Bun Yeoul Lee pp 4228 - 4237; DOI: 10.1021/ic060060r |
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Significance of the Molecular Shape of Iron Corrphycene in a Protein Pocket Saburo Neya, Kiyohiro Imai, Yoshitsugu Hiramatsu, Teizo Kitagawa, Tyuji Hoshino, Masayuki Hata, and Noriaki Funasaki pp 4238 - 4242; DOI: 10.1021/ic0600679 |
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Enhanced Solid-State Metathesis Routes to Carbon Nanotubes Julia J. Mack, Susanne Tari, and Richard B. Kaner pp 4243 - 4246; DOI: 10.1021/ic060232k |
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Molybdocalixarene Structure Control via Rim Deprotonation. Synthesis, Characterization, and Crystal Structures of Calix[4]arene Mo(VI) Monooxo Complexes and Calix[4]arene Alkali Metal/Mo(VI) Dioxo Complexes Lihua Liu, Lev N. Zakharov, James A. Golen, Arnold L. Rheingold, William H. Watson, and Tracy A. Hanna pp 4247 - 4260; DOI: 10.1021/ic060404d |
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Macrocyclic Amines as Structure-Directing Agents for the Synthesis of Three-Dimensional Antimony-Sulfide Frameworks Anthony V. Powell, Rachel J. E. Lees, and Ann M. Chippindale pp 4261 - 4267; DOI: 10.1021/ic060263f |
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Electronic Structure and Reactivity of Isomeric Oxo-Mn(V) Porphyrins: Effects of Spin-State Crossing and pKa Modulation Filippo De Angelis, Ning Jin, Roberto Car, and John T. Groves pp 4268 - 4276; DOI: 10.1021/ic060306s |
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EPR and UV-Vis Studies of the Nitric Oxide Adducts of Bacterial Phenylalanine Hydroxylase: Effects of Cofactor and Substrate on the Iron Environment Andrew Y. Han, Amanda Q. Lee, and Mahdi M. Abu-Omar pp 4277 - 4283; DOI: 10.1021/ic060478p |
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Assembly of Heterometallic Clusters and Coordination Polymers by Combining Mo-S-Based Clusters with Mn2+ Ping Lin, William Clegg, Ross W. Harrington, Richard A. Henderson, Ashleigh J. Fletcher, Jon Bell, and K. Mark Thomas pp 4284 - 4302; DOI: 10.1021/ic060205u |
Issue 11
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Platinum(II) Diimine Diacetylides: Metallacyclization Enhances Photophysical Properties Fei Hua, Solen Kinayyigit, John R. Cable, and Felix N. Castellano pp 4304 - 4306; DOI: 10.1021/ic060102b |
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A Two-Dimensional Octacyanomolybdate(V)-Based Ferrimagnet: {[MnII(DMF)4]3[MoV(CN)8]2}n Jeffrey R. Withers, Dongfeng Li, Jeremy Triplet, Chad Ruschman, Sean Parkin, Guangbin Wang, Gordon T. Yee, and Stephen M. Holmes pp 4307 - 4309; DOI: 10.1021/ic0515251 |
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Supramolecular Framework with Two Different Kinds of Channels via Self-Assembly of 1D Coordination Polymers in a Prismatic Manner Byung Il Park, In Sung Chun, Young-A Lee, Ki-Min Park, and Ok-Sang Jung pp 4310 - 4312; DOI: 10.1021/ic052053t |
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Synthesis, Characterization, and Crystal Structures of Two Novel High-Nuclear Nickel-Substituted Dimeric Polyoxometalates Zhiming Zhang, Yangguang Li, Enbo Wang, Xinlong Wang, Chao Qin, and Haiyan An pp 4313 - 4315; DOI: 10.1021/ic052149n |
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Unexpected Photoisomerization of a Pincer-type Amido Ligand Leads to Facial Coordination at Pt(IV) Seth B. Harkins and Jonas C. Peters pp 4316 - 4318; DOI: 10.1021/ic052014h |
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Photoinduced Electron-Transfer Reactions of Platinum(II) Terpyridyl Acetylide Complexes: Reductive Quenching in a Hydrogen-Generating System Rupesh Narayana-Prabhu and Russell H. Schmehl pp 4319 - 4321; DOI: 10.1021/ic052045c |
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Stepwise Guest Adsorption with Large Hysteresis in a Coordination Polymer {[Cu(bhnq)(THF)2](THF)}n Constructed from a Flexible Hingelike Ligand Koichi Yamada, Hirokazu Tanaka, Sadahiro Yagishita, Keiichi Adachi, Takashi Uemura, Susumu Kitagawa, and Satoshi Kawata pp 4322 - 4324; DOI: 10.1021/ic060046e |
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Structure and Magnetic Properties of a Hydroxo-Bridged Copper(II) Distorted Cubane Stabilized via Supramolecular Hydrogen Bonding with an Ionic Hexafluoroacetylacetonate Nazario Lopez, Thomas E. Vos, Atta M. Arif, William W. Shum, Juan C. Noveron, and Joel S. Miller pp 4325 - 4327; DOI: 10.1021/ic060167e |
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A Diamagnetic Dititanium(III) Paddlewheel Complex with No Direct Metal-Metal Bond Arjun Mendiratta, Christopher C. Cummins, F. Albert Cotton, Sergey A. Ibragimov, Carlos A. Murillo, and Dino Villagrán pp 4328 - 4330; DOI: 10.1021/ic0602650 |
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p-Carborane: A New Cage Spacer for Photoactive Metal Polypyridine Dyads Marco Ghirotti, Peter F. H. Schwab, M. Teresa Indelli, Claudio Chiorboli, and Franco Scandola pp 4331 - 4333; DOI: 10.1021/ic060327m |
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[Ni(xbsms)Ru(CO)2Cl2]: A Bioinspired Nickel-Ruthenium Functional Model of [NiFe] Hydrogenase Y. Oudart, V. Artero, J. Pécaut, and M. Fontecave pp 4334 - 4336; DOI: 10.1021/ic060510f |
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New N,N,N-Heteroscorpionates Based on 2,2'-Bis(pyrazolyl)ethanamine and Its Derivatives. Ligands Designed for Probing Supramolecular Interactions Daniel L. Reger, Radu F. Semeniuc, James R. Gardinier, Jennifer O'Neal, Bryn Reinecke, and Mark D. Smith pp 4337 - 4339; DOI: 10.1021/ic060347o |
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Multinuclear Luminescent Schiff-Base Zn-Nd Sandwich Complexes Wai-Kwok Wong, Xiaoping Yang, Richard A. Jones, Joseph H. Rivers, Vince Lynch, Wing-Kit Lo, Dang Xiao, Michael M. Oye, and Archie L. Holmes pp 4340 - 4345; DOI: 10.1021/ic051866e |
The Room-Temperature Superstructure of ZrP2O7 Is Orthorhombic: There Are No Unusual 180 P-O-P Bond AnglesHenrik Birkedal, Anne Marie Krogh Andersen, Alla Arakcheeva, Gervais Chapuis, Poul Norby, and Philip Pattison pp 4346 - 4351; DOI: 10.1021/ic0600174 |
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The 136-Atom Structure of ZrP2O7 and HfP2O7 from Powder Diffraction Data Graham W. Stinton, Matthew R. Hampson, and John S. O. Evans pp 4352 - 4358; DOI: 10.1021/ic060016b |
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Structure of Anhydrous Alkali-Metal Formates Michael P. Wilson, Nathaniel W. Alcock, and P. Mark Rodger pp 4359 - 4363; DOI: 10.1021/ic051910q |
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Intercalation and Photophysical Properties of the Tetra-(8-hydroxyquinolinato) Boron Complex and 3,3',4,4'-Benzophenone Tetracarboxylic Anion into Mg-Al Layered Double Hydroxides Zhong-Liang Wang, Zhen-Hui Kang, En-Bo Wang, Zhong-Min Su, and Lin Xu pp 4364 - 4371; DOI: 10.1021/ic0519887 |
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Synthesis and Characterization of a Tripodal Amide Ligand and Its Binding with Anions of Different Dimensionality P. S. Lakshminarayanan, Eringathodi Suresh, and Pradyut Ghosh pp 4372 - 4380; DOI: 10.1021/ic052159o |
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From an ST = 3 Single-Molecule Magnet to Diamagnetic Ground State Depending on the Molecular Packing of MnIIIsalen-type Dimers Decorated by N,N'-Dicyano-1,4-naphthoquinonediiminate Radicals Chihiro Kachi-Terajima, Hitoshi Miyasaka, Ken-ichi Sugiura, Rodolphe Clérac, and Hiroyuki Nojiri pp 4381 - 4390; DOI: 10.1021/ic0519842 |
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Single-Crystal Structure of the 2H-Related Perovskites (A3-xNax)NaBO6 (A = La, Pr, Nd; B = Rh, Pt) René B. Macquart, William R. Gemmill, Matthew J. Davis, Mark D. Smith, and Hans-Conrad zur Loye pp 4391 - 4395; DOI: 10.1021/ic060105o |
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Metal-Metal Bonding in Mixed Valence Ni25+ Complexes and Spectroscopic Evidence for a Ni26+ Species John F. Berry, Eberhard Bothe, F. Albert Cotton, Sergey A. Ibragimov, Carlos A. Murillo, Dino Villagrán, and Xiaoping Wang pp 4396 - 4406; DOI: 10.1021/ic060125q |
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Molecular Precursor Route to Bulk and Silica-Supported Nb2Mo3O14 Using Water-Soluble Oxo-oxalato Complexes Daisy A. Bayot and Michel M. Devillers pp 4407 - 4412; DOI: 10.1021/ic0603149 |
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Influence of the Counterion and the Solvent Molecules in the Spin Crossover System [Co(4-terpyridone)2]Xp·nH2O Ana Galet, Ana Belén Gaspar, M. Carmen Muñoz, and José Antonio Real pp 4413 - 4422; DOI: 10.1021/ic060090u |
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Self-Assembly, Structures, and Solution Dynamics of Emissive Silver Metallacycles and Helices Ronger Lin and John H. K. Yip pp 4423 - 4430; DOI: 10.1021/ic060140v |
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Homochiral Porous Lanthanide Phosphonates with 1D Triple-Strand Helical Chains: Synthesis, Photoluminescence, and Adsorption Properties Qi Yue, Jin Yang, Guang-Hua Li, Guo-Dong Li, and Jie-Sheng Chen pp 4431 - 4439; DOI: 10.1021/ic060162h |
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Importance of the O-M-O Bridges (M = V5+, Mo6+) for the Spin-Exchange Interactions in the Magnetic Oxides of Cu2+ Ions Bridged by MO4 Tetrahedra: Spin-Lattice Models of Rb2Cu2(MoO4)3, BaCu2V2O8, and KBa3Ca4Cu3V7O28 Hyun-Joo Koo and Myung-Hwan Whangbo pp 4440 - 4447; DOI: 10.1021/ic060392w |
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Iron Porphyrin-Cyclodextrin Supramolecular Complex as a Functional Model of Myoglobin in Aqueous Solution Koji Kano, Hiroaki Kitagishi, Camille Dagallier, Masahito Kodera, Takashi Matsuo, Takashi Hayashi, Yoshio Hisaeda, and Shun Hirota pp 4448 - 4460; DOI: 10.1021/ic060137b |
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Testing Bridge-Mediated Differences in Dinuclear Valence Tautomeric Behavior Sofi Bin-Salamon, Scott H. Brewer, Ezra C. Depperman, Stefan Franzen, Jeff W. Kampf, Martin L. Kirk, R. Krishna Kumar, Simon Lappi, Katrina Peariso, Kathryn E. Preuss, and David A. Shultz pp 4461 - 4467; DOI: 10.1021/ic060170y |
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Metal and Ligand K-edge XAS of Titanium-TEMPO Complexes: Determination of Oxidation States and Insights into Ti-O Bond Homolysis Serena DeBeer George, Kuo-Wei Huang, Robert M. Waymouth, and Edward I. Solomon pp 4468 - 4477; DOI: 10.1021/ic060402t |
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In Search of Benzene-like Sn66-: Synthesis of Na4CaSn6 with Interconnected Cyclohexane-like Sn66- Iliya Todorov and Slavi C. Sevov pp 4478 - 4483; DOI: 10.1021/ic060443p |
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Lanthanide(III) Complexes with a Tetrapyridine Pendant-Armed Macrocyclic Ligand: 1H NMR Structural Determination in Solution, X-ray Diffraction, and Density-Functional Theory Calculations M. del C. Fernández-Fernández, R. Bastida, A. Macías, P. Pérez-Lourido, C. Platas-Iglesias, and L. Valencia pp 4484 - 4496; DOI: 10.1021/ic0603508 |
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Di-, Tri-, and Tetranuclear Zinc Hydroxamate Complexes as Structural Models for the Inhibition of Zinc Hydrolases by Hydroxamic Acids David A. Brown, Noel J. Fitzpatrick, Helge Müller-Bunz, and Áine T. Ryan pp 4497 - 4507; DOI: 10.1021/ic050849m |
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Mass Spectrometric and Quantum Chemical Studies of the Thermodynamics and Bonding of Neutral and Ionized LnCl, LnCl2, and LnCl3 Species (Ln = Ce, Lu) Julia Saloni, Szczepan Roszak, Klaus Hilpert, Arkadij Popovic, Miros aw Miller, and Jerzy Leszczynskipp 4508 - 4517; DOI: 10.1021/ic051205h |
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X-ray Crystallographic and Mössbauer Spectroscopic Applications in Dependence of Partial Quadrupole Splitting, [R], on the C-Sn-C Angle in Seven-Coordinated Diorganotin(IV) Complexes Gerimário F. de Sousa, Victor M. Deflon, Maria T. do P. Gambardella, Regina H. P. Francisco, José D. Ardisson, and Elke Niquet pp 4518 - 4525; DOI: 10.1021/ic0516360 |
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Spectral and Structural Characterization of Amidate-Bridged Platinum-Thallium Complexes with Strong Metal-Metal Bonds Wanzhi Chen, Fenghui Liu, Kazuko Matsumoto, Jochen Autschbach, Boris Le Guennic, Tom Ziegler, Mikhail Maliarik, and Julius Glaser pp 4526 - 4536; DOI: 10.1021/ic051678o |
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Novel Stoichiometrically Erbium-Ytterbium Cocrystalline Complex Exhibiting Enhanced Near-Infrared Luminescence Qi Zhong, Huaishan Wang, Guodong Qian, Zhiyu Wang, Jiahua Zhang, Jianrong Qiu, and Minquan Wang pp 4537 - 4543; DOI: 10.1021/ic051697y |
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Probing the Electronic Structure of Platinum(II) Chromophores: Crystal Structures, NMR Structures, and Photophysical Properties of Six New Bis- and Di- Phenolate/Thiolate Pt(II)Diimine Chromophores Julia A. Weinstein, Mark T. Tierney, E. Stephen Davies, Karel Base, Anthony A. Robeiro, and Mark W. Grinstaff pp 4544 - 4555; DOI: 10.1021/ic051733t |
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Molybdenum Oxo-Imido Aryloxide Complexes: Oxo Analogues of Olefin Metathesis Catalysts Warren B. Cross, James C. Anderson, Claire Wilson, and Alexander J. Blake pp 4556 - 4561; DOI: 10.1021/ic0521269 |
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Rh(I) and Ir(I) Derivatives of a P(S),N-Substituted Indene Ligand: Synthetic, Structural, and Catalytic Alkene Hydrosilylation Studies Dominik Wechsler, Anne Myers, Robert McDonald, Michael J. Ferguson, and Mark Stradiotto pp 4562 - 4570; DOI: 10.1021/ic060127a |
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Thiolate Alkylation in Tripod Zinc Complexes: A Comparative Kinetic Study Michael Rombach, Jan Seebacher, Mian Ji, Guofang Zhang, Guosen He, Mohamed M. Ibrahim, Boumahdi Benkmil, and Heinrich Vahrenkamp pp 4571 - 4575; DOI: 10.1021/ic060301v |
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The Underlying Spin-Orbit Coupling Structure of Intervalence Charge Transfer Bands in Dinuclear Polypyridyl Complexes of Ruthenium and Osmium D. M. D'Alessandro, P. H. Dinolfo, M. S. Davies, J. T. Hupp,and, and F. R. Keene: pp 4576 - 4576; DOI: 10.1021/ic060672b |
Issue 12
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Synthesis of Im3[Re3(3-S)(-S)3Br9]Br (Im = 1-Ethyl-3-methylimidazolium) by Means of an Ionic Liquid Hideshi Sakamoto, Yusuke Watanabe, and Taro Saito pp 4578 - 4579; DOI: 10.1021/ic060428k |
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Channel-Switching Crystal with Guest Stress Drive Satoshi Takamizawa, Kenichi Kojima, and Takamasa Akatsuka pp 4580 - 4582; DOI: 10.1021/ic051952e |
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{Fe(3CNpy)2[Cu(3CNpy)(-CN)2]2}: a One-Dimensional Cyanide-Based Spin-Crossover Coordination Polymer Ana Galet, M. Carmen Muñoz, and José Antonio Real pp 4583 - 4585; DOI: 10.1021/ic060247i |
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Poly(ethylene glycol)-Assisted Two-Dimensional Self-Assembly of Zinc Sulfide Microspheres Qingzhi Wu, Huaqiang Cao, Sichun Zhang, and Xinrong Zhang pp 4586 - 4588; DOI: 10.1021/ic060180z |
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Direct Orthoruthenation of Planar Prochiral Pyridine Derivatives by C-H Bond Activation with [Ru(CO)2Cl2]n and Its Unexpected Stereoselectivity Akram Hijazi, Jean-Pierre Djukic, Michel Pfeffer, Louis Ricard, Nathalie Kyritsakas-Gruber, Jesus Raya, Philippe Bertani, and André de Cian pp 4589 - 4591; DOI: 10.1021/ic0604112 |
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Boxes, Helicates, and Coordination Polymers: A Structural and Magnetochemical Investigation of the Diverse Coordination Chemistry of Simple Pyridine-Alcohol Ligands Shane G. Telfer, Reiko Kuroda, Julie Lefebvre, and Daniel B. Leznoff pp 4592 - 4601; DOI: 10.1021/ic0517218 |
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The Metal-NO Interaction in the Redox Systems [Cl5Os(NO)]n-, n = 1-3, and cis-[(bpy)2ClOs(NO)]2+/+: Calculations, Structural, Electrochemical, and Spectroscopic Results Priti Singh, Biprajit Sarkar, Monika Sieger, Mark Niemeyer, Jan Fiedler, Stanislav Záli , and Wolfgang Kaimpp 4602 - 4609; DOI: 10.1021/ic0517669 |
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Luminescence of Ruthenium Halide Complexes Containing a Hemilabile Phosphine Pyrenyl Ether Ligand Kristin M. Matkovich, Lisa M. Thorne, Michael O. Wolf, Tamara C. S. Pace, Cornelia Bohne, and Brian O. Patrick pp 4610 - 4618; DOI: 10.1021/ic051795j |
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Impact of Growth Kinetics on Morphology and Pore Structure of TiO2-One-Pot Synthesis of Macroporous TiO2 Microspheres Ziyi Zhong, Fengxi Chen, Thiam-Peng Ang, Yifan Han, Weiqiang Lim, and Aharon Gedanken pp 4619 - 4625; DOI: 10.1021/ic052080j |
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Ligand Effects on the Structures of Extended Networks of Dicyanamide-Containing Transition-Metal Ions Donatella Armentano, Giovanni De Munno, Francesca Guerra, Miguel Julve, and Francesc Lloret pp 4626 - 4636; DOI: 10.1021/ic060044u |
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Crystal Growth, Structure, Magnetic, and Transport Properties of TbRhIn5 Willa M. Williams, Long Pham, Samuel MaQuilon, Monica Moldovan, Zachary Fisk, David P. Young, and Julia Y. Chan pp 4637 - 4641; DOI: 10.1021/ic060185w |
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Synthesis, Characterization, and DFT-TDDFT Computational Study of a Ruthenium Complex Containing a Functionalized Tetradentate Ligand C. Barolo, Md. K. Nazeeruddin, Simona Fantacci, D. Di Censo, P. Comte, P. Liska, G. Viscardi, P. Quagliotto, Filippo De Angelis, S. Ito, and M. Grätzel pp 4642 - 4653; DOI: 10.1021/ic051970w |
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(3,4)-Connected Zincophosphites as Structural Analogues of Zinc Hydrogen Phosphate Lan Chen and Xianhui Bu pp 4654 - 4660; DOI: 10.1021/ic060059s |
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Hydrazine Nitrosation of a Metal-Bound Nitric Oxide: Structural Evidence for the Formation of an Ammine Complex Raju Prakash, Andreas W. Götz, Frank W. Heinemann, Andreas Görling, and Dieter Sellmann pp 4661 - 4667; DOI: 10.1021/ic060096j |
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Dinuclear Nickel and Palladium Complexes with Bridging 2,5-Diamino-1,4-benzoquinonediimines: Synthesis, Structures, and Catalytic Oligomerization of Ethylene Jean-philippe Taquet, Olivier Siri, Pierre Braunstein, and Richard Welter pp 4668 - 4676; DOI: 10.1021/ic060019o |
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Octanuclear Zinc(II) and Cobalt(II) Clusters Produced by Cooperative Tetrameric Assembling of Oxime Chelate Ligands Shigehisa Akine, Wenkui Dong, and Tatsuya Nabeshima pp 4677 - 4684; DOI: 10.1021/ic060055n |
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Evaluation of Electron-Withdrawing Group Effects on Heme Binding in Designed Proteins: Implications for Heme a in Cytochrome c Oxidase Jinyou Zhuang, Jennifer H. Amoroso, Ryan Kinloch, John H. Dawson, Michael J. Baldwin, and Brian R. Gibney pp 4685 - 4694; DOI: 10.1021/ic060072c |
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Spectroscopic, Magnetochemical, and Crystallographic Study of Cesium Iron Phosphate Hexahydrate: Characterization of the Electronic Structure of the Iron(II) Hexa-aqua Cation in a Quasicubic Environment Graham Carver, Christopher Dobe, Thomas B. Jensen, Philip L. W. Tregenna-Piggott, Stefan Janssen, Eckhard Bill, Garry J. McIntyre, and Anne-Laure Barra pp 4695 - 4705; DOI: 10.1021/ic0601889 |
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Synthesis and Crystal Chemistry of Two New Fluorite-Related Bismuth Phosphates, Bi4.25(PO4)2O3.375 and Bi5(PO4)2O4.5, in the Series Bi4+x(PO4)2O3+3x/2 (0.175 x 1) B. Muktha and T. N. Guru Row pp 4706 - 4711; DOI: 10.1021/ic0601337 |
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Synthesis and Structure of CpMo(CO)(dppe)H and Its Oxidation by Ph3C+ Tan-Yun Cheng, David J. Szalda, Jie Zhang, and R. Morris Bullock pp 4712 - 4720; DOI: 10.1021/ic060111k |
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Polar Symmetry and Intercalation of New Multilayered Hybrid Molybdates: [M2(pzc)2(H2O)x][Mo5O16] (M = Co, Ni) Bangbo Yan and Paul A. Maggard pp 4721 - 4727; DOI: 10.1021/ic060253e |
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Triiodide Quenching of Ruthenium MLCT Excited State in Solution and on TiO2 Surfaces: An Alternate Pathway for Charge Recombination Christopher C. Clark, Andras Marton, Ramya Srinivasan, Amy A. Narducci Sarjeant, and Gerald J. Meyer pp 4728 - 4734; DOI: 10.1021/ic060246q |
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Synthesis and Assembly with Mesoporous Silica MCM-48 of Platinum(II) Porphyrin Complexes Bearing Carbazyl Groups: Spectroscopic and Oxygen Sensing Properties Cheng Huo, Huidong Zhang, Hongyu Zhang, Houyu Zhang, Bing Yang, Ping Zhang, and Yue Wang pp 4735 - 4742; DOI: 10.1021/ic060354c |
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Charge Distribution in Chromium and Vanadium Catecholato Complexes: X-ray Absorption Spectroscopic and Computational Studies Carsten Milsmann, Aviva Levina, Hugh H. Harris, Garry J. Foran, Peter Turner, and Peter A. Lay pp 4743 - 4754; DOI: 10.1021/ic0603611 |
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Electron Delocalization Mediates the Metal-Dependent Capacity for CH/ Interactions of Acetylacetonato Chelates Milo K. Mili, Vesna B. Medakovi, Duan N. Sredojevi, Nenad O. Jurani, and Sneana D. Zaripp 4755 - 4763; DOI: 10.1021/ic051926g |
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Chiral Layered Zincophosphate [d-Co(en)3]Zn3(H0.5PO4)2(HPO4)2 Assembled about d-Co(en)33+ Complex Cations Yu Wang, Peng Chen, Jiyang Li, Jihong Yu, Jin Xu, Qinhe Pan, and Ruren Xu pp 4764 - 4768; DOI: 10.1021/ic0519640 |
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Fast Catalytic Hydroxylation of Hydrocarbons with Ruthenium Porphyrins Chuanqing Wang, Kirill V. Shalyaev, Marcella Bonchio, Tommaso Carofiglio, and John T. Groves pp 4769 - 4782; DOI: 10.1021/ic0520566 |
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Titanium and Zirconium Complexes of Dianionic and Trianionic Amine-Phenolate-Type Ligands in Catalysis of Lactide Polymerization Shimrit Gendler, Sharon Segal, Israel Goldberg, Zeev Goldschmidt, and Moshe Kol pp 4783 - 4790; DOI: 10.1021/ic052120j |
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Molybdenum and Tungsten 2-Alkyne-1-thio Complexes Acting as Sulfur Donors in Homoleptic Werner Type Complexes with Nickel(II) and Palladium(II) Wolfram W. Seidel, Maria D. Ibarra Arias, Markus Schaffrath, Mareike C. Jahnke, Alexander Hepp, and Tania Pape pp 4791 - 4800; DOI: 10.1021/ic052178y |
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Diversity of Coordination Architecture of Metal 4,5-Dicarboxyimidazole Rui-Qin Fang and Xian-Ming Zhang pp 4801 - 4810; DOI: 10.1021/ic052099m |
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Factors Governing the Metal Coordination Number in Isolated Group IA and IIA Metal Hydrates Ingvar Tunell and Carmay Lim pp 4811 - 4819; DOI: 10.1021/ic0519741 |
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Photoinduced Energy Transfer Coupled to Charge Separation in a Ru(II)-Ru(II)-Acceptor Triad Magnus Borgström, Sascha Ott, Reiner Lomoth, Jonas Bergquist, Leif Hammarström, and Olof Johansson pp 4820 - 4829; DOI: 10.1021/ic060121l |
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Synthesis, Reactivities, and Magnetostructural Properties of FeIII, FeIII-O-FeIII, and ZnIIFeIII-O-FeIIIZnII Complexes of a Tetraiminodiphenolate Macrocycle Papu Biswas, Meenakshi Ghosh, Sujit K. Dutta, Ulrich Flörke, and Kamalaksha Nag pp 4830 - 4844; DOI: 10.1021/ic060183b |
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Fabrication and Characterization of Ultralong Ag/C Nanocables, Carbonaceous Nanotubes, and Chainlike -Ag2Se Nanorods inside Carbonaceous Nanotubes Dekun Ma, Meng Zhang, Guangcheng Xi, Junhao Zhang, and Yitai Qian pp 4845 - 4849; DOI: 10.1021/ic060126i |
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From a Trinuclear Platinum(III) Phosphido Derivative to a Platinum(II) Cluster: Formation of a P-C Bond Juan Forniés, Consuelo Fortuño, Susana Ibáñez, and Antonio Martín pp 4850 - 4858; DOI: 10.1021/ic0602695 |
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Stereoselective Preparation, Structures, and Reactivities of Phosphine-Bridged Mixed-Metal Trinuclear and Pentanuclear Complexes with Tris[2-(diphenylphosphino)ethyl]phosphine Sen-ichi Aizawa, Kenji Saito, Tatsuya Kawamoto, and Emi Matsumoto pp 4859 - 4866; DOI: 10.1021/ic060277l |
Issue 13
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Homochiral 1D Zinc-Quitenine Coordination Polymer with a High Dielectric Constant Yun-Zhi Tang, Xue-Feng Huang, Yu-Mei Song, Philip Wai Hong Chan, and Ren-Gen Xiong pp 4868 - 4870; DOI: 10.1021/ic0603095 |
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Diiron Amido-Imido Complex [(Cp*Fe)2(2-NHPh)(2-NPh)]: Synthesis and a Net Hydrogen Atom Abstraction Reaction To Form a Bis(imido) Complex Shin Takemoto, Shin-ichiro Ogura, Ho Yo, Yuko Hosokoshi, Ken Kamikawa, and Hiroyuki Matsuzaka pp 4871 - 4873; DOI: 10.1021/ic060744z |
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Crystal Engineering in Ionic Liquids. The Crystal Structures of [Mppyr]3[NdI6] and [Bmpyr]4[NdI6][Tf2N] Arash Babai and Anja-Verena Mudring pp 4874 - 4876; DOI: 10.1021/ic060414e |
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One-Dimensional Ferromagnetic Complexes Built with MnIII3O Units Jun Tao, Yuan-Zhu Zhang, Yue-Lin Bai, and Osamu Sato pp 4877 - 4879; DOI: 10.1021/ic060159y |
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Conformation-Controlled Luminescent Properties of Lanthanide Clusters Containing p-tert-Butylsulfonylcalix[4]arene Takashi Kajiwara, Kensuke Katagiri, Miki Hasegawa, Ayumi Ishii, Marilena Ferbinteanu, Shinya Takaishi, Tasuku Ito, Masahiro Yamashita, and Nobuhiko Iki pp 4880 - 4882; DOI: 10.1021/ic060397t |
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1,1-Azide-Bridged Ferromagnetic MnIII Dimer with Slow Relaxation of Magnetization Chun-Hua Ge, Ai-Li Cui, Zhong-Hai Ni, Yun-Bo Jiang, Li-Fang Zhang, Joan Ribas, and Hui-Zhong Kou pp 4883 - 4885; DOI: 10.1021/ic060479h |
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New -Bi2O3 Metastable Polymorph Nicoleta Cornei, Nathalie Tancret, Francis Abraham, and Olivier Mentré pp 4886 - 4888; DOI: 10.1021/ic0605221 |
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Ferromagnetic Coupling by Orthogonal Magnetic Orbitals in a Heterodinuclear CuIIVIV=O Complex and in a Homodinuclear CuIICuII Complex Thorsten Glaser, Hubert Theil, Ioannis Liratzis, Thomas Weyhermüller, and Eckhard Bill pp 4889 - 4891; DOI: 10.1021/ic0606328 |
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Self-Assembly of cis and trans Forms of the Copper(II) Complex with 1-Aminocyclopropane-1-carboxylate into Discrete Trimers in the Solid State Nenad Juda and Nenad Raospp 4892 - 4894; DOI: 10.1021/ic060780y |
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Photochemical E-Z Isomerization of meta-Terphenyl-Protected Phosphaalkenes and Structural Characterizations Vittal B. Gudimetla, Arnold L. Rheingold, John L. Payton, Huo-Lei Peng, M. Cather Simpson, and John D. Protasiewicz pp 4895 - 4901; DOI: 10.1021/ic0520521 |
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Iron(III)-Nitro Porphyrins: Theoretical Exploration of a Unique Class of Reactive Molecules Jeanet Conradie and Abhik Ghosh pp 4902 - 4909; DOI: 10.1021/ic060362t |
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Theoretical Evidence Favoring True Iron(V)-Oxo Corrole and Corrolazine Intermediates Ingar Wasbotten and Abhik Ghosh pp 4910 - 4913; DOI: 10.1021/ic0602493 |
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Biliverdine-Based Metalloradicals: Sterically Enhanced Noninnocence Ingar Wasbotten and Abhik Ghosh pp 4914 - 4921; DOI: 10.1021/ic052037w |
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Synthesis of CdSe, ZnSe, and ZnxCd1-xSe Nanocrystals and Their Silica Sheathed Core/Shell Structures Jian-Ping Ge, Sheng Xu, Jing Zhuang, Xun Wang, Qing Peng, and Ya-Dong Li pp 4922 - 4927; DOI: 10.1021/ic051598k |
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The Vibrational Spectra of the Cyanide Ligand Revisited: Terminal Cyanides Sidney F. A. Kettle, Gian Luca Aschero, Eliano Diana, Rosanna Rossetti, and Pier Luigi Stanghellini pp 4928 - 4937; DOI: 10.1021/ic0514041 |
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Chemistry of 2,2,6,6,-Tetramethyl-3,5-heptanedione (Hthd) Modification of Zirconium and Hafnium Propoxide Precursors Gerald I. Spijksma, Henny J. M. Bouwmeester, Dave H. A. Blank, Andreas Fischer, Marc Henry, and Vadim G. Kessler pp 4938 - 4950; DOI: 10.1021/ic051674j |
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Equilibria and Structure of the Lanthanide(III)-2-hydroxy-1,3-diaminopropane-N,N,N',N'-tetraacetate Complexes: Formation of Alkoxo-Bridged Dimers in Solid State and Solution Gyula Tircsó, Attila Bényei, Ernõ Brücher, Anita Kis, and Róbert Király pp 4951 - 4962; DOI: 10.1021/ic0517321 |
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Computational Studies of Nucleophilic Attack and Protonation of Electron-Deficient Benzoheterocycle Triosmium Clusters Taraneh Nowroozi-Isfahani, Djamaladdin G. Musaev, Keiji Morokuma, and Edward Rosenberg pp 4963 - 4973; DOI: 10.1021/ic052012x |
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Density Functional Theory Study of 10-Atom Germanium Clusters: Effect of Electron Count on Cluster Geometry R. B. King, I. Silaghi-Dumitrescu, and M. M. U   pp 4974 - 4981; DOI: 10.1021/ic051905m |
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Molecular Electrostatic Potential Approach to Determining the Steric Effect of Phosphine Ligands in Organometallic Chemistry Cherumuttathu H. Suresh pp 4982 - 4986; DOI: 10.1021/ic051959w |
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Transformation from a Low-Dimensional Framework to a High-Dimensional Architecture Based on Different Metal Ions: Syntheses, Structures, and Photoluminescences Yun Gong, Wang Tang, Wenbin Hou, Zhongyong Zha, and Changwen Hu pp 4987 - 4995; DOI: 10.1021/ic052095h |
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- and -FOX-7, Polymorphs of a High Energy Density Material, Studied by X-ray Single Crystal and Powder Investigations in the Temperature Range from 200 to 423 K Jürgen Evers, Thomas M. Klapötke, Peter Mayer, Gilbert Oehlinger, and Jan Welch pp 4996 - 5007; DOI: 10.1021/ic052150m |
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Preparation, Properties, and Reactivities of Unprecedented Oxo-Sulfido Nb(IV) Aqua Ions and Crystal Structure of (Me2NH2)6[Nb5(3-S)2(3-O)2(2-O)2(NCS)14]·3.5H2O Bee-Lean Ooi, Inger S tofte, Maxim N. Sokolov, Svetlana G. Kozlova, Sren B. Rasmussen, Loa C. Nielsen, and Jonas Henriksenpp 5008 - 5017; DOI: 10.1021/ic052145i |
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Synthesis, Structures, and Magnetic Properties of a Series of Cyano-Bridged Fe-Mn Bimetallic Complexes Long Jiang, Xiao-Long Feng, Tong-Bu Lu, and Song Gao pp 5018 - 5026; DOI: 10.1021/ic052168x |
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Structural Basis for the Phase Switching of Bisaminecopper(II) Cations at the Thermal Limits of Lattice Stability Pan e Naumov, Kenji Sakurai, Toru Asaka, Alexei A. Belik, Shin-ichi Adachi, Junichi Takahashi, and Shin-ya Koshiharapp 5027 - 5033; DOI: 10.1021/ic060110s |
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Novel Biscapped and Monocapped Tris(dioxime) Mn(II) Complexes: X-ray Crystal Structure of the First Cationic Tris(dioxime) Mn(II) Complex [Mn(CDOH)3BPh]OH (CDOH2 = 1,2-cyclohexanedione dioxime) Wen-Yuan Hsieh and Shuang Liu pp 5034 - 5043; DOI: 10.1021/ic060216n |
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Electronic Structure, Spectroscopic Properties, and Reactivity of Molybdenum and Tungsten Nitrido and Imido Complexes with Diphosphine Coligands: Influence of the trans Ligand Klaus Mersmann, Andreas Hauser, Nicolai Lehnert, and Felix Tuczek pp 5044 - 5056; DOI: 10.1021/ic060141n |
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Formation, Spectral, Electrochemical, and Photochemical Behavior of Zinc N-Confused Porphyrin Coordinated to Imidazole Functionalized Fullerene Dyads Francis D'Souza, Phillip M. Smith, Lisa Rogers, Melvin E. Zandler, D.-M. Shafiqul Islam, Yasuyaki Araki, and Osamu Ito pp 5057 - 5065; DOI: 10.1021/ic0601687 |
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Pressure-Induced Switch of the Direction of the Unique Jahn-Teller Axis of the Chromium(II) Hexaqua Cation in the Deuterated Ammonium Chromium Tutton Salt Christopher Dobe, Thierry Strässle, Fanni Juranyi, and Philip L. W. Tregenna-Piggott pp 5066 - 5072; DOI: 10.1021/ic060187g |
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Unusual Reaction between (Nitrile)Pt Complexes and Pyrazoles: Substitution Proceeds via Metal-Mediated Nitrile-Pyrazole Coupling Followed by Elimination of the Nitrile Anatoly V. Khripun, Vadim Yu. Kukushkin, Stanislav I. Selivanov, Matti Haukka, and Armando J. L. Pombeiro pp 5073 - 5083; DOI: 10.1021/ic0602300 |
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The Correlation of Redox Potential, HOMO Energy, and Oxidation State in Metal Sulfide Clusters and Its Application to Determine the Redox Level of the FeMo-co Active-Site Cluster of Nitrogenase Ian Dance pp 5084 - 5091; DOI: 10.1021/ic060438l |
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Auto-Assembling of Ditopic Macrocyclic Lanthanide Chelates with Transition-Metal Ions. Rigid Multimetallic High Relaxivity Contrast Agents for Magnetic Resonance Imaging Jérôme Paris, Cristiana Gameiro, Valérie Humblet, Prasanta K. Mohapatra, Vincent Jacques, and Jean F. Desreux pp 5092 - 5102; DOI: 10.1021/ic0603050 |
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Growth and Optical Properties of Wurtzite-Type CdS Nanocrystals Huaqiang Cao, Guozhi Wang, Sichun Zhang, Xinrong Zhang, and Daniel Rabinovich pp 5103 - 5108; DOI: 10.1021/ic060440c |
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Spin-Gap Formation and Thermal Structural Studies in Reduced Hybrid Layered Vanadates Bangbo Yan, Junhua Luo, Paul Dube, Athena S. Sefat, John E. Greedan, and Paul A. Maggard pp 5109 - 5118; DOI: 10.1021/ic0604563 |
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Hydrogen Atom Abstraction by a High-Valent Manganese(V)-Oxo Corrolazine David E. Lansky and David P. Goldberg pp 5119 - 5125; DOI: 10.1021/ic060491+ |
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Effects of Coordinating Metal Ions on the Mediated Inhibition of Trypsin by Bis(benzimidazoles) and Related Compounds Jared J. Paul, Sandra R. Kircus, Thomas N. Sorrell, Patricia A. Ropp, and H. Holden Thorp pp 5126 - 5135; DOI: 10.1021/ic0516461 |
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Recognition of Small Polar Molecules with an Ionic Crystal of -Keggin-Type Polyoxometalate with a Macrocation Sayaka Uchida, Ryosuke Kawamoto, and Noritaka Mizuno pp 5136 - 5144; DOI: 10.1021/ic060684x |
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Synthesis and Characterization of Ag Nanoshells by a Facile Sacrificial Template Route through in situ Replacement Reaction Minghai Chen and Lian Gao pp 5145 - 5149; DOI: 10.1021/ic060539j |
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Synthesis, Reactivity, and X-ray Crystal Structure of Some Mixed-Ligand Oxovanadium(V) Complexes: First Report of Binuclear Oxovanadium(V) Complexes Containing 4,4'-Bipyridine Type Bridge Manas Sutradhar, Gurunath Mukherjee, Michael G. B. Drew, and Saktiprosad Ghosh pp 5150 - 5161; DOI: 10.1021/ic051120g |
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Cluster-Type Basic Lanthanide Iodides [M6(6-O)(3-OH)8(H2O)24]I8(H2O)8 (M = Nd, Eu, Tb, Dy) Anja-Verena Mudring, Tudor Timofte, and Arash Babai pp 5162 - 5166; DOI: 10.1021/ic051234s |
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Unusual In2N4 Cores in Complexes Containing Triazole-Based Chalcogen-Phosphoranyl Ligands Mónica Moya-Cabrera, Vojtech Jancik, Rafael A. Castro, Regine Herbst-Irmer, and Herbert W. Roesky pp 5167 - 5171; DOI: 10.1021/ic051567p |
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Ce53Fe12S90X3 (X = Cl, Br, I): The First Rare-Earth Transition-Metal Sulfide Halides Allison M. Mills and Michael Ruck pp 5172 - 5178; DOI: 10.1021/ic0521372 |
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Molecular Structures of Tris(dipivaloylmethanato) Complexes of the Lanthanide Metals, Ln(dpm)3, Studied by Gas Electron Diffraction and Density Functional Theory Calculations: A Comparison of the Ln-O Bond Distances and Enthalpies in Ln(dpm)3 Complexes and the Cubic Sesquioxides, Ln2O3 G. V. Girichev, N. I. Giricheva, Arne Haaland, N. P. Kuzmina, Svein Samdal, T. N. Strenalyuk, N. V. Tverdova, and I. G. Zaitseva pp 5179 - 5186; DOI: 10.1021/ic060079u |
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Construction of New Heteroselenometallic Clusters: Formation of Crownlike [Et4N]4[(5-WSe4)(CuI)5(-I)2] and Octahedral Polymeric [(6-WSe4)Cu6I4(py)4]n from Planar [Et4N]4[(4-WSe4)Cu4I6] with Additional Faces Qian-Feng Zhang, Zhan Yu, Jihai Ding, Yinglin Song, Alexander Rothenberger, Dieter Fenske, and Wa-Hung Leung pp 5187 - 5195; DOI: 10.1021/ic060161p |
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Facile Route to -FeOOH and -Fe2O3 Nanorods and Magnetic Property of -Fe2O3 Nanorods Bo Tang, Guangli Wang, Linhai Zhuo, Jiechao Ge, and Lijuan Cui pp 5196 - 5200; DOI: 10.1021/ic060097b |
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Synthesis of Acetimino Complexes of Pt(II) and Pt(IV) and the First Heteronuclear -Acetimido Complexes José Vicente, María-Teresa Chicote, Rita Guerrero, Inmaculada Vicente-Hernández, Peter G. Jones, and Delia Bautista pp 5201 - 5209; DOI: 10.1021/ic060489i |
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Synthesis and Reactivity of the Ruthenium(II) Dithiocarbonate Complex [Ru(2-S2C=O)(dppm)2] (dppm = Bis(diphenylphosphino)methane) James D. E. T. Wilton-Ely, Dina Solanki, and Graeme Hogarth pp 5210 - 5214; DOI: 10.1021/ic060223b |
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Synthesis and Characterization of Osmium(II) Trispyrazolylborate Complexes Paul W. Dickinson and Gregory S. Girolami pp 5215 - 5224; DOI: 10.1021/ic0602291 |
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Scope and Limitations of the Base-Catalyzed Phospha-Peterson P=C Bond-Forming Reaction Mandy Yam, Jonathan H. Chong, Chi-Wing Tsang, Brian O. Patrick, Anita E. Lam, and Derek P. Gates pp 5225 - 5234; DOI: 10.1021/ic060236p |
Issue 14
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Assembly of a Heterometallic Polynuclear SnIV-CuI Cluster Based on Sn(edt)2 (edt = Ethane-1,2-dithiolate) as a Metalloligand Xin Wang, Tian-Lu Sheng, Rui-Biao Fu, Sheng-Min Hu, Sheng-Chang Xiang, Long-Sheng Wang, and Xin-Tao Wu pp 5236 - 5238; DOI: 10.1021/ic060131m |
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O2 Chemistry of Dicopper Complexes with Alkyltriamine Ligands. Comparing Synergistic Effects on O2 Binding Anna Company, Diana Lamata, Albert Poater, Miquel Solà, Elena V. Rybak-Akimova, Lawrence Que, Jr., Xavier Fontrodona, Teodor Parella, Antoni Llobet, and Miquel Costas pp 5239 - 5241; DOI: 10.1021/ic0602446 |
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Photoinitiated Electron Collection at a Metal in a Rhodium-Centered Mixed-Metal Supramolecular Complex Mark Elvington and Karen J. Brewer pp 5242 - 5244; DOI: 10.1021/ic0602648 |
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Destruction of Noncentrosymmetry through Chalcogenide Salt Inclusion Amitava Choudhury and Peter K. Dorhout pp 5245 - 5247; DOI: 10.1021/ic060294a |
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Heptametallic Bowl-Shaped Complexes Derived from Conjugated Schiff-Base Macrocycles: Synthesis, Characterization, and X-ray Crystal Structures Amanda J. Gallant, Jonathan H. Chong, and Mark J. MacLachlan pp 5248 - 5250; DOI: 10.1021/ic060352s |
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An S = 2 Cyanide-Bridged Trinuclear FeIII2NiII Single-Molecule Magnet Dongfeng Li, Rodolphe Clérac, Sean Parkin, Guangbin Wang, Gordon T. Yee, and Stephen M. Holmes pp 5251 - 5253; DOI: 10.1021/ic060379b |
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Rational Design of New Bright Luminescent Zinc Diphosphonates with 12-Member Ring Channels Ruibiao Fu, Xihe Huang, Shengmin Hu, Shengchang Xiang, and Xintao Wu pp 5254 - 5256; DOI: 10.1021/ic060608u |
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Self-Assembly of a Luminescent Zinc(II) Complex: a Supramolecular Host-Guest Fluorescence Signaling System for Selective Nitrobenzene Inclusion Sanjib Das and Parimal K. Bharadwaj pp 5257 - 5259; DOI: 10.1021/ic060518p |
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Sequential Generation of One-Dimensional Networks Based on a Differentiated Bischelate-Type Ligand Bearing Both 4,5-Diazafluorene and Dithiolene Units Stéphane A. Baudron and Mir Wais Hosseini pp 5260 - 5262; DOI: 10.1021/ic0603510 |
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Largest Discrete Supramolecular Architecture Based on a Lanthanide Ion: [Lanthanum(III)18{N,N'-bis(2-pyridylmethyl)-N,N'-1,2-ethanediylbis(D-alaninate)}18(H2O)36]18+ Kenji Omata, Nagayasu Hoshi, Kuninobu Kabuto, Chizuko Kabuto, and Yoichi Sasaki pp 5263 - 5265; DOI: 10.1021/ic0605625 |
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Unexpected PtII Migration between the Calixarene Oxygen Atoms Natalie Kotzen, Israel Goldberg, Sofia Lipstman, and Arkadi Vigalok pp 5266 - 5268; DOI: 10.1021/ic0606126 |
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Theoretical Probing of Deltahedral closo-AuroBoranes BxAux2- (x = 5-12) Dmitry Yu. Zubarev, Jun Li, Lai-Sheng Wang, and Alexander I. Boldyrev pp 5269 - 5271; DOI: 10.1021/ic060615i |
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Microwave-Assisted Synthesis of a Hexanuclear MnIII Single-Molecule Magnet Constantinos J. Milios, Alina Vinslava, A. Gavin Whittaker, Simon Parsons, Wolfgang Wernsdorfer, George Christou, Spyros P. Perlepes, and Euan K. Brechin pp 5272 - 5274; DOI: 10.1021/ic0606678 |
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Preparation and Structural Characterization of Transition-Metal Complexes Featuring the Cymantrenyl(bromo)boryl Ligand Holger Braunschweig, Mario Kraft, Silvia Schwarz, Fabian Seeler, and Sascha Stellwag pp 5275 - 5277; DOI: 10.1021/ic0607080 |
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Synthesis, Structure, and Properties of a Dimeric Chromium(II) Pyrazolato Complex with a Long Chromium-Chromium Distance. Maintenance of a Dimeric Structure in Solution and Interconversion between Dimeric and Monomeric Structures Oussama M. El-Kadri, Mary Jane Heeg, and Charles H. Winter pp 5278 - 5280; DOI: 10.1021/ic060749w |
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A Cube in a Tetrahedron: Microwave-Assisted Synthesis of an Octametallic FeIII Cluster Ian A. Gass, Constantinos J. Milios, A. Gavin Whittaker, Francesca P. A. Fabiani, Simon Parsons, Mark Murrie, Spyros P. Perlepes, and Euan K. Brechin pp 5281 - 5283; DOI: 10.1021/ic0607843 |
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Electronic, Magnetic, and Structural Characterization of the Five-Coordinate, High-Spin Iron(II) Nitrato Complex [Fe(TpivPP)(NO3)]- Habib Nasri, Mary K. Ellison, Ben Shaevitz, Govind P. Gupta, and W. Robert Scheidt pp 5284 - 5290; DOI: 10.1021/ic052059i |
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Speciation of the Curium(III) Ion in Aqueous Solution: A Combined Study by Quantum Chemistry and Molecular Dynamics Simulation Tianxiao Yang and Bruce E. Bursten pp 5291 - 5301; DOI: 10.1021/ic0513787 |
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Deoligomerization by Cocomplexation: Syntheses and Structures of Aluminum-Calcium Alkoxides and Aryloxides Józef Utko, Jolanta Ejfler, S awomir Szafert,  ukasz John, Lucjan B. Jerzykiewicz, and Piotr Sobotapp 5302 - 5306; DOI: 10.1021/ic051710e |
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Biomimetic Studies on Selenoenzymes: Modeling the Role of Proximal Histidines in Thioredoxin Reductases Bani Kanta Sarma and G. Mugesh pp 5307 - 5314; DOI: 10.1021/ic052033r |
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Sensitive and Selective PET-Based Diimidazole Luminophore for ZnII Ions: A Structure-Activity Correlation Husein Salman, Shay Tal, Yulia Chuvilov, Olga Solovey, Yael Abraham, Moshe Kapon, Kinga Suwinska, and Yoav Eichen pp 5315 - 5320; DOI: 10.1021/ic051897+ |
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On the Structure and Spin States of Fe(III)-EDDHA Complexes Mar Gómez-Gallego, Israel Fernández, Daniel Pellico, Ángel Gutiérrez, Miguel A. Sierra, and Juan J. Lucena pp 5321 - 5327; DOI: 10.1021/ic0520723 |
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Synthesis, Structural Characterization, Experimental, and Computational Spectrophotometric Studies of 8-Quinolinyloxymethyphosphonate Compounds Siud Pui Man, David M. Benoit, Ester Buchaca, Fola Esan, Majid Motevalli, John Wilson, and Alice Sullivan pp 5328 - 5337; DOI: 10.1021/ic052085g |
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Synthesis, Structure, and Magnetic Properties of (6-9)-Nuclear Ni(II) Trimethylacetates and Their Heterospin Complexes with Nitroxides Victor Ovcharenko, Elena Fursova, Galina Romanenko, Igor Eremenko, Evgeny Tretyakov, and Vladimir Ikorskii pp 5338 - 5350; DOI: 10.1021/ic0522028 |
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Kinetics, Mechanism, and Computational Studies of Rhenium-Catalyzed Desulfurization Reactions of Thiiranes (Thioepoxides) Abdellatif Ibdah, William S. Jenks, and James H. Espenson pp 5351 - 5357; DOI: 10.1021/ic0521426 |
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Structurally Complex Cobalt Intermetallics Grown from Liquid Aluminum: Co19Al45Si10-x (x = 0.13) and Co5Al14Si2 Xiuni Wu, Susan Latturner, and Mercouri G. Kanatzidis pp 5358 - 5366; DOI: 10.1021/ic052165k |
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Supramolecular Architectures and Magnetic Properties of Coordination Polymers Based on Pyrazinedicarboxylato Ligands Showing Embedded Water Clusters Garikoitz Beobide, Oscar Castillo, Antonio Luque, Urko García-Couceiro, Juan P. García-Terán, and Pascual Román pp 5367 - 5382; DOI: 10.1021/ic060221r |
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Coordination Capabilities of a Novel Organic Polychlorotriphenylmethyl Monosulfonate Radical Xavi Ribas, Daniel Maspoch, Klaus Wurst, Jaume Veciana, and Concepció Rovira pp 5383 - 5392; DOI: 10.1021/ic060182j |
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Two New Hybrid Organic/Inorganic Copper(II)-Oxovanadate(V) Diphosphonates: [Cu2(phen)2(O3PCH2PO3)(V2O5)(H2O)]·H2O and [Cu2(phen)2(O3P(CH2)3PO3)(V2O5)]·C3H8. Synthesis, Structure, and Magnetic Properties Svetlana Ushak, Evgenia Spodine, Eric Le Fur, Diego Venegas-Yazigi, Jean-Yves Pivan, Walter Schnelle, Raul Cardoso-Gil, and Rüdiger Kniep pp 5393 - 5398; DOI: 10.1021/ic060152g |
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Synthesis, Crystal Structure, and Porosity Estimation of Hydrated Erbium Terephthalate Coordination Polymers Carole Daiguebonne, Nicolas Kerbellec, Kevin Bernot, Yves Gérault, André Deluzet, and Olivier Guillou pp 5399 - 5406; DOI: 10.1021/ic060241t |
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Lone-Pair Activity in Lead(II) Complexes with Unsymmetrical Lariat Ethers David Esteban-Gómez, Carlos Platas-Iglesias, Teresa Enríquez-Pérez, Fernando Avecilla, Andrés de Blas, and Teresa Rodríguez-Blas pp 5407 - 5416; DOI: 10.1021/ic060252m |
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Models of the Cytochromes: Crystal Structures and EPR Spectral Characterization of Low-Spin Bis-Imidazole Complexes of (OETPP)FeIII Having Intermediate Ligand Plane Dihedral Angles Liliya A. Yatsunyk, Alice Dawson, Michael D. Carducci, Gary S. Nichol, and F. Ann Walker pp 5417 - 5428; DOI: 10.1021/ic060283h |
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Syntheses and Characterization of Oxygen/Sulfur-Bridged Incomplete Cubane-Type Clusters, [Mo3S4Tp3]+ and [Mo3OS3Tp3]+, and a Mixed-Metal Cubane-Type Cluster, [Mo3FeS4ClTp3]. X-ray Structures of [Mo3S4Tp3]Cl, [Mo3OS3Tp3]PF6, and [Mo3FeS4ClTp3] Tsutomu Yamauchi, Hideaki Takagi, Takashi Shibahara, and Haruo Akashi pp 5429 - 5437; DOI: 10.1021/ic060293i |
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Mechanistic Studies of the Oxidative N-Dealkylation of a Substrate Tethered to Carboxylate-Bridged Diiron(II) Complexes, [Fe2(-O2CArTol)2(O2CArTol)2(N,N-Bn2en)2] Sungho Yoon and Stephen J. Lippard pp 5438 - 5446; DOI: 10.1021/ic060307k |
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Heterometallic Cr-Mn Complexes Containing Cyanide and Oxalate Bridges Yuan-Zhu Zhang, Zhe-Ming Wang, and Song Gao pp 5447 - 5454; DOI: 10.1021/ic0603003 |
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Synthesis, Structure, and Characterization of Molybdenum(VI) Imido Complexes with N-Salicylidene-2-aminophenol Martin Minelli, Frances Namuswe, Daniel Jeffrey, Amy L. Morrow, Ilia A. Guzei, Dale Swenson, Eberhard Bothe, and Thomas Weyhermüller pp 5455 - 5464; DOI: 10.1021/ic060370+ |
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Tren-Based Analogues of Bacillibactin: Structure and Stability1 Emily A. Dertz, Jide Xu, and Kenneth N. Raymond pp 5465 - 5478; DOI: 10.1021/ic060321x |
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Triple-Decker Sandwich Compounds Bearing Compact Triallyl Tripods for Molecular Information Storage Applications Kisari Padmaja, W. Justin Youngblood, Lingyun Wei, David F. Bocian, and Jonathan S. Lindsey pp 5479 - 5492; DOI: 10.1021/ic060387s |
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Homologues of the Easily Ionized Compound Mo2(hpp)4 Containing Smaller Bicyclic Guanidinates F. Albert Cotton, Carlos A. Murillo, Xiaoping Wang, and Chad C. Wilkinson pp 5493 - 5500; DOI: 10.1021/ic060449e |
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Comparison of the Crystal Structures and Magnetic Properties of the Low- and High-Temperature Forms of AgCuPO4: Crystal Structure Determination, Magnetic Susceptibility Measurements, and Spin Dimer Analysis Hamdi Ben Yahia, Etienne Gaudin, Jacques Darriet, Dadi Dai, and Myung-Hwan Whangbo pp 5501 - 5509; DOI: 10.1021/ic060484l |
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Model Peptides Based on the Binding Loop of the Copper Metallochaperone Atx1: Selectivity of the Consensus Sequence MxCxxC for Metal Ions Hg(II), Cu(I), Cd(II), Pb(II), and Zn(II) Pierre Rousselot-Pailley, Olivier Sénèque, Colette Lebrun, Serge Crouzy, Didier Boturyn, Pascal Dumy, Michel Ferrand, and Pascale Delangle pp 5510 - 5520; DOI: 10.1021/ic060430b |
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Synthesis, Structural Characterization, Gas Sorption and Guest-Exchange Studies of the Lightweight, Porous Metal-Organic Framework -[Mg3(O2CH)6] Jeffrey A. Rood, Bruce C. Noll, and Kenneth W. Henderson pp 5521 - 5528; DOI: 10.1021/ic060543v |
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Directed Synthesis of Noncentrosymmetric Molybdates Using Composition Space Analysis Thomas R. Veltman, Adam K. Stover, Amy Narducci Sarjeant, Kang Min Ok, P. Shiv Halasyamani, and Alexander J. Norquist pp 5529 - 5537; DOI: 10.1021/ic060558t |
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Conformationally Gated Photoinduced Processes within Photosensitizer-Acceptor Dyads Based on Osmium(II) Complexes with Triarylpyridinio-Functionalized Terpyridyl Ligands: Insights from Theoretical Analysis Philippe P. Lainé, Frédérique Loiseau, Sebastiano Campagna, Ilaria Ciofini, and Carlo Adamo pp 5538 - 5551; DOI: 10.1021/ic060679t |
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Luminescent Amidate-Bridged One-Dimensional Platinum(II)-Thallium(I) Coordination Polymers Assembled via Metallophilic Attraction Wanzhi Chen, Fenghui Liu, Duanjun Xu, Kazuko Matsumoto, Shinobu Kishi, and Masako Kato pp 5552 - 5560; DOI: 10.1021/ic051932c |
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Spectroscopic Characterization of Primary and Secondary Phosphine Ligation on Ruthenium(II) Complexes Shadrick I. M. Paris, Jeffrey L. Petersen, Evamarie Hey-Hawkins, and Michael P. Jensen pp 5561 - 5567; DOI: 10.1021/ic0519281 |
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Facile Synthesis of Unsymmetrical 9-Phospha- and 9-Arsafluorenes Armando A. Diaz, Jackie D. Young, Masood A. Khan, and Rudolf J. Wehmschulte pp 5568 - 5575; DOI: 10.1021/ic051976l |
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Synthesis of the Novel [W3PdS4H3(dmpe)3(CO)]+ Cubane Cluster and Kinetic Studies on the Substitution of Coordinated Hydrides in Acidic Media Andrés G. Algarra, Manuel G. Basallote, Marta Feliz, M. Jesús Fernández-Trujillo, Eva Guillamón, Rosa Llusar, and Cristian Vicent pp 5576 - 5584; DOI: 10.1021/ic052184u |
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DFT Analysis of Co-Alkyl and Co-Adenosyl Vibrational Modes in B12-Cofactors Pawel M. Kozlowski, Tadeusz Andruniow, Andrzej A. Jarzecki, Marek Z. Zgierski, and Thomas G. Spiro pp 5585 - 5590; DOI: 10.1021/ic052069j |
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Effects of Methanol on the Thermodynamics of Iron(III) [Tetrakis(pentafluorophenyl)]porphyrin Chloride Dissociation and the Creation of Catalytically Active Species for the Epoxidation of Cyclooctene Ned A. Stephenson and Alexis T. Bell pp 5591 - 5599; DOI: 10.1021/ic0521067 |
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Remarkably Efficient Hydrolysis of Methylparathion Catalyzed by [2-(2-Pyridyl)phenyl-C,N]palladium(II) Complexes Mieock Kim, Alexandre Picot, and François P. Gabbaï pp 5600 - 5606; DOI: 10.1021/ic0600578 |
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Iron(III) Coordination Properties of a Pyoverdin Siderophore Produced by Pseudomonas putida ATCC 33015 Hakim Boukhalfa, Sean D. Reilly, Ryszard Michalczyk, Srinivas Iyer, and Mary P. Neu pp 5607 - 5616; DOI: 10.1021/ic060196p |
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Si-N Bond Hydrolysis Furnishes a Planar 4-Coordinate 14-Electron Ru(II) Complex with a Triplet Ground State Amy Walstrom, Maren Pink, and Kenneth G. Caulton pp 5617 - 5620; DOI: 10.1021/ic0601743 |
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Binuclear Cyclopentadienylmetal Nitrosyls of Iron, Cobalt, and Nickel: Comparison with Related Carbonyl Derivatives Hongyan Wang, Yaoming Xie, R. Bruce King, and Henry F. Schaefer III pp 5621 - 5629; DOI: 10.1021/ic060288e |
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Stabilization of a Monomethyl Orthomolybdate in the Binding Pocket of a Dinuclear Cobalt Complex Vasile Lozan and Berthold Kersting pp 5630 - 5634; DOI: 10.1021/ic0603656 |
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Synthesis and Characterization of Novel "3 + 2" Oxorhenium Complexes, ReO[SNO][NN] Aris Chiotellis, Charalambos Tsoukalas, Maria Pelecanou, Apostolos Papadopoulos, Catherine Raptopoulou, Aris Terzis, Ioannis Pirmettis, Minas Papadopoulos, and Efstratios Chiotellis pp 5635 - 5640; DOI: 10.1021/ic0604260 |
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Synthesis and Characterization of Novel Fluorinated Poly(oxomolybdates) Alexej Michailovski, Heinz Rüegger, Denis Sheptyakov, and Greta R. Patzke pp 5641 - 5652; DOI: 10.1021/ic0604359 |
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Increasing the Ordering Temperatures in Oxalate-Based 3D Chiral Magnets: the Series [Ir(ppy)2(bpy)][MIIMIII(ox)3]·0.5H2O (MIIMIII = MnCr, FeCr, CoCr, NiCr, ZnCr, MnFe, FeFe); bpy = 2,2'-Bipyridine; ppy = 2-Phenylpyridine; ox = Oxalate Dianion) Miguel Clemente-León, Eugenio Coronado, Carlos J. Gómez-García, and Alejandra Soriano-Portillo pp 5653 - 5660; DOI: 10.1021/ic060442x |
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Novel tert-Butyl-tris(3-hydrocarbylpyrazol-1-yl)borate Ligands: Synthesis, Spectroscopic Studies, and Coordination Chemistry Olivier Graziani, Paul Hamon, Jean-Yves Thépot, Loïc Toupet, Petra Á. Szilágyi,, Gábor Molnár, Azzedine Bousseksou, Mats Tilset, and Jean-René Hamon pp 5661 - 5674; DOI: 10.1021/ic060458n |
Synthesis, Structural Characterization, Reactivity, and Thermal Stability of [5: -Me2C(C5H4)(C2B10H10)]Ti(R)(NMe2)Hong Wang, Yaorong Wang, Hoi-Shan Chan, and Zuowei Xie pp 5675 - 5683; DOI: 10.1021/ic0604664 |
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Synthesis of Tubular Titanate via a Self-Assembly and Self-Removal Process Mingdeng Wei, Haoshen Zhou, Yoshinari Konishi, Masaki Ichihara, Hideki Sugiha, and Hironori Arakawa pp 5684 - 5690; DOI: 10.1021/ic060474k |
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Ferrocenyl Compound as a Multiresponsive Calcium Chemosensor with Remarkable Fluorescence Properties in CH3CN Béatrice Delavaux-Nicot, Jérôme Maynadié, Dominique Lavabre, and Suzanne Fery-Forgues pp 5691 - 5702; DOI: 10.1021/ic060535e |
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Insights into the Mechanism of Selective Olefin Epoxidation Catalyzed by [-(SiO4)W10O32H4]4-. A Computational Study Rajeev Prabhakar, Keiji Morokuma, Craig L. Hill, and Djamaladdin G. Musaev pp 5703 - 5709; DOI: 10.1021/ic060725p |
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Adventures with Substances Containing Metals in Negative Oxidation States John E. Ellis: pp 5710 - 5710; DOI: 10.1021/ic060888d |
Issue 15
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Magnetoresistance Effects Evidencing the -d Interaction in Metallic Organic Conductors, (EDT-DSDTFVO)2MX4 (M = Fe, Ga; X = Cl, Br) Hideki Fujiwara, Toshiki Hayashi, Toyonari Sugimoto, Hiroyuki Nakazumi, Satoru Noguchi, Lin Li, Keiichi Yokogawa, Syuma Yasuzuka, Keizo Murata, and Takehiko Mori pp 5712 - 5714; DOI: 10.1021/ic060034t |
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Resolving the CO/CN Ligand Arrangement in CO-Inactivated [FeFe] Hydrogenase by First Principles Density Functional Theory Calculations Silviu Zilberman, Edward I. Stiefel, Morrel H. Cohen, and Roberto Car pp 5715 - 5717; DOI: 10.1021/ic060075p |
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Hydrogen Adsorption in an Interpenetrated Dynamic Metal-Organic Framework Banglin Chen, Shengqian Ma, Fatima Zapata, Emil B. Lobkovsky, and Jun Yang pp 5718 - 5720; DOI: 10.1021/ic060437t |
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Interfacial Charge-Transfer Switch: Ruthenium-dppz Compounds Anchored to Nanocrystalline TiO2 Alvaro Delgadillo, Mauricio Arias, Ana Maria Leiva, Bárbara Loeb, and Gerald J. Meyer pp 5721 - 5723; DOI: 10.1021/ic060427s |
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One-Pot Synthesis of Metal Primary Phosphine Complexes from O=PCl2R or PCl2R. Isolation and Characterization of Primary Alkylphosphine Complexes of a Metalloporphyrin Jie-Sheng Huang, Guang-Ao Yu, Jin Xie, Nianyong Zhu, and Chi-Ming Che pp 5724 - 5726; DOI: 10.1021/ic060553w |
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Microwave-Assisted Synthesis of 3,1,2- and 2,1,8-Re(I) and 99mTc(I)-Metallocarborane Complexes Andrew E. C. Green, Patrick W. Causey, Anika S. Louie, Andrea F. Armstrong, Laura E. Harrington, and John F. Valliant pp 5727 - 5729; DOI: 10.1021/ic0605928 |
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Configuration-Specific Synthesis of the Facial and Meridional Isomers of Tris(8-hydroxyquinolinate)aluminum (Alq3) Ryo Katakura and Yoshihiro Koide pp 5730 - 5732; DOI: 10.1021/ic060594s |
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trans-Platinum Planar Amine Compounds with [N2O2] Ligand Donor Sets: Effects of Carboxylate Leaving Groups and Steric Hindrance on Chemical and Biological Properties Genevieve H. Bulluss, Kenneth M. Knott, Erin S. F. Ma, Sheena M. Aris, Eugenio Alvarado, and Nicholas Farrell pp 5733 - 5735; DOI: 10.1021/ic060741m |
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Solvothermal in Situ Ligand Synthesis through Disulfide Cleavage: 3D (3,4)-Connected and 2D Square-Grid-Type Coordination Polymers Lei Han, Xianhui Bu, Qichun Zhang, and Pingyun Feng pp 5736 - 5738; DOI: 10.1021/ic0608041 |
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Electrical Conductivity Modulation Coupled to a High-Spin-Low-Spin Conversion in the Molecular System [FeIII(qsal)2][Ni(dmit)2]3·CH3CN·H2O Kazuyuki Takahashi, Heng-Bo Cui, Yoshinori Okano, Hayao Kobayashi, Yasuaki Einaga, and Osamu Sato pp 5739 - 5741; DOI: 10.1021/ic060852l |
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Binding Affinity of Alkynes and Alkenes to Low-Coordinate Iron Ying Yu, Jeremy M. Smith, Christine J. Flaschenriem, and Patrick L. Holland pp 5742 - 5751; DOI: 10.1021/ic052136+ |
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Electron Spin-Spin Exchange Coupling Mediated by the Porphyrin System David A. Shultz, Christopher P. Mussari, Krishna Kumar Ramanathan, and Jeff W. Kampf pp 5752 - 5759; DOI: 10.1021/ic060209z |
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Two 3D Porous Cadmium Tetrazolate Frameworks with Hexagonal Tunnels Xiang He, Can-Zhong Lu, and Da-Qiang Yuan pp 5760 - 5766; DOI: 10.1021/ic0520162 |
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Structural and Magnetic Properties of [BDTA]2[MCl4] [M = Cu (1), Co (2), and Mn (3)], Revealing an S = 1/2 Square-Lattice Antiferromagnet with Weak Magnetic Exchange Sarah S. Staniland, Andrew Harrison, Neil Robertson, Konstantin V. Kamenev, and Simon Parsons pp 5767 - 5773; DOI: 10.1021/ic052024i |
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The Structure of ([W3Q4X3(dmpe)3]+, Y-) Ion Pairs (Q = S, Se; X = H, OH, Br; Y = BF4, PF6, dmpe = Me2PCH2CH2PMe2) in Dichloromethane Solution and the Effect of Ion-Pairing on the Kinetics of Proton Transfer to the Hydride Cluster [W3S4H3(dmpe)3]+ Andrés G. Algarra, Manuel G. Basallote, M. Jesús Fernández-Trujillo, Rosa Llusar, Vicent S. Safont, and Cristian Vicent pp 5774 - 5784; DOI: 10.1021/ic0520770 |
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Modulated Preparation and Structural Diversification of ZnII and CdII Metal-Organic Frameworks with a Versatile Building Block 5-(4-Pyridyl)-1,3,4-oxadiazole-2-thiol Miao Du, Zhi-Hui Zhang, Xiao-Jun Zhao, and Qiang Xu pp 5785 - 5792; DOI: 10.1021/ic060129v |
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Incorporation of a New Type of Transition Metal Complex into the Thioarsenate Anion: Syntheses, Structures, and Properties of Two Novel Compounds [Mn3(2,2'-bipy)3(AsVS4)2]n·nH2O and Mn2(2,2'-bipy)As2IIIS5 Ming-Lai Fu, Guo-Cong Guo, Xi Liu, Wen-Tong Chen, Bing Liu, and Jin-Shun Huang pp 5793 - 5798; DOI: 10.1021/ic0600228 |
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Synthesis and Characterization of a 3D Coordination Polymer Based on Trinuclear Triangular CuII as Secondary Building Units Bin Ding, Long Yi, Peng Cheng, Dai-Zheng Liao, and Shi-Ping Yan pp 5799 - 5803; DOI: 10.1021/ic060030o |
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Size Discrimination in the Coordination Chemistry of an Isoindoline Pincer Ligand with Cd(II) and Zn(II) Mark Wicholas, Andrew D. Garrett, Morgan Gleaves, Aimee M. Morris, Melanie Rehm, Oren P. Anderson, and Agnete la Cour pp 5804 - 5811; DOI: 10.1021/ic060051i |
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Silver(I) Complexes in Coordination Supramolecular System with Bulky Acridine-Based Ligands: Syntheses, Crystal Structures, and Theoretical Investigations on C-H···Ag Close Interaction Chun-Sen Liu, Pei-Quan Chen, En-Cui Yang, Jin-Lei Tian, Xian-He Bu, Zheng-Ming Li, Hong-Wei Sun, and Zhenyang Lin pp 5812 - 5821; DOI: 10.1021/ic060087a |
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Synthesis, Crystal Structure, and Characterization of New Tetranuclear Ag(I) Complexes with Triazole Bridges Ying Wang, Long Yi, Xing Yang, Bin Ding, Peng Cheng, Dai-Zheng Liao, and, and Shi-Ping Yan pp 5822 - 5829; DOI: 10.1021/ic060155t |
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Dinuclear Cu(I) Complexes of 1,2,4,5-Tetra(7-azaindolyl)benzene: Persistent 3-Coordinate Geometry, Luminescence, and Reactivity Shu-Bin Zhao, Rui-Yao Wang, and Suning Wang pp 5830 - 5840; DOI: 10.1021/ic060237h |
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Photoelectron Spectroscopy of the Bis(dithiolene) Anions [M(mnt)2]n- (M = Fe - Zn; n = 1, 2): Changes in Electronic Structure with Variation of Metal Center and with Oxidation Tom Waters, Xue-Bin Wang, Hin-Koon Woo, and Lai-Sheng Wang pp 5841 - 5851; DOI: 10.1021/ic060255z |
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Comparative Bonding Behavior of Functional Cyclopentadienyl Ligands and Boron-Containing Analogues in Heterometallic Complexes and Clusters Pierre Croizat, Nicolas Auvray, Pierre Braunstein, and Richard Welter pp 5852 - 5866; DOI: 10.1021/ic060318d |
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Reactivity of Lanthanocene Hydroxides toward Ketene, Isocyanate, Lanthanocene Alkyl, and Triscyclopentadienyllanthanide Complexes Chunmei Zhang, Ruiting Liu, Jie Zhang, Zhenxia Chen, and Xigeng Zhou pp 5867 - 5877; DOI: 10.1021/ic0602998 |
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Ag3SnCuP10: [Ag3Sn] Tetrahedra Embedded between Adamantane-Type [P10] Cages Stefan Lange, C. Peter Sebastian, Long Zhang, Hellmut Eckert, and Tom Nilges pp 5878 - 5885; DOI: 10.1021/ic060380a |
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Synthesis and Lanthanide Coordination Properties of New 2,6-Bis(N-tert-butylacetamide)pyridine and 2,6-Bis(N-tert-butylacetamide)pyridine-N-oxide Ligands Iris Binyamin, Sylvie Pailloux, Eileen N. Duesler, Brian M. Rapko, and Robert T. Paine pp 5886 - 5892; DOI: 10.1021/ic060389c |
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Intramolecular Amine-Induced [1,3]-Sigmatropic Rearrangement in the Reactions of Aminophosphinites or Phosphites with Elemental Sulfur or Selenium P. Chandrasekaran, Joel T. Mague, and Maravanji S. Balakrishna pp 5893 - 5897; DOI: 10.1021/ic060413m |
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Synthesis and Characterization of Octa- and Hexanuclear Polyoxomolybdate Wheels: Role of the Inorganic Template and of the Counterion Anne Dolbecq, Laurent Lisnard, Pierre Mialane, Jérôme Marrot, Marc Bénard, Marie-Madeleine Rohmer, and Francis Sécheresse pp 5898 - 5910; DOI: 10.1021/ic060410+ |
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Deliberate Synthesis for Magnetostructural Study of Linear Tetranuclear Complexes BIIIMnIIMnIIBIII, MnIIIMnIIMnIIMnIII, MnIVMnIIMnIIMnIV, FeIIIMnIIMnIIFeIII, and CrIIIMnIIMnIICrIII. Influence of Terminal Ions on the Exchange Coupling Sumit Khanra, Thomas Weyhermüller, Eckhard Bill, and Phalguni Chaudhuri pp 5911 - 5923; DOI: 10.1021/ic060409a |
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Synthesis, Characterization, Reactivity, and Catalytic Potential of Model Vanadium(IV, V) Complexes with Benzimidazole-Derived ONN Donor Ligands Mannar R. Maurya, , Amit Kumar, Martin Ebel, and Dieter Rehder pp 5924 - 5937; DOI: 10.1021/ic0604922 |
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Indole Rings in Palladium(II) Complexes. Dual Mode of Metal Binding and Aromatic Ring Stacking Causing syn-anti Isomerism Masako Takani, Takeshi Takeda, Tatsuo Yajima, and Osamu Yamauchi pp 5938 - 5946; DOI: 10.1021/ic060595k |
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Methylpyrazole-Capped Two-Dimensional Supramolecular M(II) (M = Mn, Ni, Co) Assemblies Constructed by Covalent and Noncovalent Interactions: Uncommon Coordination Modes of Methylpyrazoles and Magnetic Properties Da Hye Choi, Jung Hee Yoon, Jeong Hak Lim, Hyoung Chan Kim, and Chang Seop Hong pp 5947 - 5952; DOI: 10.1021/ic060429c |
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Efficient Energy Conversion in Photochromic Ruthenium DMSO Complexes Aaron A. Rachford, Jeffrey L. Petersen, and Jeffrey J. Rack pp 5953 - 5960; DOI: 10.1021/ic0603398 |
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H2CO3 and Its Oligomers: Structures, Stabilities, Vibrational and NMR Spectra, and Acidities J. A. Tossell pp 5961 - 5970; DOI: 10.1021/ic060459f |
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Gas-Phase Generation and Electronic Structure Investigation of Chlorosulfanyl Thiocyanate, ClSSCN Li Yao, Maofa Ge, Weigang Wang, Xiaoqing Zeng, Zheng Sun, and Dianxun Wang pp 5971 - 5975; DOI: 10.1021/ic060513s |
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Dynamic Behavior of the Diphosphine Ligand in H4Ru4(CO)10(dppe) Revisited: Kinetic Data Supporting a Nondissociative Isomerization of the Dppe Ligand Srikanth Kandala and Michael G. Richmond pp 5976 - 5979; DOI: 10.1021/ic060463r |
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Synthesis and Characterization of Metal-Organic Frameworks Based on 4-Hydroxypyridine-2,6-dicarboxylic Acid and Pyridine-2,6-dicarboxylic Acid Ligands Hong-Ling Gao, Long Yi, Bin Zhao, Xiao-Qing Zhao, Peng Cheng, Dai-Zheng Liao, and Shi-Ping Yan pp 5980 - 5988; DOI: 10.1021/ic060550j |
On the Origin of the Metallic and Anisotropic Magnetic Properties of NaxCoO2 (x  0.75)M.-H. Whangbo, D. Dai, and R. K. Kremer pp 5989 - 5995; DOI: 10.1021/ic060691l |
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Synthesis, Characterization, and Electrochemistry of Diruthenium(III,II) and Monoruthenium(III) Complexes Containing Pyridyl-Substituted 2-Anilinopyridinate Ligands Karl M. Kadish, Minh Nguyen, Eric Van Caemelbecke, and John L. Bear pp 5996 - 6003; DOI: 10.1021/ic060267k |
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Polyamide Platinum Anticancer Complexes Designed to Target Specific DNA Sequences David Jaramillo, Nial J. Wheate, Stephen F. Ralph, Warren A. Howard, Yitzhak Tor, and Janice R. Aldrich-Wright pp 6004 - 6013; DOI: 10.1021/ic060383n |
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Molecular Structures of arachno-Decaborane Derivatives 6,9-X2B8H10 (X = CH2, NH, Se) Including a Gas-Phase Electron-Diffraction Study of 6,9-C2B8H14 Drahomír Hnyk, Michael Bühl, Josef Holub, Stuart A. Hayes, Derek A. Wann, Iain D. Mackie, Konstantin B. Borisenko, Heather E. Robertson, and David W. H. Rankin pp 6014 - 6019; DOI: 10.1021/ic060296v |
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High-Nuclearity Ruthenium Carbonyl Cluster Complexes Derived from 2-Amino-6-methylpyridine: Synthesis of Nonanuclear Derivatives Containing 4- and 5-Oxo Ligands Javier A. Cabeza, Ignacio del Río, Pablo García-Álvarez, and Daniel Miguel pp 6020 - 6027; DOI: 10.1021/ic060433o |
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Photoreactivity of Iron(III)-Aerobactin: Photoproduct Structure and Iron(III) Coordination Frithjof C. Küpper, Carl J. Carrano, Jens-Uwe Kuhn, and Alison Butler pp 6028 - 6033; DOI: 10.1021/ic0604967 |
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Na2[(VO)2(HPO4)2C2O4]·2H2O: Crystal Structure Determination from Combined Powder Diffraction and Solid-State NMR J. F. Colin, T. Bataille, S. E. Ashbrook, N. Audebrand, L. Le Pollès, J. Y. Pivan, and E. Le Fur pp 6034 - 6040; DOI: 10.1021/ic060483t |
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Transformation and Structural Discrimination between the Neutral {Fe(NO)2}10 Dinitrosyliron Complexes (DNICs) and the Anionic/Cationic {Fe(NO)2}9 DNICs Mu-Cheng Hung, Ming-Che Tsai, Gene-Hsiang Lee, and Wen-Feng Liaw pp 6041 - 6047; DOI: 10.1021/ic0605120 |
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Hydrogen Atom Abstraction by a Mononuclear Ferric Hydroxide Complex: Insights into the Reactivity of Lipoxygenase Christian R. Goldsmith and T. Daniel P. Stack pp 6048 - 6055; DOI: 10.1021/ic060621e |
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Redox-Induced Ligand Reorganization and Helicity Inversion in Copper Complexes of N,N-Dialkylmethionine Derivatives Steffen Zahn, Debasis Das, and James W. Canary pp 6056 - 6063; DOI: 10.1021/ic060660q |
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Oxygenation of Zinc Dialkyldithiocarbamate Complexes: Isolation, Characterization, and Reactivity of the Stoichiometric Oxygenates Daniel F. Brayton, Kristine Tanabe, Mariya Khiterer, Kian Kolahi, Joseph Ziller, John Greaves, and Patrick J. Farmer pp 6064 - 6072; DOI: 10.1021/ic060671j |
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Chemistry of the Silica Surface: Reaction with Phosphorus Pentachloride Shaokuan Zheng, Ji-Wen Feng, Joseph A. DiVerdi, and Gary E. Maciel pp 6073 - 6082; DOI: 10.1021/ic060681k |
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Electron Distribution in Iron Octaethyloxophlorin Complexes. Importance of the Fe(III) Oxophlorin Trianion Form in the Bis-pyridine and Bis-imidazole Complexes Sankar Prasad Rath, Marilyn M. Olmstead, and Alan L. Balch pp 6083 - 6093; DOI: 10.1021/ic0607033 |
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One-Dimensional Ferromagnetic Complexes Built with MnIII3O Units Jun Tao, Yuan-Zhu Zhang, Yue-Lin Bai, and Osamu Sato: pp 6094 - 6094; DOI: 10.1021/ic061029s |
Issue 16
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Expanding the Crystal Chemistry of Actinyl Peroxides: Open Sheets of Uranyl Polyhedra in Na5[(UO2)3(O2)4(OH)3](H2O)13 Karrie-Ann Kubatko and Peter C. Burns pp 6096 - 6098; DOI: 10.1021/ic0518677 |
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Crystal Structure of a CsF-Uranyl-Salen Complex. An Unusual Cesium-Chlorine Coordination Massimo Cametti, Maija Nissinen, Antonella Dalla Cort, Kari Rissanen, and Luigi Mandolini pp 6099 - 6101; DOI: 10.1021/ic060251u |
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Synthesis and Characterization of Copper(II) Complexes of Cysteinyldopa and Benzothiazine Model Ligands Related to Pheomelanin Yohannes T. Tesema, David M. Pham, and Katherine J. Franz pp 6102 - 6104; DOI: 10.1021/ic060262n |
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Near-Infrared Luminescence from Platinum(II) Diimine Compounds Christopher J. Adams, Natalie Fey, and Julia A. Weinstein pp 6105 - 6107; DOI: 10.1021/ic060399d |
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Electron Transfer vs Coordination Chemistry: Isomer-Specific Binding of HgII by an ortho-Wurster's Thiacrown Ether John W. Sibert, Philip B. Forshee, and Vincent Lynch pp 6108 - 6110; DOI: 10.1021/ic060624r |
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Novel Configurational Structures of Sodium Tetrakis(3-heptafluorobutylryl-(+)-camphorato) Ln(III) Complexes with a Trapped Na+ by Na+···FC Interactions in the Solid State and in Solution Dai Shirotani, Takayoshi Suzuki, and Sumio Kaizaki pp 6111 - 6113; DOI: 10.1021/ic0606633 |
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Carbon Monoxide Ligand-Exchange Reaction of Triruthenium Cluster Complexes Induced by Photosensitized Electron Transfer: A New Type of Photoactive CO Color Sensor Mitsunari Itou, Yasuyuki Araki, Osamu Ito, and Hiroaki Kido pp 6114 - 6116; DOI: 10.1021/ic060751n |
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New Hybrid [2]Catenanes Based on a 4,4'-Bipyridinium Ligand Marcos Chas, Elena Pia, Rosa Toba, Carlos Peinador, and José M. Quintela pp 6117 - 6119; DOI: 10.1021/ic0605165 |
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Gold(III) and Platinum(II) Polypyridyl Double Salts and a General Metathesis Route to Metallophilic Interactions Rebecca Hayoun, Diane K. Zhong, Arnold L. Rheingold, and Linda H. Doerrer pp 6120 - 6122; DOI: 10.1021/ic060830z |
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Bis(bismuth)toluene Inverted-Sandwich Complex Supported by Aminetris(phenoxide) Ligands Luke E. Turner, Matthew G. Davidson, Matthew D. Jones, Holger Ott, Verena S. Schulz, and Paul J. Wilson pp 6123 - 6125; DOI: 10.1021/ic0609406 |
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Inverse Aggregation Behavior of Alkali-Metal Triazenides Hyui Sul Lee and Mark Niemeyer pp 6126 - 6128; DOI: 10.1021/ic060873f |
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Novel Heterometallic 3d-4f Metal-Azido Complex of Mixed Ligands with Unprecedented Structure Type: Synthesis, Structure, and Magnetic Properties Fu-Chen Liu, Yong-Fei Zeng, Jiao Jiao, Jian-Rong Li, Xian-He Bu, Joan Ribas, and Stuart R. Batten pp 6129 - 6131; DOI: 10.1021/ic060773+ |
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New Stepwise Approach to Inert Heterometallic Triple-Stranded Helicates Nicholas C. Fletcher, Rodney T. Brown, and Andrew P. Doherty pp 6132 - 6134; DOI: 10.1021/ic060966x |
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Characterization of the Chloranilate(3-) Radical as a Strong Spin-Coupling Bridging Ligand Kil Sik Min, Arnold L. Rheingold, Antonio DiPasquale, and Joel S. Miller pp 6135 - 6137; DOI: 10.1021/ic061076k |
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Metal-Controlled Assembly and Selectivity of a Urea-Based Anion Receptor Valeria Amendola, Massimo Boiocchi, Benoît Colasson, and Luigi Fabbrizzi pp 6138 - 6147; DOI: 10.1021/ic060160x |
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Chloro and Hydroxo Forms of a Boron(III) Subtriazaporphyrin Macrocycle Jay R. Stork, Jeffrey J. Brewer, Takamitsu Fukuda, Jeffrey P. Fitzgerald, Gordon T. Yee, Alexander Y. Nazarenko, Nagao Kobayashi, and William S. Durfee pp 6148 - 6151; DOI: 10.1021/ic051093u |
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Series of New Cationic Iridium(III) Complexes with Tunable Emission Wavelength and Excited State Properties: Structures, Theoretical Calculations, and Photophysical and Electrochemical Properties Qiang Zhao, Shujuan Liu, Mei Shi, Chuanming Wang, Mengxiao Yu, Lei Li, Fuyou Li, Tao Yi, and Chunhui Huang pp 6152 - 6160; DOI: 10.1021/ic052034j |
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Theoretical Studies of Phosphorescence Spectra of Tris(2,2'-bipyridine) Transition Metal Compounds Koichi Nozaki, Keisei Takamori, Yuji Nakatsugawa, and Takeshi Ohno pp 6161 - 6178; DOI: 10.1021/ic052068r |
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Control of Copper(I) Iodide Architectures by Ligand Design: Angular versus Linear Bridging Ligands Frédéric Thébault, Sarah A. Barnett, Alexander J. Blake, Claire Wilson, Neil R. Champness, and Martin Schröder pp 6179 - 6187; DOI: 10.1021/ic052130k |
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Polyaryl Ether Dendrimer with a 4-Phenylacetyl-5-pyrazolone-based Terbium(III) Complex as Core: Synthesis and Photopysical Properties Li Shen, Mei Shi, Fuyou Li, Dengqing Zhang, Xianghong Li, Enxian Shi,, Tao Yi, Yukou Du, and Chunhui Huang pp 6188 - 6197; DOI: 10.1021/ic052148v |
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A Topological Study of the Geometry of AF6E Molecules: Weak and Inactive Lone Pairs Julien Pilmé, Edward A. Robinson, and Ronald J. Gillespie pp 6198 - 6204; DOI: 10.1021/ic052182+ |
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Bis(acetylacetonato)tricarbonyl Tungsten(II): A Convenient Precursor to Chiral Bis(acac) Tungsten(II) Complexes Andrew B. Jackson, Peter S. White, and Joseph L. Templeton pp 6205 - 6213; DOI: 10.1021/ic0600329 |
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Evaluation of Hexaniobate Nanoscrolls as Support for Immobilization of a Copper Complex Catalyst Marcos A. Bizeto, Wendel A. Alves, César A. S. Barbosa, Ana M. D. C. Ferreira, and Vera R. L. Constantino pp 6214 - 6221; DOI: 10.1021/ic0600580 |
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Polymer-Bound Dirhodium Tetracarboxylate Films for Fluorescent Detection of Nitric Oxide Rhett C. Smith, Andrew G. Tennyson, and Stephen J. Lippard pp 6222 - 6226; DOI: 10.1021/ic060070s |
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On the Disorder of the Cl Atom Position in and Its Probable Effect on the Magnetic Properties of (CuCl)LaNb2O7 Myung-Hwan Whangbo and Dadi Dai pp 6227 - 6234; DOI: 10.1021/ic060104w |
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Degradation of Ionized OV(OCH3)3 in the Gas Phase. From the Neutral Compound All the Way down to the Quasi-terminal Fragments VO+ and VOH+ Detlef Schröder, Marianne Engeser, Helmut Schwarz, Esther C. E. Rosenthal, Jens Döbler, and Joachim Sauer pp 6235 - 6245; DOI: 10.1021/ic060150w |
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The Very Covalent Diammino(o-benzoquinonediimine) Dichlororuthenium(II). An Example of Very Strong -Back-Donation Julia Rusanova, Eduard Rusanov, S. I. Gorelsky, Dharamdat Christendat, Raluca Popescu, Abdiaziz A. Farah, Rémi Beaulac, Christian Reber, and A. B. P. Lever pp 6246 - 6262; DOI: 10.1021/ic060220z |
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Synthesis, Structure, and Anticancer Activity of Gallium(III) Complexes with Asymmetric Tridentate Ligands: Growth Inhibition and Apoptosis Induction of Cisplatin-Resistant Neuroblastoma Cells Rajendra Shakya, Fangyu Peng, Jianguo Liu, Mary Jane Heeg, and Claudio N. Verani pp 6263 - 6268; DOI: 10.1021/ic060106g |
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Formation and Reactivity of Ir(III) Hydroxycarbonyl Complexes Paul I. P. Elliott, Claire E. Haslam, Sharon E. Spey, and Anthony Haynes pp 6269 - 6275; DOI: 10.1021/ic0601844 |
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Two Cobalt(II) 5-Aminoisophthalate Complexes and Their Stable Supramolecular Microporous Frameworks En Tang, Yu-Mei Dai, Jian Zhang, Zhao-Ji Li, Yuan-Gen Yao, Jie Zhang, and Xu-Dong Huang pp 6276 - 6281; DOI: 10.1021/ic0602244 |
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Influence of the "Innocent" Ligands on the MLCT Excited-State Behavior of Mono(bipyridine)ruthenium(II) Complexes: A Comparison of X-ray Structures and 77 K Luminescence Properties Yuan-Jang Chen, Puhui Xie, Mary Jane Heeg, and John F. Endicott pp 6282 - 6297; DOI: 10.1021/ic0602547 |
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Molecular and Electronic Structures of Tetrahedral Complexes of Nickel and Cobalt Containing N,N'-Disubstituted, Bulky o-Diiminobenzosemiquinonate(1-) -Radical Ligands Krzysztof Ch opek, Eberhard Bothe, Frank Neese, Thomas Weyhermüller, and Karl Wieghardtpp 6298 - 6307; DOI: 10.1021/ic060242l |
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Crystal Structures and Magnetic and Luminescent Properties of a Series of Homodinuclear Lanthanide Complexes with 4-Cyanobenzoic Ligand Yan Li, Fa-Kun Zheng, Xi Liu, Wen-Qiang Zou, Guo-Cong Guo, Can-Zhong Lu, and Jin-Shun Huang pp 6308 - 6316; DOI: 10.1021/ic0602603 |
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Platinum(IV) Analogues of AMD473 (cis-[PtCl2(NH3)(2-picoline)]): Preparative, Structural, and Electrochemical Studies Andrew R. Battle, Robin Choi, David E. Hibbs, and Trevor W. Hambley pp 6317 - 6322; DOI: 10.1021/ic060273g |
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Water Induces a Structural Conversion and Accelerates the Oxygenation of Carboxylate-Bridged Non-Heme Diiron Enzyme Synthetic Analogues Min Zhao, Datong Song, and Stephen J. Lippard pp 6323 - 6330; DOI: 10.1021/ic0602906 |
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Metal-Organic Frameworks Derived from Imidazolium Dicarboxylates and Group I and II Salts Zhaofu Fei, Tilmann J. Geldbach, Rosario Scopelliti, and Paul J. Dyson pp 6331 - 6337; DOI: 10.1021/ic060297n |
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Tuning the Rate and pH Accessibility of a Conformational Electron Transfer Gate Saritha Baddam and Bruce E. Bowler pp 6338 - 6346; DOI: 10.1021/ic0603712 |
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Palladium(II) and Platinum(II) Organometallic Complexes with the Model Nucleobase Anions of Thymine, Uracil, and Cytosine: Antitumor Activity and Interactions with DNA of the Platinum Compounds José Ruiz, Julia Lorenzo, Laura Sanglas, Natalia Cutillas, Consuelo Vicente, María Dolores Villa, Francesc X. Avilés, Gregorio López, Virtudes Moreno, José Pérez, and Delia Bautista pp 6347 - 6360; DOI: 10.1021/ic060374e |
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Ionothermal Synthesis of Metal Oxalatophosphonates with a Three-Dimensional Framework Structure: Na2M3(C2O4)3(CH3PO3H)2 (M = FeII and MnII) Chun-Po Tsao, Chyi-Yang Sheu, Ninh Nguyen, and Kwang-Hwa Lii pp 6361 - 6364; DOI: 10.1021/ic0603959 |
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Synthesis, Crystal and Band Structures, and Optical Properties of a New Quaternary Metal Pnictidehalide: (Hg2Cd2As2Br)Br Jian-Ping Zou, Guo-Cong Guo, Wen-Tong Chen, Xi Liu, Ming-Lai Fu, Zhang-Jing Zhang, and Jin-Shun Huang pp 6365 - 6369; DOI: 10.1021/ic060503r |
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The HETTAP Approach: Self-Assembly and Metal Ion Sensing of Dumbbell-Shaped Molecules and Clip Molecules Michael Schmittel, Venkateshwarlu Kalsani, Prasenjit Mal, and Jan W. Bats pp 6370 - 6377; DOI: 10.1021/ic060403l |
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Angle-Dependent Electronic Effects in 4,4'-Bipyridine-Bridged Ru3 Triangle and Ru4 Square Complexes Louise A. Berben, Mary C. Faia, Nathan R. M. Crawford, and Jeffrey R. Long pp 6378 - 6386; DOI: 10.1021/ic060570l |
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Transition from a Nonbonding to a Bonding Interaction in a Tetranuclear [Mo2]2(-OR)4 Cluster F. Albert Cotton, Zhong Li, Chun Y. Liu, Carlos A. Murillo, and Qinliang Zhao pp 6387 - 6395; DOI: 10.1021/ic060604p |
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Syntheses and Characterization of Unsymmetric Dicationic Salts Incorporating Imidazolium and Triazolium Functionalities Ruihu Wang, Chuan-Ming Jin, Brendan Twamley, and Jean'ne M. Shreeve pp 6396 - 6403; DOI: 10.1021/ic060822i |
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Low-Temperature Synthesis of -MnO2 Hollow Urchins and Their Application in Rechargeable Li+ Batteries Benxia Li, Guoxin Rong, Yi Xie, Lunfeng Huang, and Chuanqi Feng pp 6404 - 6410; DOI: 10.1021/ic0606274 |
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Synthesis, Structures, and Olefin Polymerization Capability of Vanadium(4+) Imido Compounds with fac-N3 Donor Ligands Helen R. Bigmore, Martin A. Zuideveld, Radoslaw M. Kowalczyk, Andrew R. Cowley, Mirko Kranenburg, Eric J. L. McInnes, and Philip Mountford pp 6411 - 6423; DOI: 10.1021/ic060454i |
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Three Novel Zinc(II) Sulfonate-Phosphonates with Tetranuclear or Hexanuclear Cluster Units Zi-Yi Du, Hai-Bing Xu, and Jiang-Gao Mao pp 6424 - 6430; DOI: 10.1021/ic0606577 |
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Molecular Oxygen Dianions Trapped in Lithium Cluster Cages Qiong Luo, Qian-Shu Li, Jun Zhang, Yaoming Xie, Paul v. R. Schleyer, and Henry F. Schaefer, III pp 6431 - 6434; DOI: 10.1021/ic060825v |
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Nonheme Oxoiron(IV) Complexes of Tris(2-pyridylmethyl)amine with cis-Monoanionic Ligands Jan-Uwe Rohde, Audria Stubna, Emile L. Bominaar, Eckard Münck, Wonwoo Nam, and Lawrence Que, Jr. pp 6435 - 6445; DOI: 10.1021/ic060740u |
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Anion Separation by Selective Crystallization of Metal-Organic Frameworks Radu Custelcean, Tamara J. Haverlock, and Bruce A. Moyer pp 6446 - 6452; DOI: 10.1021/ic060958g |
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Silane Complexes of Electrophilic Metal Centers Steven L. Matthews, Vincent Pons, and D. Michael Heinekey pp 6453 - 6459; DOI: 10.1021/ic052134p |
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Ferromagnetic Coupling Promoted by 3N:2N Bridging System Asako Igashira-Kamiyama, Takashi Kajiwara, Takumi Konno, and Tasuku Ito pp 6460 - 6466; DOI: 10.1021/ic0520925 |
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Structural Evolution in Polyoxometalates: A DFT Study of Dimerization Processes in Lindqvist and Keggin Cluster Anions Xavier López, Ira A. Weinstock, Carles Bo, Jose Pedro Sarasa, and Josep M. Poblet pp 6467 - 6473; DOI: 10.1021/ic060112c |
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Analogues of Zinpyr-1 Provide Insight into the Mechanism of Zinc Sensing Christian R. Goldsmith and Stephen J. Lippard pp 6474 - 6478; DOI: 10.1021/ic060378j |
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meso-Porphyrinylphosphine Oxides: Mono- and Bidentate Ligands for Supramolecular Chemistry and the Crystal Structures of Monomeric {[10,20-Diphenylporphyrinatonickel(II)-5,15-diyl]-bis-[P(O)Ph2] and Polymeric Self-Coordinated {[10,20-Diphenylporphyrinatozinc(II)-5,15-diyl]-bis-[P(O)Ph2]} Farzad Atefi, John C. McMurtrie, Peter Turner, Martin Duriska, and Dennis P. Arnold pp 6479 - 6489; DOI: 10.1021/ic060372u |
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Titanium and Zirconium Complexes of a Phosphorus-Containing p-tert-Butylcalix[5]arene Ligand: Importance of Metal and Conformation on Ligand/Metal Binding Maomian Fan, Hongming Zhang, and Michael Lattman pp 6490 - 6496; DOI: 10.1021/ic0601283 |
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Systematic Study on the Structures and Reactivity of Hydrazobenzenes and Azobenzenes Bearing a Chalcogenophosphoryl Group Masaki Yamamura, Naokazu Kano, and Takayuki Kawashima pp 6497 - 6507; DOI: 10.1021/ic0601790 |
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On the Preparation of Coordination Polymers by Controlled Thermal Decomposition: Synthesis, Crystal Structures, and Thermal Properties of Zinc Halide Pyrazine Coordination Compounds Gaurav Bhosekar, Inke Jess, and Christian Näther pp 6508 - 6515; DOI: 10.1021/ic060298f |
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Titanium(IV) and Zirconium(IV) Amido Complexes Derived from the Azaoxa Macrocycle 3,3-Dimethyl-1,5-diaza-8-oxacyclodecane Robin M. Porter, Andreas A. Danopoulos, and Gillian Reid pp 6516 - 6522; DOI: 10.1021/ic060302n |
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Mechanistic Studies on the Nitrite-Catalyzed Reductive Nitrosylation of Highly Charged Anionic and Cationic FeIII Porphyrin Complexes Joo-Eun Jee and Rudi van Eldik pp 6523 - 6534; DOI: 10.1021/ic0603104 |
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Supramolecular Co(II)-[2 × 2] Grids: Metamagnetic Behavior in a Single Molecule Oliver Waldmann, Mario Ruben, Ulrich Ziener, Paul Müller, and Jean M. Lehn pp 6535 - 6540; DOI: 10.1021/ic060619n |
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Dinuclear Bis(1,2-diaryl-1,2-ethylenedithiolato)iron Complexes: [FeIII2(L)4]n (n = 2-, 1-, 0, 1+) Apurba K. Patra, Eckhard Bill, Thomas Weyhermüller, Keira Stobie, Zoe Bell, Michael D. Ward, Jon A. McCleverty, and Karl Wieghardt pp 6541 - 6548; DOI: 10.1021/ic060665n |
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Cesium Hydridotris(trifluoromethyl)borate, Cs[(CF3)3BH] Jens Geier, Gottfried Pawelke, and Helge Willner pp 6549 - 6554; DOI: 10.1021/ic0604361 |
Issue 17
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Excited-State Mixed Valence in Transition Metal Complexes Edward A. Plummer and Jeffrey I. Zink pp 6556 - 6558; DOI: 10.1021/ic060847h |
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Highly Diastereoselective Oxidative Addition of Methyl Iodide to a Chiral Square-Planar Complex Mesfin Janka, Abdurrahman Ç. Atesin, Daniel J. Fox, Christine Flaschenriem, William W. Brennessel, and Richard Eisenberg pp 6559 - 6561; DOI: 10.1021/ic052027v |
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Cubic Octanuclear Aluminum Fluoride Phosphonate Jan Kratochvil, Marek Necas, Vaclav Petricek, and Jiri Pinkas pp 6562 - 6564; DOI: 10.1021/ic060344b |
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Luminescently Tagged 2,2'-Bipyridine Complex of FeII: Synthesis and Photophysical Studies of 4-[N-(2-Anthryl)carbamoyl]-4'-methyl-2,2'-bipyridine David F. Zigler, Mark C. Elvington, Julie Heinecke, and Karen J. Brewer pp 6565 - 6567; DOI: 10.1021/ic060207e |
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Periodic Density Functional Theory Investigation of the Uranyl Ion Sorption on the TiO2 Rutile (110) Face Hadrien Perron, Christophe Domain, Jérôme Roques, Romuald Drot, Eric Simoni, and Hubert Catalette pp 6568 - 6570; DOI: 10.1021/ic0603914 |
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A Supramolecular Hexameric Ring from Alumazene and Methylsulfonate Jiri Löbl, Jiri Pinkas, Herbert W. Roesky, Winfried Plass, and Helmar Görls pp 6571 - 6573; DOI: 10.1021/ic060490h |
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Characterization of the First N2S(alkylthiolate)lead Compound: A Model for Three-Coordinate Lead in Biological Systems Ryan J. Andersen, Robert C. diTargiani, Robert D. Hancock, Charlotte L. Stern, David P. Goldberg, and Hilary A. Godwin pp 6574 - 6576; DOI: 10.1021/ic060497z |
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Two Chiral Metal Clusters Derived from Nucleophilic Addition of L-proline to Di-2-pyridyl Ketone Yamin Li, Shengchang Xiang, Tianlu Sheng, Jianjun Zhang, Shengmin Hu, Ruibiao Fu, Xihe Huang, and Xintao Wu pp 6577 - 6579; DOI: 10.1021/ic060530h |
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A Tantalum(V) Carbene Complex: Formation of a Carbene-Bis(phenoxide) Ligand by Sequential Proton and Hydride Abstraction Takahito Watanabe, Tsukasa Matsuo, and Hiroyuki Kawaguchi pp 6580 - 6582; DOI: 10.1021/ic0608492 |
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Neutral {Fe(NO)2}9 Dinitrosyliron Complex (DNIC) [(SC6H4-o-NHCOPh)(Im)Fe(NO)2] (Im = Imidazole): Interconversion among the Anionic/Neutral {Fe(NO)2}9 DNICs and Roussin's Red Ester Ming-Li Tsai and Wen-Feng Liaw pp 6583 - 6585; DOI: 10.1021/ic0608849 |
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Hydrothermal Synthesis of a Three-Dimensional Organic-Inorganic Hybrid Network Formed by Poly(oxomolybdophosphate) Anions and Nickel Coordination Cations Wen-Jung Chang, Yau-Chen Jiang, Sue-Lein Wang, and Kwang-Hwa Lii pp 6586 - 6588; DOI: 10.1021/ic060911v |
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Technetium Complexes with Triazacyclononane Henrik Braband and Ulrich Abram pp 6589 - 6591; DOI: 10.1021/ic060569m |
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Trinuclear Gold(I) Triazolates: A New Class of Wide-Band Phosphors and Sensors Chi Yang, Marc Messerschmidt, Philip Coppens, and Mohammad A. Omary pp 6592 - 6594; DOI: 10.1021/ic060943i |
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Air-Stable Titanium Alkoxide Based Metal-Organic Framework as an Initiator for Ring-Opening Polymerization of Cyclic Esters Christopher J. Chuck, Matthew G. Davidson, Matthew D. Jones, Gabriele Kociok-Köhn, Matthew D. Lunn, and Stephen Wu pp 6595 - 6597; DOI: 10.1021/ic060969+ |
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Stabilization by a Divalent Transition Metal in Lead Indium Quaternary Selenide, Fe0.47Pb8.04In17.37Se34, and Specific Indium Coordination Yoshitaka Matsushita, Kazumasa Sugiyama, and Yutaka Ueda pp 6598 - 6600; DOI: 10.1021/ic0611600 |
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Hydrogen Bonding Cavities Regulating Redox Behavior and Binding of Metal-Bound Ligands Laurent Metteau, Simon Parsons, and Juan C. Mareque-Rivas pp 6601 - 6603; DOI: 10.1021/ic0612193 |
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Bi3+/M2+ Oxyphosphate: A Continuous Series of Polycationic Species from the 1D Single Chain to the 2D Planes. Part 1: From HREM Images to Crystal-Structure Deduction M. Huvé, M. Colmont, and O. Mentré pp 6604 - 6611; DOI: 10.1021/ic060342r |
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Bi3+/M2+ Oxyphosphate: A Continuous Series of Polycationic Species from the 1D Single Chain to the 2D Planes. Part 2: Crystal Structure of Three Original Structural Types Showing a Combination of New Ribbonlike Polycations Marie Colmont, Marielle Huvé, and Olivier Mentré pp 6612 - 6621; DOI: 10.1021/ic060343j |
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Hydrothermal Synthesis and Characterization of Two Cobalt Phosphates Based on Double-Four-Ring Units with Fluorine-Occlusion and Phosphite-Substitution Modifications Wei-Kuo Chang, Ching-Shuei Wur, Sue-Lein Wang, and Ray-Kuang Chiang pp 6622 - 6627; DOI: 10.1021/ic051634f |
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Neutral and Cationic Complexes with P-Bonded 2-Pyridylphosphines as N-Donor Ligands toward Rhodium. Electrical Charge vs Steric Hindrance on the Conformational Control Juan A. Casares, Pablo Espinet, José M. Martín-Álvarez, and Verónica Santos pp 6628 - 6636; DOI: 10.1021/ic0600477 |
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Crystallographic Evidence of Nitrate- Interactions Involving the Electron-Deficient 1,3,5-Triazine Ring Palanisamy Uma Maheswari, Barbara Modec, Andrej Pevec, Bojan Kozlev ar, Chiara Massera, Patrick Gamez, and Jan Reedijkpp 6637 - 6645; DOI: 10.1021/ic060101j |
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Tetranuclear Copper(II) Complexes Bridged by -D-Glucose-1-Phosphate and Incorporation of Sugar Acids through the Cu4 Core Structural Changes Merii Kato, Ajay Kumar Sah, Tomoaki Tanase, and Masahiro Mikuriya pp 6646 - 6660; DOI: 10.1021/ic060202h |
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Hydrothermal Synthesis of Rare-Earth Fluoride Nanocrystals Xun Wang, Jing Zhuang, Qing Peng, and Yadong Li pp 6661 - 6665; DOI: 10.1021/ic051683s |
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Aggregation in Nanobundles and the Effect of Diverse Environments on the Solution-Phase Photochemistry and Photophysics of -Re(CO)3L+ (L= 1,10-phenanthroline, 2,2'-bipyridine) Pendants Bonded to Poly(4-vinylpyridine) Ezequiel Wolcan, Mario R. Feliz, Jose L. Alessandrini, and Guillermo Ferraudi pp 6666 - 6677; DOI: 10.1021/ic060266s |
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Copper(I) Coordination Polymers [{Cu(-X)}2{RP(-NtBu)}2]n (R = OC6H4OMe-o; X = Cl, Br, and I) and Their Reversible Conversion into Mononuclear Complexes [CuX{(RP(-NtBu))2}2]: Synthesis and Structural Characterization P. Chandrasekaran, Joel T. Mague, and Maravanji S. Balakrishna pp 6678 - 6683; DOI: 10.1021/ic060464j |
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Two-Dimensional Indium Sulfide Framework Constructed from Pentasupertetrahedral P1 and Supertetrahedral T2 Clusters Qichun Zhang, Xianhui Bu, Lei Han, and Pingyun Feng pp 6684 - 6687; DOI: 10.1021/ic060367q |
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Oxacalix[3]arene Complexes with the ReI(CO)3 Fragment Matthias Hinrichs, Florian R. Hofbauer, Peter Klüfers, and Mihael Suhanji pp 6688 - 6693; DOI: 10.1021/ic0603048 |
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Coordination Polymers with End-On Azido and Pyridine Carboxylate N-Oxide Bridges Displaying Long-Range Magnetic Ordering with Low Dimensional Character Zheng He, Zhe-Ming Wang, Song Gao, and Chun-Hua Yan pp 6694 - 6705; DOI: 10.1021/ic060225w |
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Synthesis and Characterization of Imidocubanes with Exocube GeIV and SnIV Substituents: [M(3-NGeMe3)]4 (M = Sn, Ge, Pb); [Sn(3-NSnMe3)]4 Jack F. Eichler, Oliver Just, and William S. Rees, Jr. pp 6706 - 6712; DOI: 10.1021/ic060331y |
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High-Nuclearity Manganese and Iron Complexes with the Anionic Ligand Methyl Salicylimidate Meenal D. Godbole, Olivier Roubeau, Allison M. Mills, Huub Kooijman, Anthony L. Spek, and Elisabeth Bouwman pp 6713 - 6722; DOI: 10.1021/ic0605322 |
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Dimers of Heptapnictide Anions: As144- and P144- in the Crystal Structures of [Rb(18-crown-6)]4As14·6NH3 and [Li(NH3)4]4P14·NH3 Tobias Hanauer, Jürgen C. Aschenbrenner, and Nikolaus Korber pp 6723 - 6727; DOI: 10.1021/ic060418j |
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13C NMR Studies of the Electronic Structure of Low-Spin Iron(III) Tetraphenylchlorin Complexes Akira Ikezaki, Mikio Nakamura, Sandrine Juillard, and Gérard Simonneaux pp 6728 - 6739; DOI: 10.1021/ic060508o |
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Carbon Dioxide Fixation by an Unprecedented Hydroxo Lead-Chromium Carbonyl Complex: Synthesis, Reactivity, and Theoretical Calculations Miao-Hsing Hsu, Rung-Tsang Chen, Wen-Shyan Sheu, and Minghuey Shieh pp 6740 - 6747; DOI: 10.1021/ic060554o |
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Synthesis and Coordination Chemistry of a Novel Bidentate Phosphine: 6-(Diphenylphosphino)-1,3,5-triaza-7-phosphaadamantane (PTA-PPh2) Gene W. Wong, Jennifer L. Harkreader, Charles A. Mebi, and Brian J. Frost pp 6748 - 6755; DOI: 10.1021/ic060576a |
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2D LnIIIRuIII2 Compounds Constructed from trans-[Ru(acac)2(CN)2]-. Syntheses, Structures, and Magnetic Properties Wai-Fun Yeung, Tai-Chu Lau, Xin-Yi Wang, Song Gao, Lap Szeto, and Wing-Tak Wong pp 6756 - 6760; DOI: 10.1021/ic060580m |
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Neutral Molecular Pd6 Hexagons Using 3-P2O-Terdentate Ligands Mark R. J. Elsegood, Martin B. Smith, and Paul M. Staniland pp 6761 - 6770; DOI: 10.1021/ic060629o |
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The Neglected Pt-N(sulfonamido) Bond in Pt Chemistry. New Fluorophore-Containing Pt(II) Complexes Useful for Assessing Pt(II) Interactions with Biomolecules Anna Maria Christoforou, Patricia A. Marzilli, and Luigi G. Marzilli pp 6771 - 6781; DOI: 10.1021/ic0606375 |
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A Family of [Mn6] Complexes Featuring Tripodal Ligands Constantinos J. Milios, Maria Manoli, Gopalan Rajaraman, Abhudaya Mishra, Laura E. Budd, Fraser White, Simon Parsons, Wolfgang Wernsdorfer, George Christou, and Euan K. Brechin pp 6782 - 6793; DOI: 10.1021/ic060676g |
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Ligand-Promoted Solvent-Dependent Ionization and Conformational Equilibria of Re(CO)3Br[CH2(S-tim)2] (tim = 1-methylthioimidazolyl). Crystal Structures of Re(CO)3Br[CH2(S-tim)2] and {Re(CO)3(CH3CN)[CH2(S-tim)2]}(PF6) Rosalice M. Silva, Brendan J. Liddle, Sergey J. Lindeman, Mark D. Smith, and James R. Gardinier pp 6794 - 6802; DOI: 10.1021/ic060765t |
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Palladium Complexes of a Phosphorus Ylide with Two Stabilizing Groups: Synthesis, Structure, and DFT Study of the Bonding Modes Larry R. Falvello, Juan Carlos Ginés, Jorge J. Carbó, Agustí Lledós, Rafael Navarro, Tatiana Soler, and Esteban P. Urriolabeitia pp 6803 - 6815; DOI: 10.1021/ic060706f |
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13C and 15N NMR Studies of Iron-Bound Cyanides of Heme Proteins and Related Model Complexes: Sensitive Probe for Detecting Hydrogen-bonding Interactions at the Proximal and Distal Sides Hiroshi Fujii and Tadashi Yoshida pp 6816 - 6827; DOI: 10.1021/ic0607383 |
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On the Paucity of Molecular Actinide Complexes with Unsupported Metal-Metal Bonds: A Comparative Investigation of the Electronic Structure and Metal-Metal Bonding in U2X6 (X = Cl, F, OH, NH2, CH3) Complexes and d-Block Analogues Germán Cavigliasso and Nikolas Kaltsoyannis pp 6828 - 6839; DOI: 10.1021/ic060777e |
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Ba4Ga2B8O18Cl2·NaCl: A New Polar Structure with NaCl Inclusion R. K. Li and Yi Yu pp 6840 - 6843; DOI: 10.1021/ic060786n |
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A Novel ZnII-Sensitive Fluorescent Chemosensor Assembled within Aminopropyl-Functionalized Mesoporous SBA-15 Ling Gao, Ying Wang, Jianqiang Wang, Li Huang, Liying Shi, Xiaoxing Fan, Zhigang Zou, Tao Yu, Mei Zhu, and Zhaosheng Li pp 6844 - 6850; DOI: 10.1021/ic0516562 |
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Optimizing Small Molecule Activation and Cleavage in Three-Coordinate M[N(R)Ar]3 Complexes Gemma J. Christian, Robert Stranger, and Brian F. Yates pp 6851 - 6859; DOI: 10.1021/ic051778u |
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Preparation and Crystal Structure of Dual-Functional Precursor Complex Bis(acetylacetonato)nickel(II) with 4-Pyridyltetrathiafulvalene Lei Wang, Bin Zhang, and Jingping Zhang pp 6860 - 6863; DOI: 10.1021/ic060095r |
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Phosphorus(I) Iodide: A Versatile Metathesis Reagent for the Synthesis of Low Oxidation State Phosphorus Compounds Bobby D. Ellis and Charles L. B. Macdonald pp 6864 - 6874; DOI: 10.1021/ic060186o |
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Structural, Redox, and Photophysical Studies of the Tetra(pyridyl)porphyrin Complex Containing Four (2,2'-Bipyridine)(2,2':6',2' '-terpyridine)ruthenium(II) Groups Hiroki Kon, Kiyoshi Tsuge, Taira Imamura, Yoichi Sasaki, Shoji Ishizaka, and Noboru Kitamura pp 6875 - 6883; DOI: 10.1021/ic0602852 |
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Proton-Induced Luminescence of Mono- and Dinuclear Rhenium(I) Tricarbonyl Complexes Containing 4-Pyridinealdazine Mauricio Cattaneo, Florencia Fagalde, and Néstor E. Katz pp 6884 - 6891; DOI: 10.1021/ic060287m |
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Reactivity of (Ferrocenylmethyl)phosphine toward Palladium and Platinum Chlorides. X-ray Structure of [Pd(PH2CH2Fc)Cl(-PHCH2Fc)]4 (Fc = Ferrocenyl), a Unique Complex Containing a Pd4P4 Cycle Maria Michela Dell'Anna, Ulli Englert, Mario Latronico, Pablo Lorenzo Luis, Piero Mastrorilli, Daniela Giardina Papa, Cosimo Francesco Nobile, and Maurizio Peruzzini pp 6892 - 6900; DOI: 10.1021/ic060311w |
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Cube-Type Nitrido Complexes Containing Titanium and Zinc/Copper Avelino Martín, Noelia Martínez-Espada, Miguel Mena, Adrián Pérez-Redondo, and Carlos Yélamos pp 6901 - 6911; DOI: 10.1021/ic0603407 |
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Coordination Chemistry of the Solvated AgI and AuI Ions in Liquid and Aqueous Ammonia, Trialkyl and Triphenyl Phosphite, and Tri-n-butylphosphine Solutions Kersti B. Nilsson, Ingmar Persson, and Vadim G. Kessler pp 6912 - 6921; DOI: 10.1021/ic060175v |
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Structure and Magnetic Properties of a Non-Heme Diiron Complex Singly Bridged by a Hydroxo Group Josseline Jullien, Gergely Juhász, Pierre Mialane, Eddy Dumas, Cédric R. Mayer, Jérôme Marrot, Eric Rivière, Emile L. Bominaar, Eckard Münck, and Francis Sécheresse pp 6922 - 6927; DOI: 10.1021/ic0604009 |
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Tessellation of Porphyrazines with Porphyrins by Design Kai Fan Cheng, Ngee Ai Thai, Klaus Grohmann, Lucile C. Teague, and Charles Michael Drain pp 6928 - 6932; DOI: 10.1021/ic060448m |
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NO Release from MbFe(II)NO and HbFe(II)NO after Oxidation by Peroxynitrite Susanna Herold and Francesca Boccini pp 6933 - 6943; DOI: 10.1021/ic060469g |
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Solvent-Controlled Synthesis and Electrochemical Lithium Storage of One-Dimensional TiO2 Nanostructures Qiang Wang, Zhenhai Wen, and Jinghong Li pp 6944 - 6949; DOI: 10.1021/ic060477x |
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Jrgensen Complex within a Molecular Container: Selective Encapsulation of trans-[Co(en)2Cl2]+ into Cucurbit[8]uril and Influence of Inclusion on Guest's Properties Tatiana V. Mitkina, Maxim N. Sokolov, Dmitry Y. Naumov, Natalia V. Kuratieva, Olga A. Gerasko, and Vladimir P. Fedin pp 6950 - 6955; DOI: 10.1021/ic060502z |
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Chemical Bonding in Phosphane and Amine Complexes of Main Group Elements and Transition Metals Fabienne Bessac and Gernot Frenking pp 6956 - 6964; DOI: 10.1021/ic060541a |
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M-P versus M=M Bonds as Protonation Sites in the Organophosphide-Bridged Complexes [M2Cp2(-PR2)(-PR'2)(CO)2], (M = Mo, W; R, R' = Ph, Et, Cy) M. Angeles Alvarez, M. Esther García, M. Eugenia Martínez, Alberto Ramos, Miguel A. Ruiz, David Sáez, and Jacqueline Vaissermann pp 6965 - 6978; DOI: 10.1021/ic060544n |
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Glucosamine Conjugates of Tricarbonylcyclopentadienyl Rhenium(I) and Technetium(I) Cores Cara L. Ferreira, Charles B. Ewart, Simon R. Bayly, Brian O. Patrick, Jennifer Steele, Michael J. Adam, and Chris Orvig pp 6979 - 6987; DOI: 10.1021/ic0605672 |
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A Rare -Hydroxo-Bridged Species. Synthesis, Structure, and Properties of -Hydroxo(tetraphenylporphyrinatomanganese(III))(phthalocyaninato(azido)chromium(III)), [(TPP)Mn-O(H)-CrPc(N3)] Maria Pia Donzello, Laura Bartolino, Claudio Ercolani, and Corrado Rizzoli pp 6988 - 6995; DOI: 10.1021/ic060574q |
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Which nido:nido-Macropolyhedral Boranes are Most Stable? Farooq Ahmad Kiani and Matthias Hofmann pp 6996 - 7003; DOI: 10.1021/ic060591f |
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Observation of Internal Electron Transfer in Bulky Allyl Ytterbium Complexes with Substituted Terpyridine Ligands Rosemary E. White, Christin N. Carlson, Jacqueline M. Veauthier, Cheslan K. Simpson, J. D. Thompson, Brian L. Scott, Timothy P. Hanusa, and Kevin D. John pp 7004 - 7009; DOI: 10.1021/ic060603x |
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Roof-Shaped Halide-Bridged Bimetallic Complexes via Ring Expansion Reaction Clarite Azerraf, Shmuel Cohen, and Dmitri Gelman pp 7010 - 7017; DOI: 10.1021/ic060700q |
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Rhenium-Mediated Coupling of Acetonitrile and Pyrazoles. New Molecular Clefts for Anion Binding Marta Arroyo, Daniel Miguel, Fernando Villafañe, Sonia Nieto, Julio Pérez, and Lucía Riera pp 7018 - 7026; DOI: 10.1021/ic0607078 |
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Open Metal-Organic Framework Containing Cuprate Chains Dat T. Tran, Xiaojuan Fan, Daniel P. Brennan, Peter Y. Zavalij,and, and Scott R. J. Oliver: pp 7027 - 7027; DOI: 10.1021/ic061264a |
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Synthesis of Im3[Re3(3-S)(-S)3Br9]Br (Im = 1-Ethyl-3-methyl-imidazolium) by Means of an Ionic Liquid. Hideshi Sakamoto, Yusuke Watanabe, and Taro Saito: pp 7028 - 7028; DOI: 10.1021/ic061346z |
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Tetrakis(dimethylphosphoniumdimethylido)-dichromium and -dimolybdenum. 1. Crystal and Molecular Structures. F. Albert Cotton, Brian E. Hanson, William H. Ilsley,, and Gary W. Rice: pp 7029 - 7030; DOI: 10.1021/ic068004d |
Issue 18
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An Appreciation of Henry Taube Richard Eisenberg pp 7031 - 7031; DOI: 10.1021/ic0613412 |
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Chiral Molecule-Based Ferrimagnets with Helical Structures He-Rui Wen, Cai-Feng Wang, Yi-Zhi Li, Jing-Lin Zuo, You Song, and Xiao-Zeng You pp 7032 - 7034; DOI: 10.1021/ic060462z |
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Heterotopic Helicand for Designing Heterometallic Helicates Paula Cucos, Mirela Pascu, Roberta Sessoli, Narcis Avarvari, Fabrice Pointillart, and Marius Andruh pp 7035 - 7037; DOI: 10.1021/ic060533u |
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Ferromagnetic Cobalt Metallocycles María Moragues-Canovás, Caytie E. Talbot-Eeckelaers, Laure Catala, Francesc Lloret, Wolfgang Wernsdorfer, Euan K. Brechin, and Talal Mallah pp 7038 - 7040; DOI: 10.1021/ic0605773 |
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Charge Gating and Electronic Delocalization over a Denderimeric Assembly of Trinuclear Ruthenium Clusters Benjamin J. Lear and Clifford P. Kubiak pp 7041 - 7043; DOI: 10.1021/ic060766l |
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Conjugation Length Dependent Ground and Excited State Electronic Behavior in Oligothienyl Ru Complexes Carolyn Moorlag, Biprajit Sarkar, Carlos N. Sanrame, Peter Bäuerle, Wolfgang Kaim, and Michael O. Wolf pp 7044 - 7046; DOI: 10.1021/ic060912n |
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16-Electron Elongated Dihydrogen Complex Stabilized by Agostic Interaction Saikat Dutta and Balaji R. Jagirdar pp 7047 - 7049; DOI: 10.1021/ic061143a |
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Coordination of Diatomic Ligands to Heme: Simply CO Nathan J. Silvernail, Bruce C. Noll, Charles E. Schulz, and W. Robert Scheidt pp 7050 - 7052; DOI: 10.1021/ic0613356 |
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High-Spin M2+ Carboxylate Triangles from the Microwave Constantinos J. Milios, Alessandro Prescimone, J. Sanchez-Benitez, Simon Parsons, Mark Murrie, and Euan K. Brechin pp 7053 - 7055; DOI: 10.1021/ic061035o |
Reactivity of the Metal BX3 Dative -Bond: 1,2-Addition Reactions of the FeBX3 Moiety of the Ferraboratrane Complex [4-B(mimBut)3]Fe(CO)2Joshua S. Figueroa, Jonathan G. Melnick, and Gerard Parkin pp 7056 - 7058; DOI: 10.1021/ic061353n |
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Henry Taube: Inorganic Chemist Extraordinaire Carol Creutz, Peter C. Ford, and Thomas J. Meyer pp 7059 - 7068; DOI: 10.1021/ic060669s |
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Chiral Magnetic Metal-Organic Frameworks of Dimetal Subunits: Magnetism Tuning by Mixed-Metal Compositions of the Solid Solutions Ming-Hua Zeng, Bo Wang, Xin-Yi Wang, Wei-Xiong Zhang, Xiao-Ming Chen, and Song Gao pp 7069 - 7076; DOI: 10.1021/ic060520g |
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Spin-Crossover in an Iron(III)-Bispidine-Alkylperoxide System Jochen Bautz, Peter Comba, and Lawrence Que Jr. pp 7077 - 7082; DOI: 10.1021/ic0602401 |
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Interaction of Vanadyl (VO2+) with Ligands Containing Serine, Tyrosine, and Threonine Martin Ebel and Dieter Rehder pp 7083 - 7090; DOI: 10.1021/ic0602953 |
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Indium Flux Synthesis of RE4Ni2InGe4 (RE = Dy, Ho, Er, and Tm): An Ordered Quaternary Variation on the Binary Phase Mg5Si6 James R. Salvador and Mercouri G. Kanatzidis pp 7091 - 7099; DOI: 10.1021/ic0605017 |
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[PPh4]3[W(CN)7(O2)]·4H2O as the Representative of the [M(L)7(LL)] Class for Nine-Coordinate Complexes Dariusz Matoga, Janusz Szklarzewicz, and Masahiro Mikuriya pp 7100 - 7104; DOI: 10.1021/ic060523t |
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Vanadium Complex of 2-(2'-Pyridyl)-4,5-dicyanoimidazole Showing Spermicidal and Cytotoxic Properties Gregory B. Less, Nathan W. Ockwig, Paul G. Rasmussen, Gary D. Smith, Laura M. Keller, and John C. Drach pp 7105 - 7110; DOI: 10.1021/ic060545f |
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Synthesis of [(HIPTNCH2CH2)3N]Cr Compounds (HIPT = 3,5-(2,4,6-i-Pr3C6H2)2C6H3) and an Evaluation of Chromium for the Reduction of Dinitrogen to Ammonia Nathan C. Smythe, Richard R. Schrock, Peter Müller, and Walter W. Weare pp 7111 - 7118; DOI: 10.1021/ic060549k |
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Cu(I) or Cu(I)-Cu(II) Mixed-Valence Complexes of 2,4,6-Tri(2-pyridyl)-1,3,5-triazine: Syntheses, Structures, and Theoretical Study of the Hydrolytic Reaction Mechanism Xiao-Ping Zhou, Dan Li, Shao-Liang Zheng, Xuanjun Zhang, and Tao Wu pp 7119 - 7125; DOI: 10.1021/ic060564p |
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Ba11Cd8Bi14: Bismuth Zigzag Chains in a Ternary Alkaline-Earth Transition-Metal Zintl Phase Sheng-qing Xia and Svilen Bobev pp 7126 - 7132; DOI: 10.1021/ic060583z |
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Insight into the Catalytic Mechanism of Vanadium Haloperoxidases. DFT Investigation of Vanadium Cofactor Reactivity. Giuseppe Zampella, Piercarlo Fantucci, Vincent L. Pecoraro, and Luca De Gioia pp 7133 - 7143; DOI: 10.1021/ic060555g |
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Targeted Guanine Oxidation by a Dinuclear Copper(II) Complex at Single Stranded/Double Stranded DNA Junctions Lei Li, Narasimha N. Murthy, Joshua Telser, Lev. N. Zakharov, Glenn P. A. Yap, Arnold L. Rheingold, Kenneth D. Karlin, and Steven E. Rokita pp 7144 - 7159; DOI: 10.1021/ic0605930 |
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Reactivity Study of a Hydroperoxodicopper(II) Complex: Hydroxylation, Dehydrogenation, and Ligand Cross-Link Reactions Lei Li, Amy A. Narducci Sarjeant, and Kenneth D. Karlin pp 7160 - 7172; DOI: 10.1021/ic060598x |
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Syntheses, Structures, and Properties of High-Nuclear 3d-4f Clusters with Amino Acid as Ligand: {Gd6Cu24}, {Tb6Cu26}, and {(Ln6Cu24)2Cu} (Ln= Sm, Gd) Jian-Jun Zhang, Sheng-Min Hu, Sheng-Chang Xiang, Tianlu Sheng, Xin-Tao Wu, and Ya-Min Li pp 7173 - 7181; DOI: 10.1021/ic060610l |
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Chemistry of HIV-1 Virucidal Pt Complexes Having Neglected Bidentate sp2 N-Donor Carrier Ligands with Linked Triazine and Pyridine Rings. Synthesis, NMR Spectral Features, Structure, and Reaction with Guanosine Vidhi Maheshwari, Debadeep Bhattacharyya, Frank R. Fronczek, Patricia A. Marzilli, and Luigi G. Marzilli pp 7182 - 7190; DOI: 10.1021/ic060605h |
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A Three-Dimensional Ferromagnet, [Ni(dipn)]3[Cr(CN)6]2·3H2O (dipn = dipropylene triamine), Based on a Cubic Cr8Ni12 Unit Wakako Kaneko, Masaaki Ohba, Hisashi  kawa, and Susumu Kitagawapp 7191 - 7196; DOI: 10.1021/ic0606882 |
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A Model Iridium Hydroformylation System with the Large Bite Angle Ligand Xantphos: Reactivity with Parahydrogen and Implications for Hydroformylation Catalysis Daniel J. Fox, Simon B. Duckett, Christine Flaschenriem, William W. Brennessel, Jacob Schneider, Ahmet Gunay, and Richard Eisenberg pp 7197 - 7209; DOI: 10.1021/ic060731l |
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Ce4(P1-xSix)3-z: A First Example for the Stabilization of the Anti-Th3P4 Type Structure by Substitution in the Non-Metal Substructure Pavel S. Chizhov, Nellie R. Khasanova, Michael Baitinger, Walter Schnelle, Yuri Prots, Ulrich Burkhardt, Evgeny V. Antipov, and Yuri Grin pp 7210 - 7216; DOI: 10.1021/ic060726h |
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A Novel Layered Titanoniobate LiTiNbO5: Topotactic Synthesis and Electrochemistry versus Lithium J.-F. Colin, V. Pralong, V. Caignaert, M. Hervieu, and B. Raveau pp 7217 - 7223; DOI: 10.1021/ic060801o |
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ZrIV-Monosubstituted Keggin-Type Dimeric Polyoxometalates: Synthesis, Characterization, Catalysis of H2O2-Based Oxidations, and Theoretical Study Oxana A. Kholdeeva, Gennadii M. Maksimov, Raisa I. Maksimovskaya, Marina P. Vanina, Tatiana A. Trubitsina, Dmitry Yu. Naumov, Boris A. Kolesov, Nadya S. Antonova, Jorge J. Carbó, and Josep M. Poblet pp 7224 - 7234; DOI: 10.1021/ic0608142 |
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Concerning the Different Roles of Cations in Metallic Zintl Phases: Ba7Ga4Sb9 as a Test Case Pere Alemany, Miquel Llunell, and Enric Canadell pp 7235 - 7241; DOI: 10.1021/ic0608187 |
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Complexes of an Anionic Gallium(I) N-Heterocyclic Carbene Analogue with Group 14 Element(II) Fragments: Synthetic, Structural and Theoretical Studies Shaun P. Green, Cameron Jones, Kai-Alexander Lippert, David P. Mills, and Andreas Stasch pp 7242 - 7251; DOI: 10.1021/ic060851t |
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Bis(diisopropylphosphino)pyridine Iron Dicarbonyl, Dihydride, and Silyl Hydride Complexes Ryan J. Trovitch, Emil Lobkovsky, and Paul J. Chirik pp 7252 - 7260; DOI: 10.1021/ic0608647 |
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Mercury(II) 2-Aminoethanethiolate Clusters: Intramolecular Transformations and Mechanisms Mohan S. Bharara, Sean Parkin, and David A. Atwood pp 7261 - 7268; DOI: 10.1021/ic060863e |
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Experimental Determination of the nN *P-O Interaction Energy of O-Equatorial C-Apical Phosphoranes Bearing a Primary Amino Group Takahiro Adachi, Shiro Matsukawa, Masaaki Nakamoto, Kazumasa Kajiyama, Satoshi Kojima, Yohsuke Yamamoto, Kin-ya Akiba, Suyong Re, and Shigeru Nagase pp 7269 - 7277; DOI: 10.1021/ic0609047 |
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1D and 2D Homochiral Metal-Organic Frameworks Built from a New Chiral Elongated Binaphthalene-Derived Bipyridine Chuan-De Wu, Lin Zhang, and Wenbin Lin pp 7278 - 7285; DOI: 10.1021/ic060891x |
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Vacancy Ordering in SmGe2-x and GdGe2-x (x = 0.33): Structure and Properties of Two Sm3Ge5 Polymorphs and of Gd3Ge5 Paul H. Tobash, Daniel Lins, Svilen Bobev, Namjung Hur, Joe D. Thompson, and John L. Sarrao pp 7286 - 7294; DOI: 10.1021/ic060913f |
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Structure and Dynamics of Tetrakis(thiophosphinato)resorcinarene Complexes of Silver(I), Gold(I), and Palladium(II) Dana J. Eisler and Richard J. Puddephatt pp 7295 - 7305; DOI: 10.1021/ic060865z |
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Model Complexes of Cobalt-Substituted Matrix Metalloproteinases: Tools for Inhibitor Design Faith E. Jacobsen, Robert M. Breece, William K. Myers, David L. Tierney, and Seth M. Cohen pp 7306 - 7315; DOI: 10.1021/ic060901u |
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Generation and Optical Properties of Monodisperse Wurtzite-Type ZnS Microspheres Qingzhi Wu, Huaqiang Cao, Sichun Zhang, Xinrong Zhang, and Daniel Rabinovich pp 7316 - 7322; DOI: 10.1021/ic060936u |
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Synthesis and Characterization of New Trimeric Rhenium(I) Complexes. The Influence of Steric Factors on the Size of Pyrazolonaterhenium(I) Metallomacrocycles Paula Barbazán, Rosa Carballo, José S. Casas, Emilia García-Martínez, Gumersindo Pereiras-Gabián, Agustín Sánchez, and Ezequiel M. Vázquez-López pp 7323 - 7330; DOI: 10.1021/ic061080w |
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Technetium Tetrachloride as A Precursor for Small Technetium(IV) Complexes Adelheid Hagenbach, Eda Yegen, and Ulrich Abram pp 7331 - 7338; DOI: 10.1021/ic060896u |
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Dual Fluorescence from an Isonido ReIII Rhenacarborane Phosphine Complex, [7,10--H-7-CO-7,7-(PPh3)2-isonido-7,8,9-ReC2B7H9] Steven W. Buckner, Matthew J. Fischer, Paul A. Jelliss, Rensheng Luo, Shelley D. Minteer, Nigam P. Rath, and Aleksander Siemiarczuk pp 7339 - 7347; DOI: 10.1021/ic061071n |
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Synthesis, Characterization, and Structural Determination of Polynuclear Lithium Aggregates and Factors Affecting Their Aggregation Bor-Hunn Huang, Bao-Tsan Ko, Taimur Athar, and Chu-Chieh Lin pp 7348 - 7356; DOI: 10.1021/ic060467w |
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Unusual Oxidation of Phosphines Employing Water as the Oxygen Atom Source and Tris(benzene-1,2-dithiolate)molybdenum(VI) as the Oxidant. A Functional Molybdenum Hydroxylase Analogue System Antonio Cervilla, Francisco Pérez-Pla, Elisa Llopis, and María Piles pp 7357 - 7366; DOI: 10.1021/ic052161f |
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Solubility of Al2O3 in Some Chloride-Fluoride Melts Victor L. Cherginets, Vyacheslav N. Baumer, Sergey S. Galkin, Lidiya V. Glushkova, Tatyana P. Rebrova, and Zoya V. Shtitelman pp 7367 - 7371; DOI: 10.1021/ic060181r |
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Reactivity and Structural and Physical Studies of Tetranuclear Iron(III) Clusters Containing the [Fe4(3-O)2]8+ "Butterfly" Core: an FeIII4 Cluster with an S = 1 Ground State Theocharis C. Stamatatos, Athanassios K. Boudalis, Yiannis Sanakis, and Catherine P. Raptopoulou pp 7372 - 7381; DOI: 10.1021/ic0604821 |
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A Theoretical Characterization of Covalency in Rare Earth Complexes through Their Absorption Electronic Properties: f-f Transitions Laurence Petit, Alain Borel, Claude Daul, Pascale Maldivi, and Carlo Adamo pp 7382 - 7388; DOI: 10.1021/ic060149x |
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-Elimination in the Reactions of ·CR1R2CR3R4X Radicals with Metal Powders Immersed in Aqueous Solutions Irena Rusonik, Haim Cohen, and Dan Meyerstein pp 7389 - 7396; DOI: 10.1021/ic0605219 |
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Electronic Excited States of Tetracyanonickelate(II) Patrick Hummel, Nicholas W. Halpern-Manners, and Harry B. Gray pp 7397 - 7400; DOI: 10.1021/ic060584r |
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U(IV) Chalcogenolates Synthesized via Oxidation of Uranium Metal by Dichalcogenides Andrew J. Gaunt, Brian L. Scott, and Mary P. Neu pp 7401 - 7407; DOI: 10.1021/ic060560k |
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Localized and Delocalized Chemical Bonding in the Compounds CaNiGe2, SrNiGe2, and SrNiSn2 Viktor Hlukhyy, Steffen Eck, and Thomas F. Fässler pp 7408 - 7416; DOI: 10.1021/ic060613y |
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Vibrational Spectroscopy and Analysis of Pseudo-tetrahedral Complexes with Metal Imido Bonds Mark P. Mehn, Steven D. Brown, David M. Jenkins, Jonas C. Peters, and Lawrence Que, Jr. pp 7417 - 7427; DOI: 10.1021/ic060670r |
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Coordination Chemistry of the Solvated Silver(I) Ion in the Oxygen Donor Solvents Water, Dimethyl Sulfoxide, and N,N'-Dimethylpropyleneurea Ingmar Persson and Kersti B. Nilsson pp 7428 - 7434; DOI: 10.1021/ic060636c |
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Diligating Tripodal Amido-Phosphine Ligands: the Effect of a Proximal Antipodal Early Transition Metal on Phosphine Donor Ability in a Building Block for Heterometallic Complexes Hua Han, Mona Elsmaili, and Samuel A. Johnson pp 7435 - 7445; DOI: 10.1021/ic060692d |
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Investigations on the Synthesis, Structures, and Properties of New Copper(I) 2,3-Dimethylpyrazine Coordination Compounds Inke Jess and Christian Näther pp 7446 - 7454; DOI: 10.1021/ic060747b |
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A Novel Approach toward Asymmetric Synthesis of Alcohol Functionalized C-Chiral Diphosphines via Two-Stage Hydrophosphination of Terminal Alkynols Sumod A. Pullarkat, Ding Yi, Yongxin Li, Geok-Kheng Tan, and Pak-Hing Leung pp 7455 - 7463; DOI: 10.1021/ic060937m |
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An ab Initio Molecular Dynamics and Density Functional Theory Study of the Formation of Phosphate Chains from Metathiophosphates Nicholas J. Mosey and Tom K. Woo pp 7464 - 7479; DOI: 10.1021/ic0608391 |
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Biomimetic Oxidation of 3,5-Di-tert-butylcatechol by Dioxygen via Mn-Enhanced Base Catalysis Imola Cs. Szigyártó, László I. Simándi, László Párkányi, László Korecz, and Gitta Schlosser pp 7480 - 7487; DOI: 10.1021/ic060618v |
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Structure of the Active Site of Sulfite Dehydrogenase from Starkeya novella Christian J. Doonan, Ulrike Kappler, and Graham N. George pp 7488 - 7492; DOI: 10.1021/ic0607944 |
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Zn-OH2 and Zn-OH Complexes with Hydroborate-Derived Tripod Ligands: A Comprehensive Study Mohamed M. Ibrahim, Cristina Pérez Olmo, Teame Tekeste, Jan Seebacher, Guosen He, José A. Maldonado Calvo, Karin Böhmerle, Gunther Steinfeld, Horst Brombacher, and Heinrich Vahrenkamp pp 7493 - 7502; DOI: 10.1021/ic060752f |
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Reactions of Potassium Bis(phosphinimino)methanide with Group 11 Compounds Tarun K. Panda, Peter W. Roesky, Patrick Larsen, Shuang Zhang, and Claudia Wickleder pp 7503 - 7508; DOI: 10.1021/ic060932p |
Issue 19
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Preface: Nanowires Peidong Yang and Kenneth Poeppelmeier pp 7509 - 7510; DOI: 10.1021/ic0611903 |
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Solution-Liquid-Solid Growth of Semiconductor Nanowires Fudong Wang, Angang Dong, Jianwei Sun, Rui Tang, Heng Yu, and William E. Buhro pp 7511 - 7521; DOI: 10.1021/ic060498r |
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Solution-Based Synthetic Strategies for 1-D Nanostructures Xun Wang and Yadong Li pp 7522 - 7534; DOI: 10.1021/ic051885o |
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Solution-Grown Zinc Oxide Nanowires Lori E. Greene, Benjamin D. Yuhas, Matt Law, David Zitoun, and Peidong Yang pp 7535 - 7543; DOI: 10.1021/ic0601900 |
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One-Dimensional Colloidal Gold and Silver Nanostructures Catherine J. Murphy, Anand M. Gole, Simona E. Hunyadi, and Christopher J. Orendorff pp 7544 - 7554; DOI: 10.1021/ic0519382 |
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Template-Grown Metal Nanowires Timothy R. Kline, Mingliang Tian, Jinguo Wang, Ayusman Sen, Moses W. H. Chan, and Thomas E. Mallouk pp 7555 - 7565; DOI: 10.1021/ic0601384 |
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Stability and Porosity Enhancement through Concurrent Ligand Extension and Secondary Building Unit Stabilization Daofeng Sun, Yanxiong Ke, Tracy M. Mattox, Sean Parkin, and Hong-Cai Zhou pp 7566 - 7568; DOI: 10.1021/ic0609002 |
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Ancillary Ligand Functionalization of Cyanide-Bridged S = 6 FeIII4NiII4 Complexes for Molecule-Based Electronics Dongfeng Li, Sean Parkin, Rodolphe Clérac, and Stephen M. Holmes pp 7569 - 7571; DOI: 10.1021/ic060695q |
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Mechanistic Studies of Hangman Salophen-Mediated Activation of O-O Bonds Shih-Yuan Liu, Jake D. Soper, Jenny Y. Yang, Elena V. Rybak-Akimova, and Daniel G. Nocera pp 7572 - 7574; DOI: 10.1021/ic0602087 |
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Antiferromagnetic Interaction Achieved by a 3-D Supramolecular CuII Complex with Pyrazino-Fused TTF as the Ligand, [CuCl2(BP-TTF)] Shun Ichikawa, Shinya Kimura, Hatsumi Mori, Gosuke Yoshida, and Hiroyuki Tajima pp 7575 - 7577; DOI: 10.1021/ic060746j |
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Chirality and Magnetism in a Novel Series of Isotypic Borophosphates: MII[BPO4(OH)2] (MII = Mn, Fe, Co) Ya-Xi Huang, Bastian Ewald, Walter Schnelle, Yurii Prots, and Rüdiger Kniep pp 7578 - 7580; DOI: 10.1021/ic0607991 |
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Active-Site Models of Bacterial Nitric Oxide Reductase Featuring Tris-Histidyl and Glutamic Acid Mimics: Influence of a Carboxylate Ligand on FeB Binding and the Heme Fe/FeB Redox Potential James P. Collman, Yi-Long Yan, Jianping Lei, and Peter H. Dinolfo pp 7581 - 7583; DOI: 10.1021/ic0609150 |
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1D Helical Polymeric Chain with a Pseudo-53 Screw Axis Formed by Cuprophilicity. Synthesis and Crystal Structure of Copper(I) Pivalate Tetsuya Sugiura, Hirofumi Yoshikawa, and Kunio Awaga pp 7584 - 7586; DOI: 10.1021/ic060989b |
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Thermotropic Mesomorphism of Soft Materials Bearing Carboxylate-Supported 4-Oxo Tetracupric Clusters Rajendra Shakya, Paul H. Keyes, Mary Jane Heeg, Azzam Moussawel, Paul A. Heiney, and Claudio N. Verani pp 7587 - 7589; DOI: 10.1021/ic061136m |
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Coordination of Fluoro Ligands toward Sodium Ions Makes the Difference: Aqua Sodium Ions Act as Brnsted Acids in Polymerization of Vinyl Ethers and Styrenes Chi-Tsing Chang, Chuan-Lin Chen, Yi-Hong Liu, Shie-Ming Peng, Pi-Tai Chou, and Shiuh-Tzung Liu pp 7590 - 7592; DOI: 10.1021/ic061162k |
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New Members in the Nin+1(QO3)nX2 Family: Unusual 3D Network Based on Ni4ClO3 Cubane-like Clusters in Ni7(TeO3)6Cl2 Hai-Long Jiang and Jiang-Gao Mao pp 7593 - 7599; DOI: 10.1021/ic060356x |
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Electronic Structures and Absorption Spectra of Linkage Isomers of Trithiocyanato (4,4',4' '-Tricarboxy-2,2':6,2' '-terpyridine) Ruthenium(II) Complexes: A DFT Study Sutapa Ghosh, G. Krishna Chaitanya, K. Bhanuprakash, Md. K. Nazeeruddin, M. Grätzel, and P. Yella Reddy pp 7600 - 7611; DOI: 10.1021/ic051851g |
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Tuning the Structural and Magnetic Properties of Thermally Robust Coordination Polymers Norberto Masciocchi, Simona Galli, Angelo Sironi, Elena Cariati, Miguel A. Galindo, Elisa Barea, M Angustias Romero, Juan M. Salas, Jorge A. R. Navarro, and Francisco Santoyo-González pp 7612 - 7620; DOI: 10.1021/ic0602188 |
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Structural and Magnetic Properties of a Complete Halide Series of NiII Complexes with a Pyridine-Containing 14-Membered Macrocycle Abel Tamayo, Lluis Escriche, Carlos Lodeiro, Jordi Ribas-Ariño, Joan Ribas, Berta Covelo, and Jaume Casabó pp 7621 - 7627; DOI: 10.1021/ic060231s |
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Evolution of the Structural Chemistry of Vanadium Organodiphosphonate Networks and Frameworks: Structural Consequences of Fluoride Incorporation in the Development of Stable Phases with Void Channels Wayne Ouellette, Ming Hui Yu, Charles J. O'Connor, and Jon Zubieta pp 7628 - 7641; DOI: 10.1021/ic0604462 |
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Assembling of Dimeric Entities of Cd(II) with 6-Mercaptopurine to Afford One-Dimensional Coordination Polymers: Synthesis and Scanning Probe Microscopy Characterization Pilar Amo-Ochoa, M Isabel Rodríguez-Tapiador, Oscar Castillo, David Olea, Alejandro Guijarro, Simone S. Alexandre, Julio Gómez-Herrero, and Félix Zamora pp 7642 - 7650; DOI: 10.1021/ic060384f |
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Helices versus Zigzag Chains: One-Dimensional Coordination Polymers of AgI and Bis(4-pyridyl)amine David B. Cordes, Lyall R. Hanton, and Mark D. Spicer pp 7651 - 7664; DOI: 10.1021/ic060487y |
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An Unprecedented Asymmetric End-On Azido-Bridged Copper(II) Imino Nitroxide Complex: Structure, Magnetic Properties, and Density Functional Theory Analysis Licun Li, Daizheng Liao, Zonghui Jiang, Jean-Marie Mouesca, and Paul Rey pp 7665 - 7670; DOI: 10.1021/ic0606429 |
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Toward Rational Construction of Gold, Gold-Silver, and Gold-Mercury String Complexes: Syntheses, Structures, and Properties of [Au(Tab)2]2L2 (L = I and PF6), {[(Tab)2M][Au(CN)2]}2 (M = Au and Ag), and {[Hg(Tab)2][Au(CN)2]2} [Tab = 4-(Trimethylammonio)benzenethiolate] Jin-Xiang Chen, Wen-Hua Zhang, Xiao-Yan Tang, Zhi-Gang Ren, Hong-Xi Li, Yong Zhang, and Jian-Ping Lang pp 7671 - 7680; DOI: 10.1021/ic060655m |
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Structural Diversity in 4,4'-Trimethylenedipyridine-zinc phosphite Hybrids: Incorporation of Neutral Guest Molecules in Hybrid Materials Liangming Hu, Jian Fan, Carla Slebodnick, and Brian E. Hanson pp 7681 - 7688; DOI: 10.1021/ic0605266 |
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Dimethylammonium Trichlorocuprate(II): Structural Transition, Low-Temperature Crystal Structure, and Unusual Two-Magnetic Chain Structure Dictated by Nonbonding Chloride-Chloride Contacts Roger D. Willett, Brendan Twamley, Wouter Montfrooij, Garrett E. Granroth, Stephen E. Nagler, Donavan W. Hall, Ju-Hyun Park, Brian C. Watson, Mark W. Meisel, and Daniel R. Talham pp 7689 - 7697; DOI: 10.1021/ic060654u |
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Ferromagnetic Exchange Interactions for Cu612+ and Mn612+ Hexagons Sandwiched by Two B--[XW9O33]9- (X = AsIII and SbIII) Ligands in D3d-Symmetric Polyoxotungstates Toshihiro Yamase, Keisuke Fukaya, Hiroyuki Nojiri, and Yuhgo Ohshima pp 7698 - 7704; DOI: 10.1021/ic060666f |
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Hydrothermal Synthesis and Structural Characterizations of Two New Germanates with a Novel Topological Framework and Unusual Ge4(OH)4 Cubane Yan Xu, Liying Cheng, and Wansheng You pp 7705 - 7708; DOI: 10.1021/ic0606779 |
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Trigonal-Bipyramidal Geometry Induced by an External Water Ligand in a Sterically Hindered Iron Salen Complex, Related to the Active Site of Protocatechuate 3,4-Dioxygenase Takuya Kurahashi, Kenji Oda, Manabu Sugimoto, Takashi Ogura, and Hiroshi Fujii pp 7709 - 7721; DOI: 10.1021/ic060650p |
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Tuning of Inter- versus Intrachain Magnetic Interactions in Cyano-Bridged NiII/MIII (M = Cr, Fe, Co) Chain Complexes Mihail Atanasov, Peter Comba, Sebastian Förster, Gerald Linti, Thomas Malcherek, Ronald Miletich, Alexander I. Prikhod'ko, and Hubert Wadepohl pp 7722 - 7735; DOI: 10.1021/ic060453q |
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EPR Investigation and Spectral Simulations of Iron-Catecholate Complexes and Iron-Peptide Models of Marine Adhesive Cross-Links Jaime T. Weisser, Mark J. Nilges, Mary J. Sever, and Jonathan J. Wilker pp 7736 - 7747; DOI: 10.1021/ic060685p |
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Hybrid Inorganic-Metalorganic Compounds Containing Copper(II)-Monosubstituted Keggin Polyanions and Polymeric Copper(I) Complexes. Leire San Felices, Pablo Vitoria, Juan M. Gutiérrez-Zorrilla, Luis Lezama, and Santiago Reinoso pp 7748 - 7757; DOI: 10.1021/ic060762g |
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Crystal Retro-Engineering: Structural Impact on Silver(I) Complexes with Changing Complexity of Tris(pyrazolyl)methane Ligands Daniel L. Reger, Radu F. Semeniuc, Christine A. Little, and Mark D. Smith pp 7758 - 7769; DOI: 10.1021/ic0606936 |
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Gold(I) and Silver(I) Mixed-Metal Trinuclear Complexes: Dimeric Products from the Reaction of Gold(I) Carbeniates or Benzylimidazolates with Silver(I) 3,5-Diphenylpyrazolate Ahmed A. Mohamed, Rossana Galassi, Fabrizio Papa, Alfredo Burini, and John P. Fackler, Jr. pp 7770 - 7776; DOI: 10.1021/ic060792j |
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2-Aminopyrrolines: New Chiral Amidinate Ligands with a Rigid Well-Defined Molecular Structure and Their Coordination to TiIV Benjamin D. Ward, Hélène Risler, Katharina Weitershaus, Stéphane Bellemin-Laponnaz, Hubert Wadepohl, and Lutz H. Gade pp 7777 - 7787; DOI: 10.1021/ic060809y |
Influence of Solvent and Weak C-H···O Contacts in the Self-Assembled [Pt2M4{C C(3-OMe)C6H4}8] (M = Cu, Ag) Clusters and Their Role in the Luminescence BehaviorBelén Gil, Juan Forniés, Julio Gómez, Elena Lalinde, Antonio Martín, and, and M. Teresa Moreno pp 7788 - 7798; DOI: 10.1021/ic0608344 |
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Substituent Effects in Five Oxo-Centered Trinuclear Rhodium(III) Clusters Jacqueline R. Houston, Marilyn M. Olmstead, and William H. Casey pp 7799 - 7805; DOI: 10.1021/ic060837g |
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Lanthanide Triple-Stranded Helicates: Controlling the Yield of the Heterobimetallic Species Thomas B. Jensen, Rosario Scopelliti, and Jean-Claude G. Bünzli pp 7806 - 7814; DOI: 10.1021/ic0608501 |
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Polyester-Based Carborane-Containing Dendrons Kristin M. Galie, Alexis Mollard, and Ilya Zharov pp 7815 - 7820; DOI: 10.1021/ic060866r |
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Synthesis, Crystal Structures, and Magnetic Properties of Cyano-Bridged Honeycomblike Layers MV-CuII (M = Mo, W) Chelated by a Macrocyclic Ligand Jeong Hak Lim, Jun Sung Kang, Hyoung Chan Kim, Eui Kwan Koh, and Chang Seop Hong pp 7821 - 7827; DOI: 10.1021/ic060868b |
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Iron Complexes of N-Confused Pyriporphyrin: NMR Studies Radomir My  liborski, Krystyna Rachlewicz, and Lechosaw Latos-Grayskipp 7828 - 7834; DOI: 10.1021/ic060906r |
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Synthesis and Characterization of Novel Fluorophosphazene-Derived Cobaltacyclopentadienyl Metallacycles: Reagents for Assembly of Aryl-Bridged Fluorophosphazenes Muthiah Senthil Kumar, Shailesh Upreti, and Anil J. Elias pp 7835 - 7842; DOI: 10.1021/ic0609204 |
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195Pt NMR Study of the Speciation and Preferential Extraction of Pt(IV)-Mixed Halide Complexes by Diethylenetriamine-Modified Silica-Based Anion Exchangers Jurjen Kramer and Klaus R. Koch pp 7843 - 7855; DOI: 10.1021/ic0609655 |
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Gas-Phase Reactions of Atomic Lanthanide Cations with Sulfur Hexafluoride: Periodicity in Reactivity Ping Cheng and Diethard K. Bohme pp 7856 - 7863; DOI: 10.1021/ic061000o |
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Prediction of Second-Order Optical Nonlinearity of Trisorganotin-Substituted -Keggin Polyoxotungstate Wei Guan, Guochun Yang, Likai Yan, and Zhongmin Su pp 7864 - 7868; DOI: 10.1021/ic061077c |
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Nitrite Impurities Are Responsible for the Reaction Observed between Vitamin B12 and Nitric Oxide in Acidic Aqueous Solution Federico Roncaroli, Tatyana E. Shubina, Timothy Clark, and Rudi van Eldik pp 7869 - 7876; DOI: 10.1021/ic061151r |
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Electronic Structure of Mononuclear Bis(1,2-diaryl-1,2-ethylenedithiolato)iron Complexes Containing a Fifth Cyanide or Phosphite Ligand: A Combined Experimental and Computational Study Apurba K. Patra, Eckhard Bill, Eberhard Bothe, Krzysztof Chlopek, Frank Neese, Thomas Weyhermüller, Keira Stobie, Michael D. Ward, Jon A. McCleverty, and Karl Wieghardt pp 7877 - 7890; DOI: 10.1021/ic061171t |
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Potentiometric Titration of Metal Ions in Ethanol Graham T. T. Gibson, Mark F. Mohamed, Alexei A. Neverov, and R. S. Brown pp 7891 - 7902; DOI: 10.1021/ic060517x |
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Coordination Chemistry of Amine Bis(phenolate) Cobalt(II), Nickel(II), and Copper(II) Complexes Laura Rodríguez, Elena Labisbal, Antonio Sousa-Pedrares, José Arturo García-Vázquez, Jaime Romero, María Luz Durán, José A. Real, and Antonio Sousa pp 7903 - 7914; DOI: 10.1021/ic0602594 |
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The Solution Structures and Dynamics and the Solid-State Structures of Substituted Cyclopentadienyltitanium(IV) Trifluorides Franc Perdih, Andrej Pevec, Sa a Petriek, Andrej Petri, Nina Lah, Ksenija Kogej, and Alojz Demarpp 7915 - 7921; DOI: 10.1021/ic060714w |
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Phosphine-Mediated Dehalogenation Reactions of Trichloro(N-silyl)phosphoranimines Keith Huynh, Eric Rivard, Wesley LeBlanc, Vivienne Blackstone, Alan J. Lough, and Ian Manners pp 7922 - 7928; DOI: 10.1021/ic0607888 |
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Osmium(VII) Fluorine Compounds Hashem Shorafa and Konrad Seppelt pp 7929 - 7934; DOI: 10.1021/ic0608290 |
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Influence of the Reaction Conditions on the Self-assembly of Lead(II) 5-Sulfosalicylate Coordination Polymers with Chelating Amine Ligands Sai-Rong Fan and Long-Guan Zhu pp 7935 - 7942; DOI: 10.1021/ic060871v |
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KCaEr2CuS5: A New Pentanary Rare-Earth Layered Chalcogenide without Substitutional Disorder Hui-Yi Zeng, Hansjürgen Mattausch, Arndt Simon, Fa-Kun Zheng, Zhen-Chao Dong, Guo-Cong Guo, and Jin-Shun Huang pp 7943 - 7946; DOI: 10.1021/ic060907j |
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Prediction of pKa Values of nido-Carboranes by Density Functional Theory Methods Pau Farràs, Francesc Teixidor, and Vicenç Branchadell pp 7947 - 7954; DOI: 10.1021/ic060908b |
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2,2'-Dipyridylketone (dpk) as Ancillary Acceptor and Reporter Ligand in Complexes [(dpk)(Cl)Ru(-tppz)Ru(Cl)(dpk)]n+ where tppz = 2,3,5,6-Tetrakis(2-pyridyl)pyrazine Sandeep Ghumaan, Biprajit Sarkar, Nripen Chanda, Monika Sieger, Jan Fiedler, Wolfgang Kaim, and Goutam Kumar Lahiri pp 7955 - 7961; DOI: 10.1021/ic060887l |
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Distinct Water-Exchange Mechanisms for Trinuclear Transition-Metal Clusters Jacqueline R. Houston, David T. Richens, and William H. Casey pp 7962 - 7967; DOI: 10.1021/ic0609608 |
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Condensation of [Si3O9]6- Anions in the Solid State to the Dimeric Cyclotrisilicate Anion [Si6O17]10- Stefan Hoffmann and Thomas F. Fässler pp 7968 - 7972; DOI: 10.1021/ic0610886 |
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Cu2{[18]ane-N6} Complexes: Structures, Magnetism, and Phosphate Monoester Binding Julia E. Barker, Yu Liu, Gordon T. Yee, Wei-Zhong Chen, Guangbin Wang, Vilma M. Rivera, and Tong Ren pp 7973 - 7980; DOI: 10.1021/ic0611140 |
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Are the NF4+ Cations in NF4BF4 Really Nontetrahedral? Ralf Haiges, Michael Gerken, Adriana Iuga, Robert Bau, and Karl O. Christe pp 7981 - 7984; DOI: 10.1021/ic061206p |
Issue 20
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Extended Calix[4]arene Analogues by Two P-CuI-P Bridges and Anion Encapsulation Xiang-Tai Meng, Qing-Shan Li, Feng-Bo Xu, Hai-Bin Song, Christopher E. Anson, and Zheng-Zhi Zhang pp 7986 - 7987; DOI: 10.1021/ic060892p |
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New Porphyrin-Based Metal-Organic Framework with High Porosity: 2-D Infinite 22.2-Å Square-Grid Coordination Network Tetsushi Ohmura, Arimitsu Usuki, Kenzo Fukumori, Takashi Ohta, Mikinao Ito, and Kazuyuki Tatsumi pp 7988 - 7990; DOI: 10.1021/ic060358h |
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Steric Control of a Bridging Ligand for High-Nuclearity Metallamacrocycle Formation: A Highly Puckered 60-Membered Icosanuclear Metalladiazamacrocycle Dohyun Moon, Kyungjae Lee, Rohith P. John, Ghyung Hwa Kim, Byoung Jin Suh, and Myoung Soo Lah pp 7991 - 7993; DOI: 10.1021/ic060646d |
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Cu(NO3)2·3H2O-Mediated Synthesis of 4'-(2-Pyridyl)-2,2':6',2' '-terpyridine (L2) from N-(2-Pyridylmethyl)pyridine-2-methylketimine (L1). A C-C Bond-Forming Reaction and the Structure of {[Cu(L2)(OH)(NO3)][Cu(L2)(NO3)2]}·2H2O Sumanta Kumar Padhi and Vadivelu Manivannan pp 7994 - 7996; DOI: 10.1021/ic060968h |
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Synthesis of the First rNHC (Remote N-Heterocyclic Carbene) Complexes with No Heteroatom in the Carbene Carbon-Containing Ring Oliver Schuster and Helgard G. Raubenheimer pp 7997 - 7999; DOI: 10.1021/ic060963k |
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Active-Site Models for Iron Hydrogenases: Reduction Chemistry of Dinuclear Iron Complexes Inigo Aguirre de Carcer, Antonio DiPasquale, Arnold L. Rheingold, and D. Michael Heinekey pp 8000 - 8002; DOI: 10.1021/ic0610381 |
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Self-Assembly of the 2-His-1-carboxylate Facial Triad in Mononuclear Iron(II) and Zinc(II) Models of Metalloenzyme Active Sites Seth J. Friese, Benjamin E. Kucera, Lawrence Que, Jr., and William B. Tolman pp 8003 - 8005; DOI: 10.1021/ic061564s |
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Mononitrosyl Iron Complexes Supported by Sterically Hindered Carboxylate Ligands David P. Klein, Victor G. Young, Jr., William B. Tolman, and Lawrence Que, Jr. pp 8006 - 8008; DOI: 10.1021/ic0610740 |
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Electrochemical Generation of a Nonheme Oxoiron(IV) Complex Michael J. Collins, Kallol Ray, and Lawrence Que, Jr. pp 8009 - 8011; DOI: 10.1021/ic061263i |
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Spectroscopic Methods in Bioinorganic Chemistry: Blue to Green to Red Copper Sites Edward I. Solomon pp 8012 - 8025; DOI: 10.1021/ic060450d |
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Coordination Modes in the Formation of the Ternary Am(III), Cm(III), and Eu(III) Complexes with EDTA and NTA: TRLFS, 13C NMR, EXAFS, and Thermodynamics of the Complexation J. N. Mathur, P. Thakur, C. J. Dodge, A. J. Francis, and G. R. Choppin pp 8026 - 8035; DOI: 10.1021/ic052166c |
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Two-Dimensional Lanthanide Heteropolyvanadates of Manganese(IV) and Nickel(IV) Containing Two Types of Heteropoly Anions with 1:13 and 1:12 Stoichiometry Shuxia Liu, Dehui Li, Linhua Xie, Haiyan Cheng, Xinyu Zhao, and Zhongmin Su pp 8036 - 8040; DOI: 10.1021/ic060623z |
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Neutral RuII-Based Emitting Materials: A Prototypical Study on Factors Governing Radiationless Transition in Phosphorescent Metal Complexes Elise Y. Li, Yi-Ming Cheng, Cheng-Chih Hsu, Pi-Tai Chou, Gene-Hsiang Lee, I-Hui Lin, Yun Chi, and Chao-Shiuan Liu pp 8041 - 8051; DOI: 10.1021/ic060066g |
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Synthesis, Characterization, and Solution Properties of a Novel Cross-Bridged Cyclam Manganese(IV) Complex Having Two Terminal Hydroxo Ligands Guochuan Yin, James M. McCormick, Maria Buchalova, Andrew M. Danby, Kent Rodgers, Victor W. Day, Kevyn Smith, Chris M. Perkins, David Kitko, John D. Carter, William M. Scheper, and Daryle H. Busch pp 8052 - 8061; DOI: 10.1021/ic0521123 |
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Organic-Inorganic Hybrid Compounds of Li with Bisimidazole Derivatives: Li Ion Binding Study and Topochemical Properties In-Chul Hwang, R. Prakash Chandran, N. Jiten Singh, Manish Khandelwal, T. Daniel Thangadurai, Jung-Woo Lee, Jeong Ah Chang, and Kwang S. Kim pp 8062 - 8069; DOI: 10.1021/ic060323h |
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CH··· Interaction for Rhenium-Based Rectangles: An Interaction That Is Rarely Designed into a Host-Guest Pair Bala. Manimaran, Liang-Jian Lai, P. Thanasekaran, Jing-Yun Wu, Rong-Tang Liao, Tien-Wen Tseng, Yen-Hsiang Liu, Gene-Hsiang Lee, Shie-Ming Peng, and Kuang-Lieh Lu pp 8070 - 8077; DOI: 10.1021/ic0604720 |
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Novel Ti-O-Ti Bonding Species Constructed in a Metal-Oxide Cluster: Reaction Products of Bis(oxalato)oxotitanate(IV) with the Dimeric, 1,2-Dititanium(IV)-Substituted Keggin Polyoxotungstate Kunihiko Hayashi, Hideyuki Murakami, and Kenji Nomiya pp 8078 - 8085; DOI: 10.1021/ic060661i |
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Spectroscopic and Potentiometric Characterization of Oxovanadium(IV) Complexes Formed by 3-Hydroxy-4-Pyridinones. Rationalization of the Influence of Basicity and Electronic Structure of the Ligand on the Properties of VIVO Species in Aqueous Solution Maria Rangel, Andreia Leite, M. João Amorim, Eugenio Garribba, Giovanni Micera, and Elzbieta Lodyga-Chruscinska pp 8086 - 8097; DOI: 10.1021/ic0605571 |
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Cadmium(II) and Copper(II) Complexes with Imidazole-Containing Tripodal Polyamine Ligands: pH and Anion Effects on Carbon Dioxide Fixation and Assembling Ling-Yan Kong, Hui-Fang Zhu, Yong-Qing Huang, Taka-aki Okamura, Xi-Hong Lu, You Song, Guang-Xiang Liu, Wei-Yin Sun, and Norikazu Ueyama pp 8098 - 8107; DOI: 10.1021/ic0605524 |
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Syntheses and X-ray Crystal Structures of Zirconium(IV) and Hafnium(IV) Complexes Containing Monovacant Wells-Dawson and Keggin Polyoxotungstates Chika Nozaki Kato, Akira Shinohara, Kunihiko Hayashi, and Kenji Nomiya pp 8108 - 8119; DOI: 10.1021/ic060656e |
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Two Mixed-Valence Vanadium(III,IV) Phosphonoacetates with 16-Ring Channels: H2(DABCO)[VIVO(H2O)VIII(OH)(O3PCH2CO2)2]·2.5H2O and H2(PIP)[VIVO(H2O)VIII(OH)(O3PCH2CO2)2]·2.5H2O Xian-Ming Zhang, Juan-Juan Hou, Wei-Xiong Zhang, and Xiao-Ming Chen pp 8120 - 8125; DOI: 10.1021/ic060771p |
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Structural-Electronic Correlation in the First-Order Phase Transition of [FeH2L2-Me](ClO4)2 (H2L2-Me = Bis[((2-methylimidazol-4-yl)methylidene)-3- aminopropyl]ethylenediamine) Nicolas Bréfuel, Shinya Imatomi, Haruna Torigoe, Hiroaki Hagiwara, Sergiu Shova, Jean-François Meunier, Sébastien Bonhommeau, Jean-Pierre Tuchagues, and Naohide Matsumoto pp 8126 - 8135; DOI: 10.1021/ic060674w |
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Structural and Electrochemical Investigations of the High Fluoride Affinity of Sterically Hindered 1,8-Bis(boryl)naphthalenes Mohand Melaïmi, Stéphane Solé, Ching-Wen Chiu, Huadong Wang, and François P. Gabbaï pp 8136 - 8143; DOI: 10.1021/ic060709s |
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Combined Effects of Diamines and Carboxylate Bridges on Structural and Magnetic Properties of a Series of Polynuclear Copper(II) Complexes with 1,1-Cyclobutanedicarboxylic Acid Raúl Baldomá, Montserrat Monfort, Joan Ribas, Xavier Solans, and Miguel A. Maestro pp 8144 - 8155; DOI: 10.1021/ic060797g |
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Preparation and Characterization of a Family of Ru2 Compounds Bearing Iodo/Ethynyl Substituents on the Periphery Wei-Zhong Chen and Tong Ren pp 8156 - 8164; DOI: 10.1021/ic0608389 |
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Luminescent Phosphine Gold(I) Thiolates: Correlation between Crystal Structure and Photoluminescent Properties in [R3PAu{SC(OMe)=NC6H4NO2-4}] (R = Et, Cy, Ph) and [(Ph2P-R-PPh2){AuSC(OMe)=NC6H4NO2-4}2] (R = CH2, (CH2)2, (CH2)3, (CH2)4, Fc) Soo Yei Ho, Eddie Chung-Chin Cheng, Edward R. T. Tiekink, and Vivian Wing-Wah Yam pp 8165 - 8174; DOI: 10.1021/ic0608243 |
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Mg5.23Sm0.77Sb4: an Ordered Superstructure Derived from the Mg3Sb2 Structure Type Shalabh Gupta, Ashok K. Ganguli, and John D. Corbett pp 8175 - 8178; DOI: 10.1021/ic060835w |
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Mono- and Polynuclear Complexes of the Model Nucleobase 1-Methylcytosine. Synthesis and Characterization of cis-[(PMe2Ph)2Pt{(1-MeCy(-H)}]3(NO3)3 and cis-[(PPh3)2Pt{1-MeCy(-H)}(1-MeCy)]NO3 Bruno Longato, Diego Montagner, and Ennio Zangrando pp 8179 - 8187; DOI: 10.1021/ic060831r |
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Syntheses and Structural Properties of Rare Earth Carbodiimides Michael Neukirch, Sonja Tragl, and H.-Jürgen Meyer pp 8188 - 8193; DOI: 10.1021/ic0608952 |
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[CpNi(dithiolene)] (and Diselenolene) Neutral Radical Complexes Mitsushiro Nomura, Thomas Cauchy, Michel Geoffroy, Prashant Adkine, and Marc Fourmigué pp 8194 - 8204; DOI: 10.1021/ic0608546 |
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BF2 Complex of Fluorinated Dipyrrolyldiketone: A New Class of Efficient Receptor for Acetate Anions Hiromitsu Maeda and Yoshihiro Ito pp 8205 - 8210; DOI: 10.1021/ic0608703 |
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Oblate Deltahedra in Dimetallaboranes: Geometry and Chemical Bonding R. B. King pp 8211 - 8216; DOI: 10.1021/ic060922o |
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Theoretical Designs for Neutral Five-Membered Carbene Analogues of the Group 13 Elements: A New Target for Synthesis Chi-Hui Chen and Ming-Der Su pp 8217 - 8226; DOI: 10.1021/ic0608593 |
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Diverse Structures and Dimensionalities in Hybrid Frameworks of Strontium and Lanthanum with Isomeric Dihydroxybenzoates Meenakshi Dan, A. K. Cheetham, and C. N. R. Rao pp 8227 - 8238; DOI: 10.1021/ic060917k |
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Synthesis, Crystal Structure, and Magnetic Studies of One-Dimensional Cyano-Bridged Ln3+-Cr3+ Complexes with bpy as a Blocking Ligand Marta Estrader, Joan Ribas, Vassilis Tangoulis, Xavier Solans, Merce Font-Bardía, Miguel Maestro, and Carmen Diaz pp 8239 - 8250; DOI: 10.1021/ic060942q |
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Structural Polarity Induced by Cooperative Hydrogen Bonding and Lone-Pair Alignment in the Molecular Uranyl Iodate Na2[UO2(IO3)4(H2O)] Travis H. Bray, James V. Beitz, Amanda C. Bean, Yaqin Yu, and Thomas E. Albrecht-Schmitt pp 8251 - 8257; DOI: 10.1021/ic060957o |
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Syntheses and Structures of [M{In(SC{O}Ph)4}2] (M = Mg and Ca): Single Molecular Precursors to MIn2S4 Materials Lu Tian, Wei Hoon Lye, Theivanayagam C. Deivaraj, and Jagadese J. Vittal pp 8258 - 8263; DOI: 10.1021/ic060993n |
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Syntheses, Structures, Physical Properties, and Theoretical Studies of CeMxOS (M = Cu, Ag; x 0.8) and CeAgOS George H. Chan, Bin Deng, Mariana Bertoni, John R. Ireland, Mark C. Hersam, Thomas O. Mason, Richard P. Van Duyne, and James A. Ibers pp 8264 - 8272; DOI: 10.1021/ic061041k |
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Electronic Transitions in [Re6S8X6]4- (X = Cl, Br, I): Results from Time-Dependent Density Functional Theory and Solid-State Calculations Lindsay E. Roy and Timothy Hughbanks pp 8273 - 8282; DOI: 10.1021/ic061061m |
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Bimetallic Clusters of Iron with Palladium and Platinum. Synthesis and Structures of Fe2(CO)9[M(PBut3)]2 (M = Pd or Pt) and Fe2(CO)8[Pt(PBut3)]2(-H)2 Richard D. Adams, Burjor Captain, and William C. Pearl, Jr. pp 8283 - 8287; DOI: 10.1021/ic061087d |
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Chromogenic Indicator for Anion Reporting Based on an N-Substituted Oxoporphyrinogen Jonathan P. Hill, Amy Lea Schumacher, Francis D'Souza, Jan Labuta, Carl Redshaw, Mark R. J. Elsegood, Masaru Aoyagi, Takashi Nakanishi, and Katsuhiko Ariga pp 8288 - 8296; DOI: 10.1021/ic0611591 |
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Influence of Hartree-Fock Exchange on the Calculated Mössbauer Isomer Shifts and Quadrupole Splittings in Ferrocene Derivatives Using Density Functional Theory Victor N. Nemykin and Ryan G. Hadt pp 8297 - 8307; DOI: 10.1021/ic061176q |
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Mono- and Dinuclear Oxovanadium(V)calixarene Complexes and Their Activity as Oxidation Catalysts Elke Hoppe, Christian Limberg, and Burkhard Ziemer pp 8308 - 8317; DOI: 10.1021/ic061106j |
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Structural Diversity within Analogous Compounds: Syntheses and Studies of M(SCH2CH2NH2)Cl (M = Zn, Cd, Hg) Holger Fleischer, Sylvia Hardt, and Dieter Schollmeyer pp 8318 - 8325; DOI: 10.1021/ic0604765 |
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Synthesis, Photophysical, Photochemical, and Redox Properties of Nitrospiropyrans Substituted with Ru or Os Tris(bipyridine) Complexes Ron T. F. Jukes, Biljana Bozic, Franti ek Hartl, Peter Belser, and Luisa De Colapp 8326 - 8341; DOI: 10.1021/ic0606680 |
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Syntheses, Characterization, and Catalytic Ability in Alkane Oxygenation of Chloro(dimethyl sulfoxide)ruthenium(II) Complexes with Tris(2-pyridylmethyl)amine and Its Derivatives1,2 Motowo Yamaguchi, Hiroyuki Kousaka, Shinichi Izawa, Yoshiki Ichii, Takashi Kumano, Dai Masui, and Takamichi Yamagishi pp 8342 - 8354; DOI: 10.1021/ic060722c |
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Substituent Effects on Gd(III)-Based MRI Contrast Agents: Optimizing the Stability and Selectivity of the Complex and the Number of Coordinated Water Molecules1 Valérie C. Pierre, Mauro Botta, Silvio Aime, and Kenneth N. Raymond pp 8355 - 8364; DOI: 10.1021/ic061262q |
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Dioxotungsten 1,2-Benzenedithiolate Complex Stabilized by NH···S Hydrogen Bonds Koji Baba, Taka-aki Okamura, Hitoshi Yamamoto, Tetsuo Yamamoto, Mitsuo Ohama, and Norikazu Ueyama pp 8365 - 8371; DOI: 10.1021/ic060719t |
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Characterization of the Particulate Methane Monooxygenase Metal Centers in Multiple Redox States by X-ray Absorption Spectroscopy Raquel L. Lieberman, Kalyan C. Kondapalli, Deepak B. Shrestha, Amanda S. Hakemian, Stephen M. Smith, Joshua Telser, Jane Kuzelka, Rajeev Gupta, A. S. Borovik, Stephen J. Lippard, Brian M. Hoffman, Amy C. Rosenzweig, and Timothy L. Stemmler pp 8372 - 8381; DOI: 10.1021/ic060739v |
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Nanocluster Formation and Stabilization Fundamental Studies: Lisa Starkey Ott and Richard G. Finke pp 8382 - 8393; DOI: 10.1021/ic060876s |
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Crystal Growth and Structure Determination of Oxygen-Deficient Sr6Co5O15 Junliang Sun, Guobao Li, Zhaofei Li, Liping You, and Jianhua Lin pp 8394 - 8402; DOI: 10.1021/ic060862m |
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Hollow PbWO4 Nanospindles via a Facile Sonochemical Route Jun Geng, Jun-Jie Zhu, Du-Juan Lu, and Hong-Yuan Chen pp 8403 - 8407; DOI: 10.1021/ic0608804 |
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Neutron Diffraction Studies of U4O9: Comparison with EXAFS Results F. Garrido, A. C. Hannon, R. M. Ibberson, L. Nowicki, and B. T. M. Willis pp 8408 - 8413; DOI: 10.1021/ic060964c |
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Synthesis, Structure, and Biological Activity of Ferrocenyl Carbohydrate Conjugates Cara L. Ferreira, Charles B. Ewart, Cheri A. Barta, Susan Little, Vanessa Yardley, Candice Martins, Elena Polishchuk, Peter J. Smith, John R. Moss, Michael Merkel, Michael J. Adam, and Chris Orvig pp 8414 - 8422; DOI: 10.1021/ic061166p |
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Preferred Bonding Motif for Indium Aminoethanethiolate Complexes: Structural Characterization of (Me2NCH2CH2S)2InX/SR (X = Cl, I; R = 4-MeC6H4, 4-MeOC6H4) Glen G. Briand, Benjamin F. T. Cooper, David B. S. MacDonald, Caleb D. Martin, and Gabriele Schatte pp 8423 - 8429; DOI: 10.1021/ic061132h |
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Steric Effects in the Aerobic Oxidation of -Allylnickel(II) Complexes with N-Heterocyclic Carbenes Benjamin R. Dible and Matthew S. Sigman pp 8430 - 8441; DOI: 10.1021/ic0612451 |
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Molecular Structures of Arachno-Heteroboranes with Decaborane Frameworks: Two Cs-symmetrical Azacarba- and Carbathiaboranes Drahomír Hnyk, Josef Holub, Stuart A. Hayes, Mark F. Robinson, Derek A. Wann, Heather E. Robertson, and David W. H. Rankin pp 8442 - 8446; DOI: 10.1021/ic061253h |
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Syntheses, Spectroscopies and Structures of Molybdenum(VI) Complexes with Homocitrate Zhao-Hui Zhou, Shu-Ya Hou, Ze-Xing Cao, Khi-Rui Tsai, and Yuan L. Chow pp 8447 - 8451; DOI: 10.1021/ic061429f |
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Organically Directed Iron Sulfate Chains: Structural Diversity Based on Hydrogen Bonding Interactions Yunlong Fu, Zhiwei Xu, Jialin Ren, Haishun Wu, and Rong Yuan pp 8452 - 8458; DOI: 10.1021/ic061059v |
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High-Frequency and -Field EPR Investigation of a Manganese(III) N-Confused Porphyrin Complex, [Mn(NCTPP)(py)2] John D. Harvey, Christopher J. Ziegler, Joshua Telser, Andrew Ozarowski, and J. Krzystek: pp 8459 - 8459; DOI: 10.1021/ic061505e |
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New Luminescent Europium(III) Chelates for DNA Labeling Takuya Nishioka, Jingli Yuan, Yuji Yamamoto, KeikoSumitomo, Zhen Wang, Kimikazu Hashino, Chihiro Hosoya, Keisuke Ikawa, Guilan Wang, and Kazuko Matsumoto: pp 8460 - 8460; DOI: 10.1021/ic0615574 |
Issue 21
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Synthesis and Reactivity of a New Octanuclear Iron-Sulfur Nitrosyl Cluster Harris Kalyvas and Dimitri Coucouvanis pp 8462 - 8464; DOI: 10.1021/ic060417r |
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A Traditional Synthetic Method, and a New Structural Motif, for Molybdenum-Gold Clusters: Synthesis and Solid-State Structure of Au8{Mo(CO)5}4(PPh3)4 Roberto Della Pergola, Luigi Garlaschelli, Maria Carlotta Malatesta, Carlo Manassero, and Mario Manassero pp 8465 - 8467; DOI: 10.1021/ic060524l |
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New 3-D La(III)-Cu(II)-Containing Coordination Polymer with a High Potential Porosity Olivier Guillou, Carole Daiguebonne, Magatte Camara, and Nicolas Kerbellec pp 8468 - 8470; DOI: 10.1021/ic0607538 |
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First 3D 3d-4f Interpenetrating Structure: Synthesis, Reaction, and Characterization of {[LnCr(IDA)2(C2O4)]}n Bin Zhai, Long Yi, Hong-Shen Wang, Bin Zhao, Peng Cheng, Dai-Zheng Liao, and Shi-Ping Yan pp 8471 - 8473; DOI: 10.1021/ic060787f |
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Intersite Structural Rearrangement of the Blue Copper Site Induced by Substrate Binding: Spectroscopic Studies of a Copper-Containing Nitrite Reductase from Alcaligenes xylosoxidans NCIMB 11015 Takamitsu Kohzuma, Makiko Kikuchi, Naoko Horikoshi, Shigenori Nagatomo, Teizo Kitagawa, and Roman S. Czernuszewicz pp 8474 - 8476; DOI: 10.1021/ic0609195 |
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An Isolable, Nonreducible High-Valent Manganese(V) Imido Corrolazine Complex David E. Lansky, Joseph R. Kosack, Amy A. Narducci Sarjeant, and David P. Goldberg pp 8477 - 8479; DOI: 10.1021/ic0609251 |
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Nonfluorinated Volatile Copper(I) 1,3-Diketiminates as Precursors for Cu Metal Deposition via Atomic Layer Deposition Kyung-Ho Park, Alexander Z. Bradley, Jeffery S. Thompson, and Will J. Marshall pp 8480 - 8482; DOI: 10.1021/ic061016e |
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The Structure and Synthesis of Plutonium(III) Chlorides from Aqueous Solution Richard E. Wilson, Philip M. Almond, Peter C. Burns, and L. Soderholm pp 8483 - 8485; DOI: 10.1021/ic060979a |
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Luminescent 2-D Double-layered Polymer, [(CuI)4(CH3SCH3)3], Containing Helical Chains Constructed by Flower-Basket-Shaped Cu4I4 Clusters Jian Zhou, Guo-Qing Bian, Jie Dai, Yong Zhang, Qin-Yu Zhu, and Wen Lu pp 8486 - 8488; DOI: 10.1021/ic060972t |
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Synthesis and Characterization of a Doxorubicin-Gd(III) Contrast Agent Conjugate: A New Approach toward Prodrug-Procontrast Complexes Luca Frullano, Baudilio Tejerina, and Thomas J. Meade pp 8489 - 8491; DOI: 10.1021/ic0612045 |
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Ultrahigh-Field NMR Spectroscopy of Quadrupolar Transition Metals: 55Mn NMR of Several Solid Manganese Carbonyls Kristopher J. Ooms, Kirk W. Feindel, Victor V. Terskikh, and Roderick E. Wasylishen pp 8492 - 8499; DOI: 10.1021/ic0608445 |
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Metal-Binding Thermodynamics of the Histidine-Rich Sequence from the Metal-Transport Protein IRT1 of Arabidopsis thaliana Nicholas E. Grossoehme, Shreeram Akilesh, Mary Lou Guerinot, and Dean E. Wilcox pp 8500 - 8508; DOI: 10.1021/ic0606431 |
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Computational Comparison of Cation Coordination to Human Prion Peptide Models Eva-Stina Riihimäki and Lars Kloo pp 8509 - 8516; DOI: 10.1021/ic052079k |
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Toward a Clear-Cut Vision on the Origin of 2,6-Di(1,2,4-triazin-3-yl)pyridine Selectivity for Trivalent Actinides: Insights from Theory Laurence Petit, Carlo Adamo, and Pascale Maldivi pp 8517 - 8522; DOI: 10.1021/ic060227g |
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Syntheses, Structures, and Photoluminescence Properties of Metal(II) Halide Complexes with Pyridine-Containing Flexible Tripodal Ligands Gang Wu, Xiao-Feng Wang, Taka-aki Okamura, Wei-Yin Sun, and Norikazu Ueyama pp 8523 - 8532; DOI: 10.1021/ic060493u |
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Density Functional Theory Study of Fe(IV) d-d Optical Transitions in Active-Site Models of Class I Ribonucleotide Reductase Intermediate X with Vertical Self-Consistent Reaction Field Methods Wen-Ge Han, Tiqing Liu, Timothy Lovell, and Louis Noodleman pp 8533 - 8542; DOI: 10.1021/ic060566+ |
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Necklace-like Hollow Carbon Nanospheres from the Pentagon-Including Reactants: Synthesis and Electrochemical Properties Changzheng Wu, Xi Zhu, Lila Ye, Chuanzi OuYang, Shuangquan Hu, Lanyu Lei, and Yi Xie pp 8543 - 8550; DOI: 10.1021/ic060827f |
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Isomeric Distribution and Catalyzed Isomerization of Cobalt(III) Complexes with Pentadentate Macrocyclic Ligands. Importance of Hydrogen Bonding Gabriel Aullón, Paul V. Bernhardt, Fernando Bozoglián, Mercè Font-Bardía, Brendan P. Macpherson, Manuel Martínez, Carlos Rodríguez, and Xavier Solans pp 8551 - 8562; DOI: 10.1021/ic060720s |
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Investigation of the Pronounced Medium Effects Observed in the Voltammetry of the Highly Charged Lacunary Anions [-SiW11O39]8- and [-PW11O39]7- Si-Xuan Guo, Andrew W. A. Mariotti, Christine Schlipf, Alan M. Bond, and Anthony G. Wedd pp 8563 - 8574; DOI: 10.1021/ic061081o |
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Dilacunary Decatungstates Functionalized by Organometallic Ruthenium(II), [{Ru(C6H6)(H2O)}{Ru(C6H6)}(-XW10O36)]4- (X = Si, Ge) Li-Hua Bi, Elena V. Chubarova, Nadeen H. Nsouli, Michael H. Dickman, Ulrich Kortz, Bineta Keita, and Louis Nadjo pp 8575 - 8583; DOI: 10.1021/ic0606835 |
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Synthesis, Structure, and Photophysical Properties of Luminescent Platinum(II) Complexes Containing Cyclometalated 4-Styryl-Functionalized 2-Phenylpyridine Ligands Biaolin Yin, Felix Niemeyer, J. A. Gareth Williams, Ji Jiang, Abdou Boucekkine, Loïc Toupet, Hubert Le Bozec, and Véronique Guerchais pp 8584 - 8596; DOI: 10.1021/ic0607282 |
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Pseudotetrahedral Manganese Complexes Supported by the Anionic Tris(phosphino)borate Ligand [PhBPiPr3] Connie C. Lu and Jonas C. Peters pp 8597 - 8607; DOI: 10.1021/ic060735q |
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New Ruthenium Nitrosyl Complexes with Tris(1-pyrazolyl)methane (tpm) and 2,2'-Bipyridine (bpy) Coligands. Structure, Spectroscopy, and Electrophilic and Nucleophilic Reactivities of Bound Nitrosyl Mariela Videla, Julián S. Jacinto, Ricardo Baggio, María T. Garland, Priti Singh, Wolfgang Kaim, Leonardo D. Slep, and José A. Olabe pp 8608 - 8617; DOI: 10.1021/ic061062e |
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Inorganic Asymmetric Synthesis: Asymmetric Synthesis of a Two-Bladed Propeller, Octahedral Metal Complex Rebecca J. Warr, Anthony C. Willis, and S. Bruce Wild pp 8618 - 8627; DOI: 10.1021/ic060856q |
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Formation of p-Phenylenediamine-Crown Ether-[PMo12O40]4- Salts Tomoyuki Akutagawa, Daigoro Endo, Hiroyuki Imai, Shin-ichiro Noro, Leroy Cronin, and Takayoshi Nakamura pp 8628 - 8637; DOI: 10.1021/ic060857i |
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Syntheses, Structures, and Nonlinear Optical Properties of Heteroselenometallic W-Se-Ag Cluster Compounds Containing Phosphine Ligands Qian-Feng Zhang, Jihai Ding, Zhan Yu, Yinglin Song, Alexander Rothenberger, Dieter Fenske, and Wa-Hung Leung pp 8638 - 8647; DOI: 10.1021/ic0610839 |
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Infrared Spectra of the M(NO)n (M = Sn, Pb; n = 1, 2) and PbNO- Molecules Qiang Xu and Ling Jiang pp 8648 - 8654; DOI: 10.1021/ic061105r |
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Catalysts for Monooxygenations Made from Polyoxometalate: An Iron(V)-Oxo Derivative of the Lindqvist Anion Etienne Derat, Devesh Kumar, Ronny Neumann, and Sason Shaik pp 8655 - 8663; DOI: 10.1021/ic0610435 |
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Cadmium(II) and Zinc(II) Complexes of S-Confused Thiaporphyrin Micha J. Chmielewski, Miosz Pawlicki, Natasza Sprutta, Ludmia Szterenberg, and Lechosaw Latos-Grayskipp 8664 - 8671; DOI: 10.1021/ic061091p |
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Porous Metal-Organic Framework with Coordinatively Unsaturated MnII Sites:Sorption Properties for Various Gases Hoi Ri Moon, Norihito Kobayashi, and Myunghyun Paik Suh pp 8672 - 8676; DOI: 10.1021/ic0611948 |
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Construction of 3D Layer-Pillared Homoligand Coordination Polymers from a 2D Layered Precursor Jinyu Sun, Yaming Zhou, Qianrong Fang, Zhenxia Chen, Linhong Weng, Guangshan Zhu, Shilun Qiu, and Dongyuan Zhao pp 8677 - 8684; DOI: 10.1021/ic0612303 |
Luminescent Complexes of Iridium(III) Containing N CN-Coordinating Terdentate LigandsAndrew J. Wilkinson, Horst Puschmann, Judith A. K. Howard, Clive E. Foster, and J. A. Gareth Williams pp 8685 - 8699; DOI: 10.1021/ic061172l |
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Experimental and Theoretical Study of the Coordination of 1,2,4-Triazolato, Tetrazolato, and Pentazolato Ligands to the [K(18-crown-6)]+ Fragment Issam Kobrsi, Wenjun Zheng, John E. Knox, Mary Jane Heeg, H. Bernhard Schlegel, and Charles H. Winter pp 8700 - 8710; DOI: 10.1021/ic061256u |
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Homoleptic Zinc(II) Complexes with First and Second Coordination Shells of 5-tert-Butylpyrazole Sylvie L. Renard, Isabelle Sylvestre, Simon A. Barrett, Colin A. Kilner, and Malcolm A. Halcrow pp 8711 - 8718; DOI: 10.1021/ic052144q |
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Pyridine- and Phosphonate-Containing Ligands for Stable Ln Complexation. Extremely Fast Water Exchange on the GdIII Chelates Edina Balogh, Marta Mato-Iglesias, Carlos Platas-Iglesias, Éva Tóth, Kristina Djanashvili, Joop A. Peters, Andrés de Blas, and Teresa Rodríguez-Blas pp 8719 - 8728; DOI: 10.1021/ic0604157 |
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Theoretical Insight into Electronic Structures and Spectroscopic Properties of [Pt2(pop)4]4-, [Pt2(pcp)4]4-, and Related Derivatives (pop = P2O5H22- and pcp = P2O4CH42-) Qing-Jiang Pan, Hong-Gang Fu, Hai-Tao Yu, and Hong-Xing Zhang pp 8729 - 8735; DOI: 10.1021/ic060336v |
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Reversible Cation/Anion Extraction from K2La2Ti3O10: Formation of New Layered Titanates, KLa2Ti3O9.5 and La2Ti3O9 Z. Serpil Gönen, Daniel Paluchowski, Peter Zavalij, Bryan W. Eichhorn, and J. Gopalakrishnan pp 8736 - 8742; DOI: 10.1021/ic060434g |
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Synthesis, Characterization, and UV-vis Linear Absorption of Centrosymmetric -Systems Incorporating closo-Dodecaborate Clusters Rémy Bernard, David Cornu, Jean-Pierre Scharff, Rodica Chiriac, Philippe Miele, Patrice L. Baldeck, and Josef áslavskpp 8743 - 8748; DOI: 10.1021/ic060563x |
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A Dehydrogenation Mechanism of Metal Hydrides Based on Interactions between H+ and H- Jun Lu, Zhigang Zak Fang, and Hong Yong Sohn pp 8749 - 8754; DOI: 10.1021/ic060836o |
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Phosphorus-Nitrogen Compounds. Part 13. Syntheses, Crystal Structures, Spectroscopic, Stereogenic, and Anisochronic Properties of Novel Spiro-Ansa-Spiro-, Spiro-Bino-Spiro-, and Spiro-Crypta Phosphazene Derivatives Selen Bilge,  emsay Demiriz, Aytu Okumu, Zeynel Kiliç, Bari Tercan, Tuncer Hökelek, and Orhan Büyükgüngörpp 8755 - 8767; DOI: 10.1021/ic060630n |
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Kinetics and Mechanisms of Chlorine Dioxide and Chlorite Oxidations of Cysteine and Glutathione Ana Ison, Ihab N. Odeh, and Dale W. Margerum pp 8768 - 8775; DOI: 10.1021/ic0609554 |
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Isomerization Processes on Mixed Ortho-Metalated Phosphine/Succinimidato [Rh2(P(C5CH4)Ph2)2(OC4NH4O)2] Complexes. A Sliding Movement of the Succinimidato Ligand Julio Esteban, Pipsa Hirva, Pascual Lahuerta, and Manuel Martínez pp 8776 - 8784; DOI: 10.1021/ic061030r |
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Synthesis and Coordination Behavior of Planar-Chiral Ferrocene Alkenylphosphines Petr  tpnika and Ivana Císaovápp 8785 - 8798; DOI: 10.1021/ic061278g |
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Mononitrosyl Tris(Thiolate) Iron Complex [Fe(NO)(SPh)3]- and Dinitrosyl Iron Complex [(EtS)2Fe(NO)2]-: Formation Pathway of Dinitrosyl Iron Complexes (DNICs) from Nitrosylation of Biomimetic Rubredoxin [Fe(SR)4]2-/1- (R = Ph, Et) Tsai-Te Lu, Show-Jen Chiou, Chun-Yu Chen, and Wen-Feng Liaw pp 8799 - 8806; DOI: 10.1021/ic061439g |
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Aluminumoxyhydride: Improved Synthesis and Application as a Selective Reducing Agent Brij B. Tewari, Sukesh Shekar, Longchuan Huang, Carolyn E. Gorrell, Timothy P. Murphy, Kevin Warren, Nasri Nesnas, and Rudolf J. Wehmschulte pp 8807 - 8811; DOI: 10.1021/ic061276w |
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Metal-Binding Thermodynamics of the Histidine-Rich Sequence from the Metal-Transport Protein IRT1 of Arabidopsis thaliana. Nicholas E. Grossoehme, Shreeram Akilesh, Mary LouGuerinot, and Dean E. Wilcox: pp 8812 - 8812; DOI: 10.1021/ic061652c |
Issue 22
Aprotic Synthesis and Structural Determination of the Nanosized Nonprotonated  3-Octahedral [Pt6Ni38(CO)48]6- Hexaanion Stabilized as a Cubic Solvated [NMe4]+ SaltNamal de Silva and Lawrence F. Dahl pp 8814 - 8816; DOI: 10.1021/ic060648y |
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Dinuclear Cobalt Bis(dioxolene) Complex Exhibiting Two Sequential Thermally Induced Valence Tautomeric Transitions Nigel G. R. Hearns, Jasmine L. Kor ok, Michelle M. Paquette, and Kathryn E. Preusspp 8817 - 8819; DOI: 10.1021/ic0608997 |
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Novel Metalloreagent Cp(CO)2FeP(Se)(OR)2 Produced from P-Se Bond Cleavage in the Thermal Reaction of [CpFe(CO)2]2 with Phosphor-1,1-diselenolates C. W. Liu, Jem-Min Chen, Bidyut Kumar Santra, Sung-Yin Wen, Ben-Jie Liaw, and Ju-Chun Wang pp 8820 - 8822; DOI: 10.1021/ic061538u |
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Methanolysis as a Route to Gallium(III) Clusters: Synthesis and Structural Characterization of a Decanuclear Molecular Wheel Giannis S. Papaefstathiou, Anastasia Manessi, Catherine P. Raptopoulou, Aris Terzis, and Theodoros F. Zafiropoulos pp 8823 - 8825; DOI: 10.1021/ic060997s |
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Copper Complex of an Iminodioxabicyclo[3.3.1]nonane Pendant Ligand: The First Example of Iminodioxocin Bridgehead Nitrogen Coordination Debashree Mandal, A-Qing Wu, Guo-Cong Guo, and Debashis Ray pp 8826 - 8828; DOI: 10.1021/ic060833b |
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Straightforward Synthesis and Structure of a New Starting Material for Niobium Cluster Phases: [Nb6Cli12(CH3OH)a4Cla2]·6CH3OH Luis Fernando Piedra-Garza and Martin Köckerling pp 8829 - 8831; DOI: 10.1021/ic061020q |
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High-Spin [2 × 2] [FeIII2NiII2] Heterometallic Square Grid with an S = 3 Ground State Stewart R. Parsons, Laurence K. Thompson, Subrata K. Dey, Claire Wilson, and Judith A. K. Howard pp 8832 - 8834; DOI: 10.1021/ic061402w |
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K3Ln(AsS4)2 (Ln = Nd, Sm, Gd): the First Rare Earth Thioarsenate Compounds with Infinite Straight 1[Ln(AsS4)2]3- Chains Yuandong Wu, Christian Näther, and Wolfgang Bensch pp 8835 - 8837; DOI: 10.1021/ic060933h |
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Triggered Ligand Release Coupled to Framework Rearrangement: Generating Crystalline Porous Coordination Materials Junhua Jia, Xiang Lin, Alexander J. Blake, Neil R. Champness, Peter Hubberstey, Limin Shao, Gavin Walker, Claire Wilson, and Martin Schröder pp 8838 - 8840; DOI: 10.1021/ic061095u |
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Trinuclear, Antiferromagnetically Coupled CuII Complex with an EPR Spectrum of Mononuclear CuII: Effect of Alcoholic Solvents Gellert Mezei, Raphael G. Raptis, and Joshua Telser pp 8841 - 8843; DOI: 10.1021/ic061186r |
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Dicoordinate Copper(I) Silanechalcogenolates Iliana Medina, Heiko Jacobsen, Joel T. Mague, and Mark J. Fink pp 8844 - 8846; DOI: 10.1021/ic061579q |
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Coexistence of Spin Canting and Metamagnetism in a One-Dimensional Mn(III) Complex Bridged by a Single End-to-End Azide Hyun Hee Ko, Jeong Hak Lim, Hyoung Chan Kim, and Chang Seop Hong pp 8847 - 8849; DOI: 10.1021/ic061415+ |
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Neutral High-Potential Nickel Triad Bisdithiolenes: Structure and Solid-State NMR Properties of Pt[S2C2(CF3)2]2 Elzbieta Kogut, Joel A. Tang, Alan J. Lough, Cory M. Widdifield, Robert W. Schurko, and Ulrich Fekl pp 8850 - 8852; DOI: 10.1021/ic0614972 |
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Structural Factors Influencing Linear M-H-M Bonding in Bis(dialkylphosphino)methane Complexes of Nickel William S. Tyree, David A. Vicic, Paula M. B. Piccoli, and Arthur J. Schultz pp 8853 - 8855; DOI: 10.1021/ic0617036 |
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Keggin POM Microtubes: a Coincident Product of Crystal Growth and Species Transformation Zhifeng Xin, Jun Peng, Tao Wang, Bo Xue, Yumei Kong, Li Li, and Enbo Wang pp 8856 - 8858; DOI: 10.1021/ic061218a |
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Syntheses of Highly Fluorinated 1,3,5-Triazapentadienyl Ligands and Their Use in the Isolation of Copper(I)-Carbonyl and Copper(I)-Ethylene Complexes H. V. Rasika Dias, Shreeyukta Singh, and Jaime A. Flores pp 8859 - 8861; DOI: 10.1021/ic061739y |
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Structure-Function Correlations in Iron(II) Tris(pyrazolyl)borate Spin-State Crossover Complexes Daniel L. Reger, James R. Gardinier, J. Derek Elgin, Mark D. Smith, Dimitri Hautot, Gary J. Long, and Fernande Grandjean pp 8862 - 8875; DOI: 10.1021/ic0607437 |
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13C NMR Spectroscopy of Core Heme Carbons as a Simple Tool to Elucidate the Coordination State of Ferric High-Spin Heme Proteins Aileen Y. Alontaga, Richard A. Bunce, Angela Wilks, and Mario Rivera pp 8876 - 8881; DOI: 10.1021/ic0607484 |
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Enhanced Near-Infrared-Luminescence in an Erbium Tetrafluoroterephthalate Framework Banglin Chen, Yu Yang, Fatima Zapata, Guodong Qian, Yongshi Luo, Jiahua Zhang, and Emil B. Lobkovsky pp 8882 - 8886; DOI: 10.1021/ic060568u |
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Experimental and Theoretical Evaluation of the Charge Distribution over the Ruthenium and Dioxolene Framework of [Ru(OAc)(dioxolene)(terpy)] (terpy = 2,2':6',2' '-terpyridine) Depending on the Substituents Tohru Wada, Masahiro Yamanaka, Tetsuaki Fujihara, Yuji Miyazato, and Koji Tanaka pp 8887 - 8894; DOI: 10.1021/ic060696i |
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Cyano-Bridged Pentanuclear FeIII3MII2 (M = Ni, Co, Fe) Clusters: Synthesis, Structures, and Magnetic Properties Zhi-Guo Gu, Qiao-Fang Yang, Wei Liu, You Song, Yi-Zhi Li, Jing-Lin Zuo, and Xiao-Zeng You pp 8895 - 8901; DOI: 10.1021/ic060772h |
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Planar Tetracoordinate Carbon Atoms Centered in Bare Four-membered Rings of Late Transition Metals Debjani Roy, Clémence Corminboeuf, Chaitanya S. Wannere, R. Bruce King, and Paul v. R. Schleyer pp 8902 - 8906; DOI: 10.1021/ic060802g |
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Highly Phosphorescent Iridium Complexes Containing Both Tridentate Bis(benzimidazolyl)-benzene or -pyridine and Bidentate Phenylpyridine: Synthesis, Photophysical Properties, and Theoretical Study of Ir-Bis(benzimidazolyl)benzene Complex Shinya Obara, Masumi Itabashi, Fumio Okuda, Satoru Tamaki, Yoshiaki Tanabe, Youichi Ishii, Koichi Nozaki, and Masa-aki Haga pp 8907 - 8921; DOI: 10.1021/ic060796o |
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Solvent-Enhanced Magnetic Ordering Temperature for Mixed-Valent Chromium Hexacyanovanadate(II), CrII0.5CrIII[VII(CN)6]·zMeCN, Magnetic Materials Kendric J. Nelson, Ian D. Giles, Shayla A. Troff, Atta M. Arif, and Joel S. Miller pp 8922 - 8929; DOI: 10.1021/ic0608896 |
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Electronic Structure of Four-Coordinate C3v Nickel(II) Scorpionate Complexes: Investigation by High-Frequency and -Field Electron Paramagnetic Resonance and Electronic Absorption Spectroscopies Patrick J. Desrochers, Joshua Telser, S. A. Zvyagin, Andrew Ozarowski, J. Krzystek, and David A. Vicic pp 8930 - 8941; DOI: 10.1021/ic060843c |
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Synthesis, Crystal Structures, and Magnetic Properties of Cyano-Bridged Heterobimetallic Chains Based on [(Tp)Fe(CN)3]- He-Rui Wen, Cai-Feng Wang, You Song, Song Gao, Jing-Lin Zuo, and Xiao-Zeng You pp 8942 - 8949; DOI: 10.1021/ic060928d |
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Mixed-Valent Cobalt Spin Clusters: a Hexanuclear Complex and a One-Dimensional Coordination Polymer Comprised of Alternating Hepta- and Mononuclear Fragments Kerwyn G. Alley, Roland Bircher, Oliver Waldmann, Stefan T. Ochsenbein, Hans U. Güdel, Boujemaa Moubaraki, Keith S. Murray, Felix Fernandez-Alonso, Brendan F. Abrahams, and Colette Boskovic pp 8950 - 8957; DOI: 10.1021/ic060938e |
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Electronic Stabilization Effects: Three New K-In-T (T = Mg, Au, Zn) Network Compounds Bin Li and John D. Corbett pp 8958 - 8964; DOI: 10.1021/ic061089y |
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Structural, Thermal, Spectroscopic, Specific-Heat, and Magnetic Studies of (C5H18N3)[Fe3(HPO3)6]·3H2O: A New Organically Templated Iron(III) Phosphite with a Pillared Structure Formed by the Interpenetration of Two Subnets U.-Chan Chung, José L. Mesa, José L. Pizarro, Jesús Rodríguez Fernández, Jorge Sánchez Marcos, José S. Garitaonandia, María I. Arriortua, and Teófilo Rojo pp 8965 - 8972; DOI: 10.1021/ic060815u |
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In(OH)3 and In2O3 Nanorod Bundles and Spheres: Microemulsion-Mediated Hydrothermal Synthesis and Luminescence Properties Jun Yang, Cuikun Lin, Zhenling Wang, and Jun Lin pp 8973 - 8979; DOI: 10.1021/ic060934+ |
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Fluorescent Nitric Oxide Detection by Copper Complexes Bearing Anthracenyl and Dansyl Fluorophore Ligands Mi Hee Lim and Stephen J. Lippard pp 8980 - 8989; DOI: 10.1021/ic0609913 |
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Functionalities of One-Dimensional Dynamic Ultramicropores in Nickel(II) Coordination Polymers Shin-ichiro Noro, Ryo Kitaura, Susumu Kitagawa, Tomoyuki Akutagawa, and Takayoshi Nakamura pp 8990 - 8997; DOI: 10.1021/ic061052d |
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Luminescent Properties of Water-Soluble Conjugated Metallopolymers and Their Application to Fluorescent Nitric Oxide Detection Loi Do, Rhett C. Smith, Andrew G. Tennyson, and Stephen J. Lippard pp 8998 - 9005; DOI: 10.1021/ic060998k |
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Development of Organometallic Ruthenium-Arene Anticancer Drugs That Resist Hydrolysis Wee Han Ang, Elisa Daldini, Claudine Scolaro, Rosario Scopelliti, Lucienne Juillerat-Jeannerat, and Paul J. Dyson pp 9006 - 9013; DOI: 10.1021/ic061008y |
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Hybrid Organic-Inorganic Assemblies Based on Molybdates and Dimethyltin Linkers Santiago Reinoso, Michael H. Dickman, Markus Reicke, and Ulrich Kortz pp 9014 - 9019; DOI: 10.1021/ic061191v |
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Reactivity and Properties of [-O-BiIII...O=Mo-]n Chains Stefan Roggan, Christian Limberg, Burkhard Ziemer, Maike Siemons, and Ulrich Simon pp 9020 - 9031; DOI: 10.1021/ic061198c |
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Chemistry Surrounding Monomeric Copper(I) Methyl, Phenyl, Anilido, Ethoxide, and Phenoxide Complexes Supported by N-Heterocyclic Carbene Ligands: Reactivity Consistent with Both Early and Late Transition Metal Systems Laurel A. Goj, Elizabeth D. Blue, Samuel A. Delp, T. Brent Gunnoe, Thomas R. Cundari, Aaron W. Pierpont, Jeffrey L. Petersen, and Paul D. Boyle pp 9032 - 9045; DOI: 10.1021/ic0611995 |
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A Rare and Highly Oxidized Mo25.5+ Unit Stabilized by Oxo Anions and Supported by Formamidinate Bridges F. Albert Cotton, Carlos A. Murillo, Rongmin Yu, and Qinliang Zhao pp 9046 - 9052; DOI: 10.1021/ic061352v |
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Reaction of [Fe2(CO)8(-CF2)] with AsMe3 and Other Lewis Bases: Syntheses, Crystal Structures of [Fe(CO)6(AsMe3)2(-CF2)] and [Fe(CO)5(AsMe3)3(-CF2)], and Theoretical Considerations Meritxell DelaVarga, Wolfgang Petz, Bernhard Neumüller, and Ramon Costa pp 9053 - 9063; DOI: 10.1021/ic0604011 |
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Synthesis, Solid-State NMR, and X-ray Powder Diffraction Characterization of Group 12 Coordination Polymers, Including the First Example of a C-Mercuriated Pyrazole Norberto Masciocchi, Simona Galli, Enrica Alberti, Angelo Sironi, Corrado Di Nicola, Claudio Pettinari, and Luciano Pandolfo pp 9064 - 9074; DOI: 10.1021/ic061349b |
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Even-Numbered Metal Chain Complexes: Synthesis, Characterization, and DFT Analysis of [Ni4(4-Tsdpda)4(H2O)2] (Tsdpda2- = N-(p-toluenesulfonyl)dipyridyldiamido), [Ni4(4-Tsdpda)4]+, and Related Ni4 String Complexes Xavier López, Ming-Yi Huang, Gin-Chen Huang, Shie-Ming Peng, Feng-Yin Li, Marc Bénard, and Marie-Madeleine Rohmer pp 9075 - 9084; DOI: 10.1021/ic0612505 |
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Reactions of Hypersilyl Potassium with Rare-Earth Metal Bis(Trimethylsilylamides): Addition versus Peripheral Deprotonation Mark Niemeyer pp 9085 - 9095; DOI: 10.1021/ic0613659 |
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Isotropic and Antisymmetric Double-Exchange, Zero-Field, Zeeman, and Hyperfine Splittings in Trinuclear Valence-Delocalized [Cu37+] Clusters Moisey I. Belinsky pp 9096 - 9106; DOI: 10.1021/ic060732d |
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The (P4HMes4)- Anion: Lability, Fluxionality, and Structural Ambiguity (Mes = 2,4,6-Me3C6H2) Robert Wolf, Santiago Gomez-Ruiz, Joachim Reinhold, Winfried Böhlmann, and Evamarie Hey-Hawkins pp 9107 - 9113; DOI: 10.1021/ic060795w |
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Syntheses, Crystal Structures, and Magnetic Properties of [LnIII2(Succinate)3(H2O)2]·0.5H2O [Ln = Pr, Nd, Sm, Eu, Gd, and Dy] Polymeric Networks: Unusual Ferromagnetic Coupling in Gd Derivative Subal Chandra Manna, Ennio Zangrando, Alessandro Bencini, Cristiano Benelli, and Nirmalendu Ray Chaudhuri pp 9114 - 9122; DOI: 10.1021/ic060807d |
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Rhodium Dimers with 2,2-Dimethyl-1,3-diisocyano and Bis(diphenylphosphino)methane Bridging Ligands Justin J. Stace, Kurt D. Lambert, Jeanette A. Krause, and William B. Connick pp 9123 - 9131; DOI: 10.1021/ic060923g |
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Solid-State 119Sn NMR and Mössbauer Spectroscopy of "Distannynes": Evidence for Large Structural Differences in the Crystalline Phase Geoffrey H. Spikes, Jason R. Giuliani, Matthew P. Augustine, Israel Nowik, Rolfe H. Herber, and Philip P. Power pp 9132 - 9136; DOI: 10.1021/ic060983m |
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Tuning of the Optical Properties and Lewis Acidity of Dibenzopnictogenaborins by Modification on Bridging Main Group Elements Tomohiro Agou, Junji Kobayashi, and Takayuki Kawashima pp 9137 - 9144; DOI: 10.1021/ic061055q |
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Targeted Guanine Oxidation by a Dinuclear Copper(II) Complex at Single-Stranded/Double-Stranded DNA Junctions Lei Li, Narasimha N. Murthy, Joshua Telser, Lev N. Zakharov, Glenn P. A. Yap, Arnold L. Rheingold, Kenneth D. Karlin, and Steven E. Rokita pp 9145 - 9145; DOI: 10.1021/ic061786q |
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Asymmetric Transformation of a Double-Stranded, Dicopper(I) Helicate Containing Achiral Bis(bidentate) Schiff Bases Nicolle C. Habermehl, Patricia M. Angus, Nathan L. Kilah, Lasse Norén, A. David Rae, Anthony C. Willis, and S. Bruce Wild: pp 9146 - 9146; DOI: 10.1021/ic0680009 |
Issue 23
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NaCl-Type Frameworks of [M(pyrazine)2NO2]ClO4 (M = Co, Cu), the First Examples Containing 1,3-Nitrito Bridges Showing Antiferromagnetism Tao Liu, Yi-Hong Chen, Yan-Juan Zhang, Zhe-Ming Wang, and Song Gao pp 9148 - 9150; DOI: 10.1021/ic060759x |
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New Barium Cobaltite Series Ban+1ConO3n+3(Co8O8): Intergrowth Structure Containing Perovskite and CdI2-Type Layers Junliang Sun, Min Yang, Guobao Li, Tao Yang, Fuhui Liao, Yingxia Wang, Ming Xiong, and Jianhua Lin pp 9151 - 9153; DOI: 10.1021/ic060992v |
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Novel Layered Copper Phosphoramidate, Which Contains Six-Membered Rings Made of Five Different Elements Ramaswamy Murugavel and Mayank Pratap Singh pp 9154 - 9156; DOI: 10.1021/ic061298i |
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A Novel Cascade Supramolecular Complex with a Reversible Nanosized 18-Component H-Bonded {(C6H6)6(SbF6)12}12- Cage Unit Templated by a Chiral Metal-Organic Complex Yu-Bin Dong, Le Wang, Jian-Ping Ma, and Ru-Qi Huang pp 9157 - 9159; DOI: 10.1021/ic061005l |
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Metal-Metal Bonding in Sterically Frustrated Dipalladium Species Stefan Deeken, Günter Motz, Viktor Bezugly, Horst Borrmann, Frank R. Wagner, and Rhett Kempe pp 9160 - 9162; DOI: 10.1021/ic0610987 |
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Two Polyknotted Topological Isomers of Copper(I) 3,5-Bis(4-pyridyl)pyrazolates Shun-Ze Zhan, Dan Li, Xiao-Ping Zhou, and Xin-Hui Zhou pp 9163 - 9165; DOI: 10.1021/ic061152j |
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Expanding the Scope of Sulfur-Centered Arbuzov Rearrangement in Diethyl/Di-n-propyl Sulfite for the Synthesis of Mixed-Ligand Di-n-butyltin Alkanesulfonates Ravi Shankar, Atul Pratap Singh, and Shailesh Upreti pp 9166 - 9168; DOI: 10.1021/ic061377u |
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Bidentate Phosphine Ligand Based Fe2S2-Containing Macromolecules: Synthesis, Characterization, and Catalytic Electrochemical Hydrogen Production Weiming Gao, Jianhui Liu, Björn Åkermark, and Licheng Sun pp 9169 - 9171; DOI: 10.1021/ic061258e |
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NMR Observations of 13C-Enriched Coenzyme B12 Bound to the Ribonucleotide Reductase from Lactobacillus Leichmannii Kenneth L. Brown, Jing Li, and Xiang Zou pp 9172 - 9174; DOI: 10.1021/ic061385a |
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Symmetric and Unsymmetric "Dumbbells" of Ru2-Alkynyl Units via C-C Bond Formation Reactions Wei-Zhong Chen and Tong Ren pp 9175 - 9177; DOI: 10.1021/ic061511a |
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Phototriggered S O Isomerization of a Ruthenium-Bound Chelating Sulfoxide Dennis P. Butcher, Jr., Aaron A. Rachford, Jeffrey L. Petersen, and Jeffrey J. Rack pp 9178 - 9180; DOI: 10.1021/ic061611g |
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Iron-Only Hydrogenase Mimics. Thermodynamic Aspects of the Use of Electrochemistry to Evaluate Catalytic Efficiency for Hydrogen Generation Greg A. N. Felton, Richard S. Glass, Dennis L. Lichtenberger, and Dennis H. Evans pp 9181 - 9184; DOI: 10.1021/ic060984e |
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Synthesis of Molybdenum Complexes that Contain "Hybrid" Triamidoamine Ligands, [(Hexaisopropylterphenyl-NCH2CH2)2NCH2CH2N-aryl]3-, and Studies Relevant to Catalytic Reduction of Dinitrogen Walter W. Weare, Richard R. Schrock, Adam S. Hock, and Peter Müller pp 9185 - 9196; DOI: 10.1021/ic0613457 |
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Synthesis of [(HIPTNCH2CH2)3N]V Compounds (HIPT = 3,5-(2,4,6-i-Pr3C6H2)2C6H3) and an Evaluation of Vanadium for the Reduction of Dinitrogen to Ammonia Nathan C. Smythe, Richard R. Schrock, Peter Müller, and Walter W. Weare pp 9197 - 9205; DOI: 10.1021/ic061554r |
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Fluoride Abstraction and Reversible Photochemical Reduction of Cationic Uranyl(VI) Phosphine Oxide Complexes Shanmugaperumal Kannan, Morgan A. Moody, Charles L. Barnes, and Paul B. Duval pp 9206 - 9212; DOI: 10.1021/ic060742e |
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Mononuclear Schiff Base Boron Halides: Synthesis, Characterization, and Dealkylation of Trimethyl Phosphate Amitabha Mitra, Lauren J. DePue, Jeffrey E. Struss, Bijal P. Patel, Sean Parkin, and David A. Atwood pp 9213 - 9224; DOI: 10.1021/ic0607890 |
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Environmental Effects on the Structure of Metal Ion-DOTA Complexes: An ab Initio Study of Radiopharmaceutical Metals Edmond Y. Lau, Felice C. Lightstone, and Michael E. Colvin pp 9225 - 9232; DOI: 10.1021/ic0602897 |
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Coordination Framework Hosts Consisting of 4-Pyridyl-Substituted Carboxylic Acid (PCA) Dimers and 1D Chains of Ni2+ and SCN-: A Rational Structural Extension toward Coordination Framework Hosts with Large Rectangular Cavities Ryo Sekiya, Shin-ichi Nishikiori, and Katsuyuki Ogura pp 9233 - 9244; DOI: 10.1021/ic0605367 |
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Efficient Green-Blue-Light-Emitting Cationic Iridium Complex for Light-Emitting Electrochemical Cells Md. K. Nazeeruddin, R. T. Wegh, Z. Zhou, C. Klein, Q. Wang, F. De Angelis, S. Fantacci, and M. Grätzel pp 9245 - 9250; DOI: 10.1021/ic060495e |
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Synthesis and Structure of New Water-Soluble and Stable Tantalum Compound: Ammonium Tetralactatodiperoxo--oxo-ditantalate(V) Valery Petrykin, Masato Kakihana, Kohtaro Yoshioka, Satoshi Sasaki, Yoshihiro Ueda, Koji Tomita, Yoshiyuki Nakamura, Motoo Shiro, and Akihiko Kudo pp 9251 - 9256; DOI: 10.1021/ic060861u |
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Spontaneously Resolved Homochiral 3D Lanthanide-Silver Heterometallic Coordination Framework with Extended Helical Ln-O-Ag Subunits Xiaojun Gu and Dongfeng Xue pp 9257 - 9261; DOI: 10.1021/ic060806l |
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Methoxy-Substituted TQEN Family of Fluorescent Zinc Sensors Yuji Mikata, Motoko Wakamatsu, Ayano Kawamura, Natsuko Yamanaka, Shigenobu Yano, Akira Odani, Kazuko Morihiro, and Satoshi Tamotsu pp 9262 - 9268; DOI: 10.1021/ic060810x |
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Equilibrium and Formation/Dissociation Kinetics of Some LnIIIPCTA Complexes Gyula Tircsó, Zoltán Kovács, and A. Dean Sherry pp 9269 - 9280; DOI: 10.1021/ic0608750 |
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Effect of the Environment on Molecular Properties: Synthesis, Structure, and Photoluminescence of Cu(I) Bis(2,9-dimethyl-1,10-phenanthroline) Nanoclusters in Eight Different Supramolecular Frameworks Shao-Liang Zheng, Milan Gembicky, Marc Messerschmidt, Paulina M. Dominiak, and Philip Coppens pp 9281 - 9289; DOI: 10.1021/ic0609709 |
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Flexible and Shape-Selective Guest Binding at CuII Axial Sites in 1-Dimensional CuII-1,2-Bis(4-pyridyl)ethane Coordination Polymers Shin-ichiro Noro, Satoshi Horike, Daisuke Tanaka, Susumu Kitagawa, Tomoyuki Akutagawa, and Takayoshi Nakamura pp 9290 - 9300; DOI: 10.1021/ic0609249 |
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NH4[BGe3O8]: A New Borogermanate Framework Made of Infinite-Chain Building Blocks Ding-Bang Xiong, Hao-Hong Chen, Man-Rong Li, Xin-Xin Yang, and Jing-Tai Zhao pp 9301 - 9305; DOI: 10.1021/ic060967p |
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Complexes of Greatly Enhanced Thermodynamic Stability and Metal Ion Size-Based Selectivity, Formed by the Highly Preorganized Non-Macrocyclic Ligand 1,10-Phenanthroline-2,9-dicarboxylic Acid. A Thermodynamic and Crystallographic Study Darren L. Melton, Donald G. VanDerveer, and Robert D. Hancock pp 9306 - 9314; DOI: 10.1021/ic061010p |
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Heterobimetallic Zn(II)-Ln(III) Phenylene-Bridged Schiff Base Complexes, Computational Studies, and Evidence for Singlet Energy Transfer as the Main Pathway in the Sensitization of Near-Infrared Nd3+ Luminescence Wing-Kit Lo, Wai-Kwok Wong, Wai-Yeung Wong, Jianping Guo, Kai-Tai Yeung, Yuen-Kit Cheng, Xiaoping Yang, and Richard A. Jones pp 9315 - 9325; DOI: 10.1021/ic0610177 |
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Crystal Structure, Judd-Ofelt Analysis, and Spectroscopic Assessment of a TmAl3(BO3)4 Crystal as a New Potential Diode-Pumped Laser near 1.9 m Guohua Jia, Chaoyang Tu, Jianfu Li, Zhenyu You, Zhaojie Zhu, and Baichang Wu pp 9326 - 9331; DOI: 10.1021/ic061025n |
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On the Role of the Bridging Dicyanamidobenzene Ligand in a New Binuclear Ruthenium Complex: [{Ru(tpy)(thd)}2(-dicyd)][PF6] with tpy = 2,2':6',2' '-Terpyridine and thd = 2,2,6,6-Tetramethyl-3,5-heptanedione Muriel Fabre, Joël Jaud, Mohamed Hliwa, Jean-Pierre Launay, and Jacques Bonvoisin pp 9332 - 9345; DOI: 10.1021/ic061085t |
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Solid-State Coordination Chemistry of the Cu/Triazolate/X System (X = F-, Cl-, Br-, I-, OH-, and SO42-) Wayne Ouellette, Andrey V. Prosvirin, Vincent Chieffo, Kim R. Dunbar, Bruce Hudson, and Jon Zubieta pp 9346 - 9366; DOI: 10.1021/ic061102e |
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Conjugated Metallopolymers for Fluorescent Turn-On Detection of Nitric Oxide Rhett C. Smith, Andrew G. Tennyson, Annie C. Won, and Stephen J. Lippard pp 9367 - 9373; DOI: 10.1021/ic061099z |
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Crystal Structures and 77Se NMR Spectra of Molybdenum(IV) Areneselenolates Having Intramolecular NH···Se Hydrogen Bonds Taka-aki Okamura, Kaku Taniuchi, Keonil Lee, Hitoshi Yamamoto, Norikazu Ueyama, and Akira Nakamura pp 9374 - 9380; DOI: 10.1021/ic061140y |
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Structure and Thermoelectric Characterization of Ba8Al14Si31 Cathie L. Condron, J. Martin, G. S. Nolas, Paula M. B. Piccoli, Arthur J. Schultz, and Susan M. Kauzlarich pp 9381 - 9386; DOI: 10.1021/ic061241w |
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Electronic Structure and Charge Transfer in the Ternary Intercalated Graphite -KS0.25C3 Antonio Rodríguez-Fortea, Carme Rovira, Pablo Ordejón, Claire Hérold, Philippe Lagrange, and Enric Canadell pp 9387 - 9393; DOI: 10.1021/ic0612395 |
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Ferrocenyldiselenolate-Stabilized Copper-Selenium Clusters Christian Nitschke, Dieter Fenske, and John F. Corrigan pp 9394 - 9401; DOI: 10.1021/ic061111n |
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Synthesis of 1D {Cu6(3-SC3H6N2)4(-SC3H6N2)2(-I)2I4}n and 3D {Cu2(-SC3H6N2)2(-SCN)2}n Polymers with 1,3-Imidazolidine-2-thione: Bond Isomerism in Polymers Tarlok S. Lobana, Renu Sharma, Geeta Hundal, and R. J. Butcher pp 9402 - 9409; DOI: 10.1021/ic061115s |
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Deep-Red Luminescence and Efficient Singlet Oxygen Generation by Cyclometalated Platinum(II) Complexes with 8-Hydroxyquinolines and Quinoline-8-thiol Nail M. Shavaleev, Harry Adams, Jonathan Best, Ruth Edge, Suppiah Navaratnam, and Julia A. Weinstein pp 9410 - 9415; DOI: 10.1021/ic061283k |
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Copper(I) Coordination Chemistry of (Pyridylmethyl)amide Ligands Lei Yang and Robert P. Houser pp 9416 - 9422; DOI: 10.1021/ic0612810 |
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Mechanism of the Reactions of Synthetic Fe-S-Based Clusters with PhCOCl: Parallel Pathways Involving Free and Coordinated Thiolate as Nucleophiles Katie Bates, Lee Johnson, and Richard A. Henderson pp 9423 - 9433; DOI: 10.1021/ic0612707 |
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Computational Studies on the Photophysical Properties and NMR Fluxionality of the Tetranuclear Copper(I) Complexes [Cu4(-dppm)4(4-E)]2+ (E = PPh and S) Wai Han Lam, Eddie Chung-Chin Cheng, and Vivian Wing-Wah Yam pp 9434 - 9441; DOI: 10.1021/ic0612855 |
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Quantum Chemical Characterization of the Bonding of N-Heterocyclic Carbenes to Cp2MI Compounds [M = Ce(III), U(III)] Laura Gagliardi and Christopher J. Cramer pp 9442 - 9447; DOI: 10.1021/ic061306v |
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2D-Grid Layered Pd-Based Cationic Infinite Coordination Polymer/Polyoxometalate Crystal with Hydrophilic Sorption Kazuhiro Uehara, Hideaki Nakao, Ryosuke Kawamoto, Shiro Hikichi, and Noritaka Mizuno pp 9448 - 9453; DOI: 10.1021/ic061393r |
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Synthesis of Neutral (PdII, PtII), Cationic (PdII), and Water-Induced Anionic (PdII) Complexes Containing New Mesocyclic Benudhar Punji, Joel T. Mague, and Maravanji S. Balakrishna pp 9454 - 9464; DOI: 10.1021/ic061419e |
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A Dinuclear Lanthanide Complex for the Recognition of Bis(carboxylates): Formation of Terbium(III) Luminescent Self-Assembly Ternary Complexes in Aqueous Solution Andrew J. Harte, Paul Jensen, Sally E. Plush, Paul E. Kruger, and Thorfinnur Gunnlaugsson pp 9465 - 9474; DOI: 10.1021/ic0614418 |
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Synthesis and Magnetic Properties of an Amine-Templated Fe2+ (S = 2) Sulfate with a Distorted Kagome Structure J. N. Behera and C. N. R. Rao pp 9475 - 9479; DOI: 10.1021/ic061457y |
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An Isomeric Pair of Fluoride-Bridged Cyclic Dimolybdenum Triads F. Albert Cotton, Chun Y. Liu, Carlos A. Murillo, and Qinliang Zhao pp 9480 - 9486; DOI: 10.1021/ic061525g |
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Alkali-Metalated Forms of Thiacalix[4]arenes Jürgen Zeller and Udo Radius pp 9487 - 9492; DOI: 10.1021/ic0613311 |
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Strong Electronic Communication by Direct Metal-Metal Interaction in Molecules with Halide-Bridged Dimolybdenum Pairs F. Albert Cotton, Chun Y. Liu, Carlos A. Murillo, and Qinliang Zhao pp 9493 - 9501; DOI: 10.1021/ic061304a |
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Phosphate Ester Hydrolysis by Hydroxo Complexes of Trivalent Lanthanides Stabilized by 4-Imidazolecarboxylate Francisco Aguilar-Pérez, Paola Gómez-Tagle, Elisa Collado-Fregoso, and Anatoly K. Yatsimirsky pp 9502 - 9517; DOI: 10.1021/ic061024v |
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Electrochemistry and Homogeneous Self-Exchange Kinetics of the Aqueous 12-Tungstoaluminate(5-/6-) Couple Almut Czap, Nancy I. Neuman, and Thomas W. Swaddle pp 9518 - 9530; DOI: 10.1021/ic060527y |
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From Monomers to Solids: Controlled Hydrolysis To Form Novel, Heteroleptic Hydroxide-Containing Complexes Weijie Teng, Marites Guino-o, Julia Hitzbleck, Ulrich Englich, and Karin Ruhlandt-Senge pp 9531 - 9539; DOI: 10.1021/ic061119x |
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Kinetic Effects in Heterometallic Dinitrogen Cleavage Sean B. Seymore and Seth N. Brown pp 9540 - 9550; DOI: 10.1021/ic061153b |
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What External Perturbations Influence the Electronic Properties of Catalase Compound I? Sam P. de Visser pp 9551 - 9557; DOI: 10.1021/ic061019r |
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Synthesis, Characterization, and Reactivity of [Ru(bpy)(CH3CN)3(NO2)]PF6, a Synthon for [Ru(bpy)(L3)NO2] Complexes Daniel A. Freedman, Seth Kruger, Christina Roosa, and Chandra Wymer pp 9558 - 9568; DOI: 10.1021/ic061039t |
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Electrochemistry of Aluminum Phthalocyanine: Solvent and Anion Effects on UV-Visible Spectra and Reduction Mechanisms Zhongping Ou, Jing Shen, and Karl M. Kadish pp 9569 - 9579; DOI: 10.1021/ic061072f |
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Modulation of the Lowest Metal-to-Ligand Charge-Transfer State in [Ru(bpy)2(N-N)]2+ Systems by Changing the N-N from Hydrazone to Azine: Photophysical Consequences Maria Abrahamsson, Leif Hammarström, Derek A. Tocher, Samik Nag, and Dipankar Datta pp 9580 - 9586; DOI: 10.1021/ic061116k |
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Better Characterization of Surface Organometallic Catalysts through Resolution Enhancement in Proton Solid State NMR Spectra Frédéric Blanc, Christophe Copéret, Jean Thivolle-Cazat, Jean-Marie Basset, Anne Lesage, Lyndon Emsley, Amritanshu Sinha, and Richard R. Schrock pp 9587 - 9592; DOI: 10.1021/ic061222m |
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Trapping of Hemiquinone Radicals at Mo and P Sites by Phosphide-Bridged Dimolybdenum Species: Chemistry of Complexes [Mo2(5-C5H5)2(OC6H4OH)(-PR2)(CO)4] and [Mo2(5-C5H5)2{-PR(OC6H4OH)}(CO)4]- (R = Cy, Ph) Celedonio M. Alvarez, M. Angeles Alvarez, María Alonso, M. Esther García, M. Teresa Rueda, Miguel A. Ruiz, and Patrick Herson pp 9593 - 9606; DOI: 10.1021/ic061344e |
Issue 24
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Icosaniobate: A New Member of the Isoniobate Family Masaki Maekawa, Yoshiki Ozawa, and Atsushi Yagasaki pp 9608 - 9609; DOI: 10.1021/ic0601788 |
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True Blue: Blue-Emitting Aluminum(III) Quinolinolate Complexes César Pérez-Bolívar, Victor A. Montes, and Pavel Anzenbacher, Jr. pp 9610 - 9612; DOI: 10.1021/ic061051l |
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Cyanide-Bridged Single-Molecule Magnet Constructed by an Octacoordinated [W(CN)6(bpy)]- Anion Jung Hee Yoon, Jeong Hak Lim, Hyoung Chan Kim, and Chang Seop Hong pp 9613 - 9615; DOI: 10.1021/ic061651k |
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Size-Controllable Fabrication of Noble Metal Nanonets Using a TiO2 Template Lixia Yang, Qingyun Cai, and Yan Yu pp 9616 - 9618; DOI: 10.1021/ic061357s |
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Helicity Induction through Hydrogen Bonding and Spontaneous Resolution of a Bimetallic Nickel Complex Coordinated to an Octahedral Metalloligand Snehadrinarayan Khatua, Helen Stoeckli-Evans, Takunori Harada, Reiko Kuroda, and Manish Bhattacharjee pp 9619 - 9621; DOI: 10.1021/ic061226r |
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A Dinuclear Ni(II) Complex with Two Types of Intramolecular Magnetic Couplings: Ni(II)-Ni(II) and Ni(II)-TTF+ Shi-Xia Liu, Christina Ambrus, Stefan Dolder, Antonia Neels, and Silvio Decurtins pp 9622 - 9624; DOI: 10.1021/ic0613614 |
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Antimony-Antimony Bond Formation by Reductive Elimination from a Hafnium Bis(stibido) Complex Rory Waterman and T. Don Tilley pp 9625 - 9627; DOI: 10.1021/ic061826q |
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Where Are the Protons in -[HxW12O40](8-x)- (x = 2-4)? Calvin R. Sprangers, Jason K. Marmon, and Dean C. Duncan pp 9628 - 9630; DOI: 10.1021/ic061370c |
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Mechanism of Direct Molecular Oxygen Insertion in a Palladium(II)-Hydride Bond Jason M. Keith, Richard P. Muller, Richard A. Kemp, Karen I. Goldberg, William A. Goddard, III, and Jonas Oxgaard pp 9631 - 9633; DOI: 10.1021/ic061392z |
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Synthesis and Thermal Decomposition of Zn(tda)H2O [tda = S(CH2COO)22-] Ming-Cheng Wu and Chi-Shen Lee pp 9634 - 9636; DOI: 10.1021/ic061531c |
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[Me4N](NiII(BEAAM)): A Synthetic Model for Nickel Superoxide Dismutase That Contains Ni in a Mixed Amine/Amide Coordination Environment Jason Shearer and Ningfeng Zhao pp 9637 - 9639; DOI: 10.1021/ic061604s |
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Prediction of Anion Distributions Using Pauling's Second Rule Amparo Fuertes pp 9640 - 9642; DOI: 10.1021/ic061640r |
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Redox-Controlled Molecular Flipper Based on a Chiral Cu Complex Anna Company, Mireia Güell, Dana Popa, Jordi Benet-Buchholz, Teodor Parella, Xavier Fontrodona, Antoni Llobet, Miquel Solà, Xavi Ribas, Josep M. Luis, and Miquel Costas pp 9643 - 9645; DOI: 10.1021/ic0618549 |
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Electron Transfer and Ligand Addition to Atomic Mercury Cations in the Gas Phase: Kinetic and Equilibrium Studies at 295 K Xiang Zhao, Eric Flaim, Lise Huynh, Michael J. Y. Jarvis, Ping Cheng, Vitali V. Lavrov, Voislav Blagojevic, Gregory K. Koyanagi, and Diethard K. Bohme pp 9646 - 9653; DOI: 10.1021/ic060195x |
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Synthesis, Structure, and Electrochemical Properties of a Family of 2-(Arylazo)phenolate Complexes of Ruthenium with Unusual C-C Coupling and N=N Cleavage Sarmistha Halder, Rama Acharyya, Shie-Ming Peng, Gene-Hsiang Lee, Michael G. B. Drew, and Samaresh Bhattacharya pp 9654 - 9663; DOI: 10.1021/ic060689u |
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Metal-Biradical Chains from a High-Spin Ligand and Bis(hexafluoroacetylacetonato)copper(II) Chandrasekar Rajadurai, Volker Enkelmann, Vladimir Ikorskii, Victor I. Ovcharenko, and Martin Baumgarten pp 9664 - 9669; DOI: 10.1021/ic060197h |
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Pressure Effect and Crystal Structure Reinvestigations on the Spin Crossover System: [Fe(bt)2(NCS)2] (bt = 2,2'-Bithiazoline) Polymorphs A and B Ana Galet, Ana Belén Gaspar, M. Carmen Muñoz, Georgii Levchenko, and José Antonio Real pp 9670 - 9679; DOI: 10.1021/ic060729u |
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2D and 3D Supramolecular Structures via Hydrogen Bonds and -Stacking Interactions in Arylsulfonates of Nickel and Cobalt Felipe Gándara, Carlos Fortes-Revilla, Natalia Snejko, Enrique Gutiérrez-Puebla, Marta Iglesias, and M. Angeles Monge pp 9680 - 9687; DOI: 10.1021/ic060897m |
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Synthesis, Cytotoxic Effect, and Structure-Activity Relationship of Pd(II) Complexes with Coumarin Derivatives El bieta Budzisz, Magdalena Maecka, Ingo-Peter Lorenz, Peter Mayer, Renata A. Kwiecie, Piotr Paneth, Urszula Krajewska, and Marek Rózalskipp 9688 - 9695; DOI: 10.1021/ic0605569 |
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CsR(R6CoI12)2 (R = Gd, Er) and (CeI)0.26(Ce6MnI9)2: Two New Structure Types Featuring R6Z Clusters Lucas E. Sweet and Timothy Hughbanks pp 9696 - 9702; DOI: 10.1021/ic060439d |
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Electronic Modulation of Hyperpolarizable (Porphinato)zinc(II) Chromophores Featuring Ethynylphenyl-, Ethynylthiophenyl-, Ethynylthiazolyl-, and Ethynylbenzothiazolyl-Based Electron-Donating and -Accepting Moieties Tian-Gao Zhang, Yuxia Zhao, Kai Song, Inge Asselberghs, André Persoons, Koen Clays, and Michael J. Therien pp 9703 - 9712; DOI: 10.1021/ic060898e |
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A Tris(pyrazolyl) 6-Arene Ligand That Selects Cu(I) over Cu(II) Robert T. Stibrany, Chengmin Zhang, Thomas J. Emge, Harvey J. Schugar, Joseph A. Potenza, and Spencer Knapp pp 9713 - 9720; DOI: 10.1021/ic060980+ |
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Low-Spin Bis(2-methylimidazole)(octaethylporphyrinato)iron(III) Chloride (perp-[Fe(OEP)(2-MeHIm)2]Cl): A Consequence of Hydrogen Bonding? Chuanjiang Hu, Bruce C. Noll, Charles E. Schulz, and W. Robert Scheidt pp 9721 - 9728; DOI: 10.1021/ic061014u |
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Photophysical Properties of Ruthenium(II) Tris(2,2'-bipyridine) Complexes Bearing Conjugated Thiophene Appendages Anthony Harriman, Guillaume Izzet, Sébastien Goeb, Antoinette De Nicola, and Raymond Ziessel pp 9729 - 9741; DOI: 10.1021/ic060921w |
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Iron Complexes of C- and N-Methylated 2-Aza-21-carbaporphyrin: NMR Studies Krystyna Rachlewicz, Dominik Gorzela czyk, and Lechosaw Latos-Grayskipp 9742 - 9747; DOI: 10.1021/ic061092h |
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Midrange Affinity Fluorescent Zn(II) Sensors of the Zinpyr Family: Syntheses, Characterization, and Biological Imaging Applications Elizabeth M. Nolan, Jacek Jaworski, Maryann E. Racine, Morgan Sheng, and Stephen J. Lippard pp 9748 - 9757; DOI: 10.1021/ic061137e |
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SHG Active Crystals of a Remote Functionalized Achiral NLO-phore Assembled through Zinc(II) Complexation M. Jaya Prakash and T. P. Radhakrishnan pp 9758 - 9764; DOI: 10.1021/ic061145v |
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Molecular Pairs and A Propeller Containing Quadruply Bonded Dimolybdenum Units Linked by Polyamidate Ligands F. Albert Cotton, Zhong Li, Chun Y. Liu, and Carlos A. Murillo pp 9765 - 9770; DOI: 10.1021/ic0614723 |
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Removing the Sting from the Tail: Reversible Protonation of Scorpionate Ligands in Cobalt(II) Tris(carbene)borate Complexes Ryan E. Cowley, Ranko P. Bontchev, Eileen N. Duesler, and Jeremy M. Smith pp 9771 - 9779; DOI: 10.1021/ic061299a |
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Rational Design of 0D, 1D, and 3D Open Frameworks Based on Tetranuclear Lanthanide(III) Sulfonate-Phosphonate Clusters Zi-Yi Du, Hai-Bing Xu, and Jiang-Gao Mao pp 9780 - 9788; DOI: 10.1021/ic0613255 |
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Electronic Structure and Excited States of Rhenium(I) Amido and Phosphido Carbonyl-Bipyridine Complexes Studied by Picosecond Time-Resolved IR Spectroscopy and DFT Calculations Anders Gabrielsson, Michael Busby, Pavel Matousek, Michael Towrie, Eva Hevia, Luciano Cuesta, Julio Perez, Stanislav Záli , and Antonín Vlek, Jr.pp 9789 - 9797; DOI: 10.1021/ic0614768 |
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Metal Binding to Bipyridine-Modified PNA Raphael M. Franzini, Richard M. Watson, Goutam K. Patra, Robert M. Breece, David L. Tierney, Michael P. Hendrich, and Catalina Achim pp 9798 - 9811; DOI: 10.1021/ic0609610 |
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Mixed-Valent Selenidoantimonates(III,V) with Transition-Metal Complexes as Counterions: Solvothermal Syntheses and Characterization of [M(dien)2]2Sb4Se9 (M = Mn, Fe), [Co(dien)2]2Sb2Se6, and [Ni(dien)2]2Sb2Se5 Dingxian Jia, Yong Zhang, Qianxin Zhao, and Jie Deng pp 9812 - 9817; DOI: 10.1021/ic061520j |
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Pressure-Induced Internal Redox Reaction of Cs2[PdI4]·I2, Cs2[PdBr4]·I2, and Cs2[PdCl4]·I2 Peter Heines, Hans-Lothar Keller, Marc Armbrüster, Ulrich Schwarz, and John Tse pp 9818 - 9825; DOI: 10.1021/ic0601945 |
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Extremely Long Axial Cu-N Bonds in Chiral One-Dimensional Zigzag Cyanide-Bridged CuII-NiII and CuII-PtII Bimetallic Assemblies Takashiro Akitsu and Yasuaki Einaga pp 9826 - 9833; DOI: 10.1021/ic060783a |
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Synthesis and Characterization of Water-Operative Cationic and Anionic Metal-Ion Activated Molecular Receptors for Aromatic Anions Akhmad Damsyik, Stephen F. Lincoln, and Kevin P. Wainwright pp 9834 - 9842; DOI: 10.1021/ic060793b |
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Oxo- and Oxoperoxo-molybdenum(VI) Complexes with Aryl Hydroxamates: Synthesis, Structure, and Catalytic Uses in Highly Efficient, Selective, and Ecologically Benign Peroxidic Epoxidation of Olefins Swarup K. Maiti, K. M. Abdul Malik, Shalabh Gupta, Santu Chakraborty, Ashok K. Ganguli, Alok K. Mukherjee, and Ramgopal Bhattacharyya pp 9843 - 9857; DOI: 10.1021/ic0607235 |
Electron Deficient Carbon-Titanium Triple Bonds: Formation of Triplet XC TiX3 Methylidyne ComplexesJonathan T. Lyon and Lester Andrews pp 9858 - 9863; DOI: 10.1021/ic0610379 |
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A Systematic Resolution of Sulfur in Reticulated Vitreous Carbon Using X-ray Absorption Spectroscopy Patrick Frank, Serena DeBeer George, Elodie Anxolabéhère-Mallart, Britt Hedman, and Keith O. Hodgson pp 9864 - 9876; DOI: 10.1021/ic0610637 |
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Three Autocatalysts and Self-Inhibition in a Single Reaction: A Detailed Mechanism of the Chlorite-Tetrathionate Reaction Attila K. Horváth, István Nagypál, and Irving R. Epstein pp 9877 - 9883; DOI: 10.1021/ic061332t |
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Reactivity and Equilibrium Thermodynamic Studies of Rhodium Tetrakis(3,5-disulfonatomesityl)porphyrin Species with H2, CO, and Olefins in Water Xuefeng Fu, Shan Li, and Bradford B. Wayland pp 9884 - 9889; DOI: 10.1021/ic0615022 |
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Spacially Confined M2 Centers (M = Fe, Co, Ni, Zn) on a Sterically Bulky Binucleating Support: Synthesis, Structures and Ethylene Oligomerization Studies Yohan D. M. Champouret, John Fawcett, William J. Nodes, Kuldip Singh, and Gregory A. Solan pp 9890 - 9900; DOI: 10.1021/ic061286x |
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Absorption, Light Emission, and Upconversion Properties of Tm2+-Doped CsCaI3 and RbCaI3 Eva Beurer, Judith Grimm, Pascal Gerner, and Hans U. Güdel pp 9901 - 9906; DOI: 10.1021/ic061340+ |
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Lanthanide and Uranium Complexes with an SPS-Based Pincer Ligand Thérèse Arliguie, Marjolaine Doux, Nicolas Mézailles, Pierre Thuéry, Pascal Le Floch, and Michel Ephritikhine pp 9907 - 9913; DOI: 10.1021/ic061364g |
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Mono{hydrotris(mercaptoimidazolyl)borato} Complexes of Manganese(II), Iron(II), Cobalt(II), and Nickel(II) Halides Shunsuke Senda, Yasuhiro Ohki, Tomoko Hirayama, Daisuke Toda, Jing-Lin Chen, Tsuyoshi Matsumoto, Hiroyuki Kawaguchi, and Kazuyuki Tatsumi pp 9914 - 9925; DOI: 10.1021/ic0610132 |
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High-Frequency and -Field EPR Spectroscopy of Tris(2,4-pentane-dionato)manganese(III): Investigation of Solid-State Versus Solution Jahn-Teller Effects J. Krzystek, Gregory J. Yeagle, Ju-Hyun Park, R. David Britt, Mark W. Meisel, Louis-Claude Brunel, and Joshua Telser: pp 9926 - 9926; DOI: 10.1021/ic061967s |
Issue 25
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Preface: Forum on Biomolecular Design in Inorganic Chemistry Brian R. Gibney and Sonya J. Franklin pp 9927 - 9929; DOI: 10.1021/ic0617846 |
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Metalloprotein and Metallo-DNA/RNAzyme Design: Current Approaches, Success Measures, and Future Challenges Yi Lu pp 9930 - 9940; DOI: 10.1021/ic052007t |
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Femtomolar Zn(II) Affinity in a Peptide-Based Ligand Designed To Model Thiolate-Rich Metalloprotein Active Sites Amy K. Petros, Amit R. Reddi, Michelle L. Kennedy, Alison G. Hyslop, and Brian R. Gibney pp 9941 - 9958; DOI: 10.1021/ic052190q |
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Assessing the Integrity of Designed Homomeric Parallel Three-Stranded Coiled Coils in the Presence of Metal Ions Olga Iranzo, Debdip Ghosh, and Vincent L. Pecoraro pp 9959 - 9973; DOI: 10.1021/ic061183e |
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Incorporating Electron-Transfer Functionality into Synthetic Metalloproteins from the Bottom-up Jing Hong, Olesya A. Kharenko, and Michael Y. Ogawa pp 9974 - 9984; DOI: 10.1021/ic060222j |
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Insight into Heme Protein Redox Potential Control and Functional Aspects of Six-Coordinate Ligand-Sensing Heme Proteins from Studies of Synthetic Heme Peptides Aaron B. Cowley, Michelle L. Kennedy, Svetlana Silchenko, Gudrun S. Lukat-Rodgers, Kenton R. Rodgers, and David R. Benson pp 9985 - 10001; DOI: 10.1021/ic052205k |
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Of Folding and Function: Understanding Active-Site Context through Metalloenzyme Design Kinesha L. Harris, Sunghyuk Lim, and Sonya J. Franklin pp 10002 - 10012; DOI: 10.1021/ic060877k |
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A "Turn-On" Fluorescent Sensor for Selective Hg(II) Detection in Aqueous Media Based on Metal-Induced Dye Formation Yonggang Zhao, Zhihua Lin, Cheng He, Hongmei Wu, and Chunying Duan pp 10013 - 10015; DOI: 10.1021/ic061067b |
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Frequency-Switching Inversion-Recovery for Severely Hyperfine-Shifted NMR: Evidence of Asymmetric Electron Relaxation in High-Spin Co(II) Erin A. Riley, Amy K. Petros, Karen Ann Smith, Brian R. Gibney, and David L. Tierney pp 10016 - 10018; DOI: 10.1021/ic061207h |
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Spin Transition in a Chainlike Supramolecular Iron(II) Complex Chandrasekar Rajadurai, Frank Schramm, Susan Brink, Olaf Fuhr, Mohamed Ghafari, Robert Kruk, and Mario Ruben pp 10019 - 10021; DOI: 10.1021/ic0612350 |
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Using LnIII[15-MCCuII(N)(S)-pheHA-5]3+ Complexes To Construct Chiral Single-Molecule Magnets and Chains of Single-Molecule Magnets Curtis M. Zaleski, Ezra C. Depperman, Jeff W. Kampf, Martin L. Kirk, and Vincent L. Pecoraro pp 10022 - 10024; DOI: 10.1021/ic061326x |
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Metal Chelate Formation Using a Task-Specific Ionic Liquid Jitendra R. Harjani, Tomislav Fri i, Leonard R. MacGillivray, and Robert D. Singerpp 10025 - 10027; DOI: 10.1021/ic061479k |
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[(H2en)7(C2O4)2]n(Pb4I18)n·4nH2O, a New Type of Perovskite Co-templated by Both Organic Cations and Anions Zhang-Jing Zhang, Guo-Cong Guo, Gang Xu, Ming-Lai Fu, Jian-Ping Zou, and Jin-Shun Huang pp 10028 - 10030; DOI: 10.1021/ic061555j |
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Crystal Structure and DNA Interaction of the Facial-Type rac-Tris[2-(aminomethyl)benzimidazole]cobalt(III) Complex Jordi Gómez-Segura, María José Prieto, Mercè Font-Bardia, Xavier Solans, and Virtudes Moreno pp 10031 - 10033; DOI: 10.1021/ic061292t |
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Monohelical Iron(II) and Zinc(II) Complexes of a (1R,2R)-Cyclohexyl Salen Ligand with Benz[a]anthryl Sidearms Alexander V. Wiznycia, John Desper, and Christopher J. Levy pp 10034 - 10036; DOI: 10.1021/ic061553z |
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A New Approach to Functionalize an Organic Compound through the Influence of Metal Bis(dithiolene) Complexes Leading to Ion-Pair Compounds Exhibiting Strong Emission at Room Temperature in the Visible Region Vedichi Madhu and Samar K. Das pp 10037 - 10039; DOI: 10.1021/ic0615980 |
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Sensitized Near-Infrared Lanthanide Luminescence from Nd(III)- and Yb(III)-Based Cyclen-Ruthenium Coordination Conjugates Katell Sénéchal-David, Simon J. A. Pope, Susan Quinn, Stephen Faulkner, and Thorfinnur Gunnlaugsson pp 10040 - 10042; DOI: 10.1021/ic061706i |
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Tetra-, Di-, and Mononuclear Copper(I) Complexes Containing (S,S)-iPr-pybox and (R,R)-Ph-pybox Ligands Josefina Díez, M. Pilar Gamasa, and María Panera pp 10043 - 10045; DOI: 10.1021/ic061453t |
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A Perfect Linear Cu-NNN-Cu Unit Inside the Cryptand Cavity and Perchlorate Entrapment within the Channel Formed by the Cascade Complex I. Ravikumar, E. Suresh, and Pradyut Ghosh pp 10046 - 10048; DOI: 10.1021/ic061450g |
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Synthesis, Structural Characterization, and Properties of Aluminum (III) meso-Tetraphenylporphyrin Complexes Axially Bonded to Phosphinate Anions Sébastien Richeter, Julien Thion, Arie van der Lee, and Dominique Leclercq pp 10049 - 10051; DOI: 10.1021/ic0617801 |
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Gondola-Shaped Luminescent Tetrarhenium Metallacycles with Crown-Ether-like Multiple Recognition Sites Malaichamy Sathiyendiran, Rong-Tang Liao, P. Thanasekaran, Tzuoo-Tsair Luo, N. S. Venkataramanan, Gene-Hsiang Lee, Shie-Ming Peng, and Kuang-Lieh Lu pp 10052 - 10054; DOI: 10.1021/ic061886w |
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Dioxygen Reactivity of a Copper(I) Complex with a N3S Thioether Chelate; Peroxo-Dicopper(II) Formation Including Sulfur-Ligation Lanying Q. Hatcher, Dong-Heon Lee, Michael A. Vance, Ashley E. Milligan, Ritimukta Sarangi, Keith O. Hodgson, Britt Hedman, Edward I. Solomon, and Kenneth D. Karlin pp 10055 - 10057; DOI: 10.1021/ic061813c |
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Structural and Magnetic Studies on Cyano-Bridged Rectangular Fe2M2 (M = Cu, Ni) Clusters Wei Liu, Cai-Feng Wang, Yi-Zhi Li, Jing-Lin Zuo, and Xiao-Zeng You pp 10058 - 10065; DOI: 10.1021/ic061347r |
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Trinuclear Copper(II) Complexes Derived from Schiff-Base Ligands Based on a 6-Amino-6-deoxyglucopyranoside: Structural and Magnetic Characterization Arne Roth, Jana Becher, Carmen Herrmann, Helmar Görls, Gavin Vaughan, Markus Reiher, Dieter Klemm, and Winfried Plass pp 10066 - 10076; DOI: 10.1021/ic0605064 |
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Silver(I) Complexes of Fixed, Polytopic Bis(pyrazolyl)methane Ligands: Influence of Ligand Geometry on the Formation of Discrete Metallacycles and Coordination Polymers Daniel L. Reger, Russell P. Watson, and Mark D. Smith pp 10077 - 10087; DOI: 10.1021/ic0613053 |
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Metallacycles of Iron, Zinc, and Cadmium Assembled by Polytopic Bis(pyrazolyl)methane Ligands and Fluoride Abstraction from BF4- Daniel L. Reger, Russell P. Watson, James R. Gardinier, Mark D. Smith, and Perry J. Pellechia pp 10088 - 10097; DOI: 10.1021/ic0613154 |
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Thioether Sulfur Oxygenation from O2 or H2O2 Reactivity of Copper Complexes with Tridentate N2Sthioether Ligands Yunho Lee, Dong-Heon Lee, Amy A. Narducci Sarjeant, Lev N. Zakharov, Arnold L. Rheingold, and Kenneth D. Karlin pp 10098 - 10107; DOI: 10.1021/ic060730t |
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Kinetics and Mechanism of the Oxidation of Guanosine Derivatives by Pt(IV) Complexes Sunhee Choi, Livia Vastag, Chin-Hin Leung, Adam M. Beard, Darcy E. Knowles, and James A. Larrabee pp 10108 - 10114; DOI: 10.1021/ic061243g |
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Lanthanide-Transition Metal Carbonyl Complexes: Condensation of Solvent-Separated Ion-Pair Compounds into Extended Structures Pavel V. Poplaukhin, Xuenian Chen, Edward A. Meyers, and Sheldon G. Shore pp 10115 - 10125; DOI: 10.1021/ic060756k |
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[Na5(THF)10Ce(mnt)4]: A Honeycomb Network Polymer That Yields Homoleptic Cerium(III) Tetrakis(Dithiolene) Complexes in Donor Solvents Eric M. Weis, Charles L. Barnes, and Paul B. Duval pp 10126 - 10130; DOI: 10.1021/ic060779z |
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Photosensitizers Containing the 1,8-Naphthyridyl Moiety and Their Use in Dye-Sensitized Solar Cells Ahmet Kukrek, Dong Wang, Yuanjun Hou, Ruifa Zong, and Randolph Thummel pp 10131 - 10137; DOI: 10.1021/ic061022a |
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Eu(III) and Tb(III) Luminescence Sensitized by Thiophenyl-Derivatized Nitrobenzoato Antennas Subha Viswanathan and Ana de Bettencourt-Dias pp 10138 - 10146; DOI: 10.1021/ic061272r |
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New Heterobimetallic and Polymeric Selenocarboxylates Derived from [M(SeC{O}Ph)4]- (M = Ga and In) as Molecular Precursors for Ternary Selenides Meng Tack Ng and Jagadese J. Vittal pp 10147 - 10154; DOI: 10.1021/ic0611286 |
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Synthesis and Crystal Structures of Multidimensional Coordination Polymers Based on W/Cu/S Clusters with Flexible Imidazole Ligands Li Song, Jianrong Li, Ping Lin, Zhihua Li, Tao Li, Shaowu Du, and, and Xintao Wu pp 10155 - 10161; DOI: 10.1021/ic061142i |
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Preparation and Characterization of Novel Os-Diolefin Dimers: New Entry to Os-Cyclooctadiene Complexes Miguel A. Esteruelas, Cristina García-Yebra, Montserrat Oliván, and Enrique Oñate pp 10162 - 10171; DOI: 10.1021/ic0612799 |
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Tricarboranyl Pentaerythritol-Based Building Block Alexis Mollard and Ilya Zharov pp 10172 - 10179; DOI: 10.1021/ic061297q |
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Dinuclear Gold(I) Isocyanide Complexes with Luminescent Properties, and Displaying Thermotropic Liquid Crystalline Behavior Silverio Coco, Carlos Cordovilla, Pablo Espinet, José Martín-Álvarez, and Paula Muñoz pp 10180 - 10187; DOI: 10.1021/ic060702a |
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En Route to the Formation of High-Efficiency, Osmium(II)-Based Phosphorescent Materials Fang-Chi Hsu, Yung-Liang Tung, Yun Chi, Cheng-Chih Hsu, Yi-Ming Cheng, Mei-Lin Ho, Pi-Tai Chou, Shie-Ming Peng, and Arthur J. Carty pp 10188 - 10196; DOI: 10.1021/ic061301y |
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[Mn7O5(OR)2(O2CPh)9(terpy)] (R = Me, CH2Ph) Complexes with a Fused Cubane/Butterfly Core and an S = 6 Ground-State Spin Abhudaya Mishra, Wolfgang Wernsdorfer, Khalil A. Abboud, and George Christou pp 10197 - 10206; DOI: 10.1021/ic061334d |
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New Layered Uranium Phosphate Fluorides: Syntheses, Structures, Characterizations, and Ion-Exchange Properties of A(UO2)F(HPO4)·xH2O (A = Cs+, Rb+, K+; x = 0-1) Kang Min Ok, Jaewook Baek, P. Shiv Halasyamani, and Dermot O'Hare pp 10207 - 10214; DOI: 10.1021/ic061420d |
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Multinuclear High-Resolution NMR Study of Compounds from the Ternary System NaF-CaF2-AlF3: from Determination to Modeling of NMR Parameters C. Martineau, M. Body, C. Legein, G. Silly, J.-Y. Buzaré, and F. Fayon pp 10215 - 10223; DOI: 10.1021/ic061348j |
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Magnetic Properties of BiMnO3 Studied with Dc and Ac Magnetization and Specific Heat Alexei A. Belik and Eiji Takayama-Muromachi pp 10224 - 10229; DOI: 10.1021/ic061400b |
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Synthesis and Vibrational Circular Dichroism of Enantiopure Chiral Oxorhenium(V) Complexes Containing the Hydrotris(1-pyrazolyl)borate Ligand Peter R. Lassen, Laure Guy, Iyad Karame, Thierry Roisnel, Nicolas Vanthuyne, Christian Roussel, Xiaolin Cao, Rosina Lombardi, Jeanne Crassous, Teresa B. Freedman, and Laurence A. Nafie pp 10230 - 10239; DOI: 10.1021/ic061418m |
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Enhancement of the Curie Temperature by Isomerization of Diarylethene (DAE) for an Organic-Inorganic Hybrid System: Co4(OH)7(DAE)0.5·3H2O H. Shimizu, M. Okubo, A. Nakamoto, M. Enomoto, and N. Kojima pp 10240 - 10247; DOI: 10.1021/ic061498u |
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Dihydrogen to Dihydride Isomerization Mechanism in [(C5Me5)FeH2(Ph2PCH2CH2PPh2)]+ through the Experimental and Theoretical Analysis of Kinetic Isotope Effects Miguel Baya, Olivier Maresca, Rinaldo Poli, Yannick Coppel, Feliu Maseras, Agustí Lledós, Natalia V. Belkova, Pavel A. Dub, Lina M. Epstein, and Elena S. Shubina pp 10248 - 10262; DOI: 10.1021/ic061428n |
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Computational Study of Iron(II) and -(III) Complexes with a Simple Model Human H Ferritin Ferroxidase Center Daniel E. Bacelo and R. C. Binning Jr. pp 10263 - 10269; DOI: 10.1021/ic060388k |
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Electrical Conducting Bis(Oxalato)platinate Complex with Direct Connection of CuII Ions Chihiro Yamamoto, Hiroyuki Nishikawa, Masayuki Nihei, Takuya Shiga, Masato Hedo, Yoshiya Uwatoko, Hiroshi Sawa, Hiroshi Kitagawa, Yasujiro Taguchi, Yoshihiro Iwasa, and Hiroki Oshio pp 10270 - 10276; DOI: 10.1021/ic0607742 |
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Cation-Cation Interactions in Sr5(UO2)20(UO6)2O16(OH)6(H2O)6 and Cs(UO2)9U3O16(OH)5 Karrie-Ann Kubatko and Peter C. Burns pp 10277 - 10281; DOI: 10.1021/ic0609453 |
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Synthesis, Characterization, and DNA-Binding Studies of Nitro(oligopyridine)ruthenium(II) Complexes Konstantina Karidi, Achilleas Garoufis, Nick Hadjiliadis, Martin Lutz, Anthony L. Spek, and Jan Reedijk pp 10282 - 10292; DOI: 10.1021/ic0608039 |
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A Chelate-Stabilized Ruthenium(-pyrrolato) Complex: Resolving Ambiguities in Nuclearity and Coordination Geometry through 1H PGSE and 31P Solid-State NMR Studies Heather M. Foucault, David L. Bryce, and Deryn E. Fogg pp 10293 - 10299; DOI: 10.1021/ic061021i |
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The Influence of Phosphane Coligands on the Nuclearity of Rhodium(I) 4-Thiolatobenzoic Acid Complexes Ulrike Helmstedt, Peter Lönnecke, and Evamarie Hey-Hawkins pp 10300 - 10308; DOI: 10.1021/ic0610684 |
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Mononucleating Bis(-diketonate) Ligands and Their Titanium(IV) Complexes Vesela Ugrinova, Bruce C. Noll, and Seth N. Brown pp 10309 - 10320; DOI: 10.1021/ic061201s |
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Homoleptic Complexes of Cobalt(0) and Nickel(0,I) with 1,1'-Bis(diphenylphosphino)ferrocene (dppf): Synthesis and Characterization Giuseppe Pilloni, Antonio Toffoletti, Giuliano Bandoli, and Bruno Longato pp 10321 - 10328; DOI: 10.1021/ic061185z |
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Role of Donor and Secondary Interactions in the Structures and Thermal Properties of Alkaline-Earth and Rare-Earth Metal Pyrazolates Julia Hitzbleck, Anna Y. O'Brien, Glen B. Deacon, and Karin Ruhlandt-Senge pp 10329 - 10337; DOI: 10.1021/ic061294d |
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-Monodeuterated Benzyl Alcohols and Phosphobetaines from Reactions of Aromatic Aldehydes with a Water/D2O-Soluble Phosphine Dmitry V. Moiseev, Brian R. James, and Thomas Q. Hu pp 10338 - 10346; DOI: 10.1021/ic0613560 |
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Stoichiometric and Catalytic Secondary O-Atom Transfer by Fe(III)-NO2 Complexes Derived from a Planar Tetradentate Non-heme Ligand: Reminiscence of Heme Chemistry Raman K. Afshar, Aura A. Eroy-Reveles, Marilyn M. Olmstead, and Pradip K. Mascharak pp 10347 - 10354; DOI: 10.1021/ic0614115 |
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Multifrequency EPR and Redox Reactivity Investigations of a Bis(-thiolato)-dicopper(II,II) Complex Wassim Rammal, Catherine Belle, Claude Béguin, Carole Duboc, Christian Philouze, Jean-Louis Pierre, Laurent Le Pape, Sylvain Bertaina, Eric Saint-Aman, and Stéphane Torelli pp 10355 - 10362; DOI: 10.1021/ic0612606 |
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Supramolecular Structures and Columnar Mesophase Induction in Nondiscoid Pyrazoles by Complexation to Rhodium(I) Raquel Giménez, Anabel Elduque, José Antonio López, Joaquín Barberá, Emma Cavero, Ignacio Lantero, Luis A. Oro, and José Luis Serrano pp 10363 - 10370; DOI: 10.1021/ic0614216 |
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Luminescent Hepta- and Tetradecanuclear Complexes of 5,5'-Diethynyl-2,2'-bipyridine Capped with Triangular Trinuclear Cu3/Ag3 Cluster Units Qiao-Hua Wei, Gang-Qiang Yin, Li-Yi Zhang, and Zhong-Ning Chen pp 10371 - 10377; DOI: 10.1021/ic061448p |
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Relevance of the Ligand Exchange Rate and Mechanism of fac-[(CO)3M(H2O)3]+ (M = Mn, Tc, Re) Complexes for New Radiopharmaceuticals Pascal V. Grundler, Lothar Helm, Roger Alberto, and André E. Merbach pp 10378 - 10390; DOI: 10.1021/ic061578y |
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Synthesis and Catalytic Epoxidation Activity with TBHP and H2O2 of Dioxo-, Oxoperoxo-, and Oxodiperoxo Molybdenum(VI) and Tungsten(VI) Compounds Containing Monodentate or Bidentate Phosphine Oxide Ligands: Crystal Structures of WCl2(O)2(OPMePh2)2, WCl2(O)(O2)(OPMePh2)2, MoCl2(O)2dppmO2·C4H10O, WCl2(O)2dppmO2, Mo(O)(O2)2dppmO2, and W(O)(O2)2dppmO2 Ampa Jimtaisong and Rudy L. Luck pp 10391 - 10402; DOI: 10.1021/ic061455d |
Issue 26
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Three-Dimensional Heterometallic Chiral Cr-Mn Compound Constructed by Cyanide and Dicyanamide Bridges Yuan-Zhu Zhang, Zhe-Ming Wang, and Song Gao pp 10404 - 10406; DOI: 10.1021/ic0612092 |
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A Supercooled Imidazolium Iodide Ionic Liquid as a Low-Viscosity Electrolyte for Dye-Sensitized Solar Cells Zhaofu Fei, Daibin Kuang, Dongbin Zhao, Cedric Klein, Wee Han Ang, Shaik M. Zakeeruddin, Michael Grätzel, and Paul J. Dyson pp 10407 - 10409; DOI: 10.1021/ic061232n |
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Sodium Zinc Hydroxide Sulfite with a Novel Zn3OH Geometry Dan-Tam Nguyen and Xianhui Bu pp 10410 - 10412; DOI: 10.1021/ic061672e |
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A Multifunctional Tetrametallic Ru-Pt Supramolecular Complex Exhibiting Both DNA Binding and Photocleavage Ran Miao, Matthew T. Mongelli, David F. Zigler, Brenda S. J. Winkel, and Karen J. Brewer pp 10413 - 10415; DOI: 10.1021/ic061252p |
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Visible-Light-Sensitized Near-Infrared Luminescence from Rare-Earth Complexes of the 9-Hydroxyphenalen-1-one Ligand Rik Van Deun, Pascal Fias, Peter Nockemann, Kristof Van Hecke, Luc Van Meervelt, and Koen Binnemans pp 10416 - 10418; DOI: 10.1021/ic0616277 |
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Uranyl Complexation by Chloride Ions. Formation of a Tetrachlorouranium(VI) Complex in Room Temperature Ionic Liquids [Bmim][Tf2N] and [MeBu3N][Tf2N] M.-O. Sornein, C. Cannes, C. Le Naour, G. Lagarde, E. Simoni, and J.-C. Berthet pp 10419 - 10421; DOI: 10.1021/ic061751q |
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A Novel Hexatungstate Fragment Stabilized by Dimethyltin Groups: [{(CH3)2Sn}2(W6O22)]4- Santiago Reinoso, Michael H. Dickman, and Ulrich Kortz pp 10422 - 10424; DOI: 10.1021/ic0619862 |
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[Ln2(C2O4)2(pyzc)2(H2O)2]n [Ln = Pr (1), Er (2)]: Novel Two-Dimensional Lanthanide Coordination Polymers with 2-Pyrazinecarboxylate and Oxalate Bing Li, Wen Gu, Li-Zhi Zhang, Jie Qu, Zhen-Ping Ma, Xin Liu, and Dai-Zheng Liao pp 10425 - 10427; DOI: 10.1021/ic061287p |
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Unprecedented Formation of a Rhodium Cluster Triggered by Rhodium-Fastened N-Confused Gable Porphyrin Motoki Toganoh, Teppei Niino, Hiromitsu Maeda, Bruno Andrioletti, and Hiroyuki Furuta pp 10428 - 10430; DOI: 10.1021/ic061741p |
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A Singular Noninterpenetrating Coordination Polymer with the Pt3O4 Structure Containing Naked [Na+]4 Units Ana B. Gaspar, Ana Galet, M. Carmen Muñoz, Xavier Solans, and José Antonio Real pp 10431 - 10433; DOI: 10.1021/ic061797j |
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Dancing of Palladacycles around a "Juggler" 2,2-Diacetyl-1,1-Ethylenedithiolato Ligand in a Trinuclear Pd(II) Complex José Vicente, M. Teresa Chicote, Eloísa Martínez-Viviente, Antonio J. Martínez-Martínez, and Peter G. Jones pp 10434 - 10436; DOI: 10.1021/ic0620440 |
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Layered Heterometallic Iodoplumbate Containing a Novel Pb3Cu6I16 Net: Structure and Optical Properties Michael C. Burns, Meredith A. Tershansy, Joseph M. Ellsworth, Zeeshan Khaliq, LeRoy Peterson, Jr., Mark D. Smith, and Hans-Conrad zur Loye pp 10437 - 10439; DOI: 10.1021/ic061827i |
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Co(II)-Co(II) Paddlewheel Complex with a Redox-Active Ligand Derived from TTF Noura Benbellat, Konstantin S. Gavrilenko, Yann Le Gal, Olivier Cador, Stéphane Golhen, Abdelkrim Gouasmia, Jean-Marc Fabre, and Lahcène Ouahab pp 10440 - 10442; DOI: 10.1021/ic061680v |
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A New Hexaferrocene Complex with a [M3(3-O)]7+ Core Valeriu Mereacre, Motohiro Nakano, Jordi Gómez-Segura, Inhar Imaz, Christian Sporer, Klaus Wurst, Jaume Veciana, Constantin Turta, Daniel Ruiz-Molina, and Peter Jaitner pp 10443 - 10445; DOI: 10.1021/ic061322s |
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Phosphazene Cations Yun Zhang, Fook S. Tham, and Christopher A. Reed pp 10446 - 10448; DOI: 10.1021/ic062077f |
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Suzuki Coupling at the Periphery of Diruthenium Coordination and Organometallic Compounds Guo-Lin Xu and Tong Ren pp 10449 - 10456; DOI: 10.1021/ic060734y |
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Synthesis of Isostructural Cage Complexes of Copper with Cobalt and Nickel for Deposition of Mixed Ceramic Oxide Materials Mazhar Hamid, Asif A. Tahir, Muhammad Mazhar, Matthias Zeller, Kieran C. Molloy, and Allen D. Hunter pp 10457 - 10466; DOI: 10.1021/ic060119u |
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Direct Electrical Measurement of the Conversion of Metal Acetates to Metal Sulfides by Hydrogen Sulfide Shabnam Virji, Richard B. Kaner, and Bruce H. Weiller pp 10467 - 10471; DOI: 10.1021/ic0607585 |
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Potassium Phthalocyanine, KPc: One-Dimensional Molecular Stacks Bridged by K+ Ions Serena Margadonna, Kosmas Prassides, Yoshihiro Iwasa, Yasujiro Taguchi, Monica F. Craciun, Sven Rogge, and Alberto F. Morpurgo pp 10472 - 10478; DOI: 10.1021/ic060727+ |
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Structural, Spectroscopic, and Magnetic Study of Bis(9,10-dihydro-9-oxo-10-acridineacetate)bis(imidazole)bis(methanol) Nickel(II) Danuta Dobrzy ska, Lucjan B. Jerzykiewicz, Marek Duczmal, Agnieszka Wojciechowska, Katarzyna Jaboska, Jerzy Palus, and Andrzej Oarowskipp 10479 - 10486; DOI: 10.1021/ic060886t |
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Mo(W)/Cu/S Cluster-Based Supramolecular Arrays Assembled from Preformed Clusters [Et4N]4[WS4Cu4I6] and [(n-Bu)4N]2[MoOS3Cu3X3] (X = I, SCN) with Flexible Ditopic Ligands Jian-Ping Lang, Qing-Feng Xu, Wen-Hua Zhang, Hong-Xi Li, Zhi-Gang Ren, Jin-Xiang Chen, and Yong Zhang pp 10487 - 10496; DOI: 10.1021/ic060974d |
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Where Is the Limit of Highly Fluorinated High-Oxidation-State Osmium Species? Sebastian Riedel and Martin Kaupp pp 10497 - 10502; DOI: 10.1021/ic061054y |
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Superstructure in RE2-xFe4Si14-y (RE = Y, Gd-Lu) Characterized by Diffraction, Electron Microscopy, and Mössbauer Spectroscopy Mi-Kyung Han, Ya-Qiao Wu, Matthew Kramer, Benjamin Vatovez, Fernande Grandjean, Gary J. Long, and Gordon J. Miller pp 10503 - 10519; DOI: 10.1021/ic061117c |
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New Ru Complexes Containing the N-Tridentate bpea and Phosphine Ligands: Consequences of Meridional vs Facial Geometry Joaquim Mola, Montserrat Rodríguez, Isabel Romero, Antoni Llobet, Teodor Parella, Albert Poater, Miquel Duran, Miquel Solà, and Jordi Benet-Buchholz pp 10520 - 10529; DOI: 10.1021/ic061126l |
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Crystal Structure and Peroxidase Activity of Myoglobin Reconstituted with Iron Porphycene Takashi Hayashi, Dai Murata, Masatomo Makino, Hiroshi Sugimoto, Takashi Matsuo, Hideaki Sato, Yoshitsugu Shiro, and Yoshio Hisaeda pp 10530 - 10536; DOI: 10.1021/ic061130x |
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Structural and Magnetic Diversity in Cyano-Bridged Bi- and Trimetallic Complexes Assembled from Cyanometalates and [M(rac-CTH)]n+ Building Blocks (CTH = d,l-5,5,7,12,12,14-Hexamethyl-1,4,8,11-tetraazacyclotetradecane) Antonio Rodríguez-Diéguez, Raikko Kivekäs, Reijo Sillanpää, Joan Cano, Francesc Lloret, Vickie McKee, Helen Stoeckli-Evans, and Enrique Colacio pp 10537 - 10551; DOI: 10.1021/ic061187j |
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The Influence of Amine/Amide versus Bisamide Coordination in Nickel Superoxide Dismutase Kosh P. Neupane and Jason Shearer pp 10552 - 10566; DOI: 10.1021/ic061156o |
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Synthesis and Structure of Nickel-Containing Cuboidal Clusters Derived from [W3Se4(H2O)9]4+. Site-Differentiated Substitution at the Nickel Site in the Series [W3NiQ4(H2O)10]4+ (Q = S, Se) Rita Hernández-Molina, Maxim N. Sokolov, Maria Clausen, and William Clegg pp 10567 - 10575; DOI: 10.1021/ic061146n |
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Electronic Transitions Involved in the Absorption Spectrum and Dual Luminescence of Tetranuclear Cubane [Cu4I4(pyridine)4] Cluster: a Density Functional Theory/Time-Dependent Density Functional Theory Investigation Filippo De Angelis, Simona Fantacci, Antonio Sgamellotti, Elena Cariati, Renato Ugo, and Peter C. Ford pp 10576 - 10584; DOI: 10.1021/ic061147f |
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Two- and Three-Dimensional Networks of Gadolinium(III) with Dicarboxylate Ligands: Synthesis, Crystal Structure, and Magnetic Properties Laura Cañadillas-Delgado, Jorge Pasán, Oscar Fabelo, María Hernández-Molina, Francesc Lloret, Miguel Julve, and Catalina Ruiz-Pérez pp 10585 - 10594; DOI: 10.1021/ic061173d |
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Donor-Acceptor Interactions and Electron Transfer in Cyano-Bridged Trinuclear Compounds Pablo Alborés, Melina B. Rossi, Luis M. Baraldo, and Leonardo D. Slep pp 10595 - 10604; DOI: 10.1021/ic061202k |
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Structural Diversity of Silver(I) 4,6-Dipyridyl-2-Aminopyrimidine Complexes: Effect of Counteranions and Ligand Isomerism Ying-Nan Chi, Kun-Lin Huang, Feng-Yun Cui, Yan-Qing Xu, and Chang-Wen Hu pp 10605 - 10612; DOI: 10.1021/ic061231v |
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Ag(I) and Cu(II) Discrete and Polymeric Complexes Based on Single- and Double-Armed Oxadiazole-Bridging Organic Clips Yu-Bin Dong, Ting Sun, Jian-Ping Ma, Xia-Xia Zhao, and Ru-Qi Huang pp 10613 - 10628; DOI: 10.1021/ic0612552 |
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Polyoxometalate (W/Mo) Compounds Connected via Lanthanide Cations with a Three-Dimensional Framework, H2{[K(H2O)2]2[Ln(H2O)5]2(H2M12O42)}·nH2O: Synthesis, Structures, and Magnetic Properties Xiutang Zhang, Daqi Wang, Jianmin Dou, Shishen Yan, Xinxin Yao, and Jianzhuang Jiang pp 10629 - 10635; DOI: 10.1021/ic0612597 |
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19F High Magnetic Field NMR Study of -ZrF4 and CeF4: From Spectra Reconstruction to Correlation between Fluorine Sites and 19F Isotropic Chemical Shifts C. Legein, F. Fayon, C. Martineau, M. Body, J.-Y. Buzaré, D. Massiot, E. Durand, A. Tressaud, A. Demourgues, O. Péron, and B. Boulard pp 10636 - 10641; DOI: 10.1021/ic061339a |
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Incorporation, Oxidation and Pyrolysis of Ferrocene into Porous Silica Glass: a Route to Different Silica/Carbon and Silica/Iron Oxide Nanocomposites Mariane C. Schnitzler, Antônio S. Mangrich, Waldemar A. A. Macedo, José D. Ardisson, and Aldo J. G. Zarbin pp 10642 - 10650; DOI: 10.1021/ic061312r |
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Synthesis, Crystal Structure, and Luminescent Properties of Novel Eu3+ Heterocyclic -Diketonate Complexes with Bidentate Nitrogen Donors S. Biju, D. B. Ambili Raj, M. L. P. Reddy, and B. M. Kariuki pp 10651 - 10660; DOI: 10.1021/ic061425a |
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Linear and Pre-organized Carboxylic Acid Picket Porphyrins as Bismuth Chelators Zakaria Halime, Mohammed Lachkar, Eric Furet, Jean-François Halet, and Bernard Boitrel pp 10661 - 10669; DOI: 10.1021/ic061422y |
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Synthesis and Spectroscopic Properties of Platinum(II) Terpyridine Complexes Having an Arylborane Charge Transfer Unit Eri Sakuda, Akiko Funahashi, and Noboru Kitamura pp 10670 - 10677; DOI: 10.1021/ic061435b |
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Synthesis, Spectroscopic, and Structural Investigation of the Cyclic [N(PR2E)2]+ Cations (E = Se, Te; R = iPr, Ph): the Effect of Anion and R-Group Exchange Jari Konu, Tristram Chivers, and Heikki M. Tuononen pp 10678 - 10687; DOI: 10.1021/ic061545i |
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Luminescent Dipyrrinato Complexes of Trivalent Group 13 Metal Ions Van S. Thoi, Jay R. Stork, Douglas Magde, and Seth M. Cohen pp 10688 - 10697; DOI: 10.1021/ic061581h |
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Coordination Preference of Ga in Hydrides A. Klaveness, O. Swang, A. Kjekshus, and H. Fjellvåg pp 10698 - 10701; DOI: 10.1021/ic0616232 |
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Construction of Polyoxometalates-Based Coordination Polymers through Direct Incorporation between Polyoxometalates and the Voids in a 2D Network Xiang-Jian Kong, Yan-Ping Ren, Pei-Qing Zheng, Yu-Xiang Long, La-Sheng Long, Rong-Bin Huang, and Lan-Sun Zheng pp 10702 - 10711; DOI: 10.1021/ic061664y |
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Activation of Atmospheric Nitrogen and Azobenzene N=N Bond Cleavage by a Transient Nb(III) Complex Uriah J. Kilgore, Xiaofan Yang, John Tomaszewski, John C. Huffman, and Daniel J. Mindiola pp 10712 - 10721; DOI: 10.1021/ic061642b |
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Metal-Organic Frameworks from Zinc Sulfite Clusters, Chains, and Sheets: 4-Connected, (3,4)-Connected 3-D Frameworks and 2-D Arrays of Catenane-Like Interlocking Rings Dan-Tam Nguyen, Emily Chew, Qichun Zhang, Alice Choi, and Xianhui Bu pp 10722 - 10727; DOI: 10.1021/ic061677b |
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La2TeI2: A New Layered Telluride Iodide with Unusual Electrical Properties Mikhail Ryazanov, Arndt Simon, and Hansjürgen Mattausch pp 10728 - 10733; DOI: 10.1021/ic061675r |
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Bis(1-amino)cyclodistib(III)azanes: the First Structural Characterization of cis and trans Isomers of a Single Cyclodipnict(III)azane Dana J. Eisler and Tristram Chivers pp 10734 - 10742; DOI: 10.1021/ic061660t |
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Spin Dimer Analysis of the Magnetic Structures of Ba3Cr2O8, Ba3Mn2O8, Na4FeO4, and Ba2CoO4 with a Three-Dimensional Network of Isolated MO4 (M = Cr, Mn, Fe, Co) Tetrahedra Hyun-Joo Koo, Kwang-Soon Lee, and Myung-Hwan Whangbo pp 10743 - 10749; DOI: 10.1021/ic061773c |
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Built-in Axial Base Binding on Phenanthroline-Strapped Zinc(II) and Iron(III) Porphyrins Frédéric Melin, Sylvie Choua, Maxime Bernard, Philippe Turek, and Jean Weiss pp 10750 - 10757; DOI: 10.1021/ic0611185 |
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First Hydrolysis Constants of Hexaaquacobalt(III) and -manganese(III): Longstanding Issues Resolved M. J. Sisley and R. B. Jordan pp 10758 - 10763; DOI: 10.1021/ic0612956 |
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Syntheses, Structures, and Magnetic Properties of Mononuclear CuII and Tetranuclear CuII3MII (M = Cu, Co, or Mn) Compounds Derived from N,N'-Ethylenebis(3-ethoxysalicylaldimine): Cocrystallization Due to Potential Encapsulation of Water Malabika Nayak, Rajesh Koner, Hsin-Huang Lin, Ulrich Flörke, Ho-Hsiang Wei, and Sasankasekhar Mohanta pp 10764 - 10773; DOI: 10.1021/ic061049u |
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Synthesis of CdSnO3·3H2O Nanocubes via Ion Exchange and Their Thermal Decompositions to Cadmium Stannate Yiwen Tang, Yun Jiang, Zhiyong Jia, Bihui Li, Lijuan Luo, and Liang Xu pp 10774 - 10779; DOI: 10.1021/ic0613715 |
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Density Functional Theory-Based Prediction of Some Aqueous-Phase Chemistry of Superheavy Element 111. Roentgenium(I) Is the 'Softest' Metal Ion Robert D. Hancock, Libero J. Bartolotti, and Nikolas Kaltsoyannis pp 10780 - 10785; DOI: 10.1021/ic061282s |
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Li80Ba39N9: The First Li/Ba Subnitride Volodymyr Smetana, Volodymyr Babizhetskyy, Grigori V. Vajenine, and Arndt Simon pp 10786 - 10789; DOI: 10.1021/ic0613816 |
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Synthesis, Structure, and 15N NMR Studies of Paramagnetic Lanthanide Complexes Obtained by Reduction of Dinitrogen William J. Evans, Daniel B. Rego, and Joseph W. Ziller pp 10790 - 10798; DOI: 10.1021/ic061485g |
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Modeling Zinc Enzyme Inhibition with Functional Thiolate Ligands Teame Tekeste and Heinrich Vahrenkamp pp 10799 - 10806; DOI: 10.1021/ic061667a |
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F/Cl-Exchange on AlCl3-Pyridine Adducts: Synthesis and Characterization of trans-Difluoro-tetrakis-pyridine-aluminum-chloride, [AlF2(Py)4]+Cl- Anton Dimitrov, Detlef Heidemann, and Erhard Kemnitz pp 10807 - 10814; DOI: 10.1021/ic061493x |
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Radical Salts of Bis(ethylenediseleno)tetrathiafulvalene with Paramagnetic Tris(oxalato)metalate Anions Eugenio Coronado, Simona Curreli, Carlos Giménez-Saiz, Carlos J. Gómez-García, and Antonio Alberola pp 10815 - 10824; DOI: 10.1021/ic061494p |
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Modeling the Mononuclear, Dinuclear, and Trinuclear Copper(I) Reaction Centers of Copper Proteins Using Pyridylalkylamine Ligands Connected to 1,3,5-Triethylbenzene Spacer Hiromi Ohi, Yoshimitsu Tachi, and Shinobu Itoh pp 10825 - 10835; DOI: 10.1021/ic061509j |
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Biologically Relevant Phosphoranes: Synthesis and Structural Characterization of Glucofuranose-Derived Phosphoranes with Penta- and Hexacoordination at Phosphorus Natalya V. Timosheva, A. Chandrasekaran, and Robert R. Holmes pp 10836 - 10848; DOI: 10.1021/ic061596f |
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Manganese Carbonyl Nitrosyls: Comparison with Isoelectronic Iron Carbonyl Derivatives Hongyan Wang, Yaoming Xie, R. Bruce King, and Henry F. Schaefer III pp 10849 - 10858; DOI: 10.1021/ic0616939 |
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Mixed-Metal Cluster Chemistry. 29. Core Expansion and Ligand-Driven Metal Exchange at Group 6-Iridium Clusters1 Alistair J. Usher, Nigel T. Lucas, Gulliver T. Dalton, Michael D. Randles, Lydie Viau, Mark G. Humphrey, Simon Petrie, Robert Stranger, Anthony C. Willis, and A. David Rae pp 10859 - 10872; DOI: 10.1021/ic061736l |
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Probing Crystal Structures and Transformation Reactions of Ammonium Molybdates by 14N MAS NMR Spectroscopy Anders R. Hove, Henrik Bilds e, Jrgen Skibsted, Michael Brorson, and Hans J. Jakobsenpp 10873 - 10881; DOI: 10.1021/ic061197k |
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Phenylazo-pyridine and Phenylazo-pyrazole Chlorido Ruthenium(II) Arene Complexes: Arene Loss, Aquation, and Cancer Cell Cytotoxicity Sarah J. Dougan, Michael Melchart, Abraha Habtemariam, Simon Parsons, and Peter J. Sadler pp 10882 - 10894; DOI: 10.1021/ic061460h |
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Mononuclear Ni(III) Complexes [NiIII(L)(P(C6H3-3-SiMe3-2-S)3)]0/1- (L = Thiolate, Selenolate, CH2CN, Cl, PPh3): Relevance to the Nickel Site of [NiFe] Hydrogenases Chien-Ming Lee, Ya-Lan Chuang, Chao-Yi Chiang, Gene-Hsiang Lee, and Wen-Feng Liaw pp 10895 - 10904; DOI: 10.1021/ic061399g |
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Crystal Absorption Spectra in the Region of 4f-4f and 4f-5d Excitations in Tm2+-Doped CsCaCl3, CsCaBr3, and CsCaI3 Judith Grimm, Eva Beurer, and Hans U. Güdel pp 10905 - 10908; DOI: 10.1021/ic051951m |
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Luminescent Hydrido-Carbonyl Clusters of Rhenium Containing Bridging 1,2-Diazine Ligands Monica Panigati, Daniela Donghi, Giuseppe D'Alfonso, Pierluigi Mercandelli, Angelo Sironi, and Laura D'Alfonso pp 10909 - 10921; DOI: 10.1021/ic061467z |
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Phosphorescent Platinum(II) Complexes Derived from Multifunctional Chromophores: Synthesis, Structures, Photophysics, and Electroluminescence Ze He, Wai-Yeung Wong, Xiaoming Yu, Hoi-Sing Kwok, and Zhenyang Lin pp 10922 - 10937; DOI: 10.1021/ic061566c |
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Magnetic Structure and Magnetic Properties of Synthetic Lindgrenite, Cu3(OH)2(MoO4)2 Serge Vilminot, Gilles André, Mireille Richard-Plouet, Françoise Bourée-Vigneron, and Mohamedally Kurmoo pp 10938 - 10946; DOI: 10.1021/ic061182m |
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High-Pressure Synthesis and Structure Determination of K6(SeO4)(SeO5), the First Potassium Orthoselenate(VI) Denis Orosel, Robert Dinnebier, and Martin Jansen pp 10947 - 10950; DOI: 10.1021/ic061548v |
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Spectroscopic and Ab Initio Characterization of the [ReH9]2- Ion Stewart F. Parker, Keith Refson, Kenneth P. J. Williams, Dale A. Braden, Bruce S. Hudson, and Klaus Yvon pp 10951 - 10957; DOI: 10.1021/ic0611894 |
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Isostructural Bisdithiazolyl and Bisthiaselenazolyl Radicals: Trends in Bandwidth and Conductivity Jaclyn L. Brusso, Shahab Derakhshan, Mikhail E. Itkis, Holger Kleinke, Robert C. Haddon, Richard T. Oakley, Robert W. Reed, John F. Richardson, Craig M. Robertson, and Laurence K. Thompson pp 10958 - 10966; DOI: 10.1021/ic061687c |
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Heterometallic Dithiolene Complexes Formed by Stepwise Displacement of Cyclopentadienyl Ligands from Nickelocene with CpMo(S2C2Ph2)2 Harry Adams, Hannah C. Gardner, Richard A. McRoy, Michael J. Morris, Jeffrey C. Motley, and Sebastian Torker pp 10967 - 10975; DOI: 10.1021/ic0606227 |
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Copper(II) Complexes of salen Analogues with Two Differently Substituted (Push-Pull) Salicylaldehyde Moieties. A Study on the Modulation of Electronic Asymmetry and Nonlinear Optical Properties Luca Rigamonti, Francesco Demartin, Alessandra Forni, Stefania Righetto, and Alessandro Pasini pp 10976 - 10989; DOI: 10.1021/ic0613513 |
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Dinuclear Iridium(III) Complexes Consisting of Back-to-Back tpy-(ph)n-tpy Bridging Ligands (n = 0, 1, or 2) and Terminal Cyclometallating Tridentate N-C-N Ligands Audrey Auffrant, Andrea Barbieri, Francesco Barigelletti, Jean-Paul Collin, Lucia Flamigni, Cristiana Sabatini, and Jean-Pierre Sauvage pp 10990 - 10997; DOI: 10.1021/ic061009q |
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Janus Scorpionates: Supramolecular Tectons for the Directed Assembly of Hard-Soft Alkali Metallopolymer Chains Rosalice M. Silva, Chengeto Gwengo, Sergey V. Lindeman, Mark D. Smith, and James R. Gardinier pp 10998 - 11007; DOI: 10.1021/ic0615877 |
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Guanidinate-Stabilized Monomeric Hafnium Amide Complexes as Promising Precursors for MOCVD of HfO2 Andrian Milanov, Raghunandan Bhakta, Arne Baunemann, Hans-Werner Becker, Reji Thomas, Peter Ehrhart, Manuela Winter, and Anjana Devi pp 11008 - 11018; DOI: 10.1021/ic061056i |
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Extended Dipolar Nonlinear Optical Chromophores Based on trans-Bis[1,2-phenylenebis(dimethylarsine)]chlororuthenium(II) Centers Benjamin J. Coe, Josephine L. Harries, James A. Harris, Bruce S. Brunschwig, Peter N. Horton, and Michael B. Hursthouse pp 11019 - 11029; DOI: 10.1021/ic061659u |
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Layered Lanthanide Molybdate Pillared by Chiral [-Mo2O4EDTA]2- Junjian Luo and Li Xu pp 11030 - 11034; DOI: 10.1021/ic0611793 |
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Concerning the Electronic Coupling of MoMo Quadruple Bonds Linked by 4,4'-Azodibenzoate and Comparison with t2g6-Ru(II) Centers by 4,4'-Azodiphenylcyanamido Ligands Malcolm H. Chisholm, Jason S. D'Acchioli, Christopher M. Hadad, and Nathan J. Patmore pp 11035 - 11042; DOI: 10.1021/ic060956w |
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DNA Cleavage on Photoexposure at the d-d Band in Ternary Copper(II) Complexes Using Red-Light Laser Shanta Dhar, Munirathinam Nethaji, and Akhil R. Chakravarty pp 11043 - 11050; DOI: 10.1021/ic060328e |
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Multireference Ab Initio Calculations on Reaction Intermediates of the Multicopper Oxidases Jakub Chalupsk , Frank Neese, Edward I. Solomon, Ulf Ryde, and Lubomír Rulíekpp 11051 - 11059; DOI: 10.1021/ic0619512 |
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Thermodynamics of Pyridine Coordination in 1,4-Phenylene Bridged Bimetallic (Pd, Pt) Complexes Containing Two N,C,N' Motifs, 1,4-M2-[C6(CH2NR2)4-2,3,5,6] Sung Lan Jeon, David M. Loveless, Wayne C. Yount, and Stephen L. Craig pp 11060 - 11068; DOI: 10.1021/ic061188b |